Polímeros de coordenação: estratégias, design de ligantes oxamato, síntese e caracterização

Detalhes bibliográficos
Ano de defesa: 2019
Autor(a) principal: Kalinke, Lucas Hoffmann Greghi lattes
Orientador(a): Gomes, Danielle Cangussu de Castro lattes
Banca de defesa: Gomes, Danielle Cangussu de Castro, Barros, Wdeson Pereira, Oliveira, Cecília Maria Alves de, Santana, Ricardo Costa de, Martins, Felipe Terra
Tipo de documento: Tese
Tipo de acesso: Acesso aberto
Idioma: por
Instituição de defesa: Universidade Federal de Goiás
Programa de Pós-Graduação: Programa de Pós-graduação em Química (IQ)
Departamento: Instituto de Química - IQ (RG)
País: Brasil
Palavras-chave em Português:
Polímeros de coordenação
Oxamato
Magnetismo
Palavras-chave em Inglês:
Coordination polymers
Oxamate
Magnetism
Área do conhecimento CNPq:
CIENCIAS EXATAS E DA TERRA::QUIMICA::QUIMICA INORGANICA
Link de acesso: http://repositorio.bc.ufg.br/tede/handle/tede/11108
Resumo: This present work presents the synthesis and characterization of some coordination compounds containing oxamato ligands with different topologies. The precursor 1 and the chain (1D) Mn-Cu (7) with the H2Et2npbo ligand [npbo= N,N’-(naphtalene-1,8-diyl)-bis(oxamato)], the plane (2D) Ca3-Cu9 (8) with the H2Et2dabtzo ligand [dabtzo= N,N'-(4,4'-bithiazole-2,2'-diyl)-bis(oxamato)] and the 3D polymers M6-Co4 [M= Ca (9), Dy (10), Er (11) Ho(12) e Tb(13)] all of them with the H3Et3tpatox ligand [tpatox= N,N',N''-(nitrilotris(phenilene-4,1-diyl))-tris(oxamato)]. In addition were prepared precursor complexes of Cu(II) (2 and 3) and Co(II) (4) also with the H2Et2dabtzo ligand and the Ni(II) complex (6) with the H4Et4topp ligand [topp= N,N’,N’’,N’’’-tetrakis(4-aminophenyl)porphyrin-tetrakis(oxamato)]. The crystal structures of 2, 4, 7-12 were determined by single-crystal X ray diffraction. The magnetic properties of 8 have shown that Cu9 unit behaves as a trimer of trimers with different magnetic exchange paths between the Cu(II) ions. The magnetic properties for the polymers 10-13 reveal the behavior as magnetically isolated lanthanide ion with ground 6H15/2 (DyIII), 4I15/2 (ErIII), 5I8 (HoIII) e 7F6(TbIII); with Mj= ±½ (10 e 11) and Mj= 0 (12 e 13). Furthermore, the polymeric compounds 10 e 11 have shown slow magnetic relaxation with Ea and  been determined by the Arrhenius law.
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spelling Gomes, Danielle Cangussu de Castrohttp://lattes.cnpq.br/5709288358367849Gomes, Danielle Cangussu de CastroBarros, Wdeson PereiraOliveira, Cecília Maria Alves deSantana, Ricardo Costa deMartins, Felipe Terrahttp://lattes.cnpq.br/5183988899625863Kalinke, Lucas Hoffmann Greghi2021-02-22T15:56:57Z2021-02-22T15:56:57Z2019-04-11KALINKE, L. H. G. Polímeros de coordenação: estratégias, design de ligantes oxamato, síntese e caracterização. 2019. 134 f. Tese (Doutorado em Química) - Universidade Federal de Goiás, Goiânia, 2019.http://repositorio.bc.ufg.br/tede/handle/tede/11108This present work presents the synthesis and characterization of some coordination compounds containing oxamato ligands with different topologies. The precursor 1 and the chain (1D) Mn-Cu (7) with the H2Et2npbo ligand [npbo= N,N’-(naphtalene-1,8-diyl)-bis(oxamato)], the plane (2D) Ca3-Cu9 (8) with the H2Et2dabtzo ligand [dabtzo= N,N'-(4,4'-bithiazole-2,2'-diyl)-bis(oxamato)] and the 3D polymers M6-Co4 [M= Ca (9), Dy (10), Er (11) Ho(12) e Tb(13)] all of them with the H3Et3tpatox ligand [tpatox= N,N',N''-(nitrilotris(phenilene-4,1-diyl))-tris(oxamato)]. In addition were prepared precursor complexes of Cu(II) (2 and 3) and Co(II) (4) also with the H2Et2dabtzo ligand and the Ni(II) complex (6) with the H4Et4topp ligand [topp= N,N’,N’’,N’’’-tetrakis(4-aminophenyl)porphyrin-tetrakis(oxamato)]. The crystal structures of 2, 4, 7-12 were determined by single-crystal X ray diffraction. The magnetic properties of 8 have shown that Cu9 unit behaves as a trimer of trimers with different magnetic exchange paths between the Cu(II) ions. The magnetic properties for the polymers 10-13 reveal the behavior as magnetically isolated lanthanide ion with ground 6H15/2 (DyIII), 4I15/2 (ErIII), 5I8 (HoIII) e 7F6(TbIII); with Mj= ±½ (10 e 11) and Mj= 0 (12 e 13). Furthermore, the polymeric compounds 10 e 11 have shown slow magnetic relaxation with Ea and  been determined by the Arrhenius law.O presente trabalho apresenta a síntese e caracterização de diversos compostos de coordenação derivados de ligantes oxamatos com diferentes topologias. O precursor 1 e a cadeia (1D) Mn-Cu (7) derivada do ligante H2Et2npbo [npbo= N,N’-(naftaleno-1,8-diil)-bis(oxamato)], o plano (2D) Ca3-Cu9 (8) derivado do ligante H2Et2dabtzo [dabtzo= N,N'-(4,4'-bitiazol-2,2'-diil)-bis(oxamato)] e os polímeros bimetálicos 3D M6-Co4 [M= Ca (9), Dy (10), Er (11) Ho(12) e Tb(13)] todos derivados do ligante H3Et3tpatox [tpatox= N,N',N''-(nitrilotris(fenileno-4,1-diil))-tris(oxamato)]. Além disso foram preparados os complexos precursores inéditos de Cu(II) (2 e 3) e Co(II) (4) derivados do ligante H2Et2dabtzo e o complexo de Ni(II) (6) derivado do ligante H4Et4topp [topp= N,N’,N’’,N’’’-tetra(4-aminofenil)porfirina-tetrakis(oxamato)]. As estruturas cristalinas de 2, 4, 7-12 foram determinadas por difração de raios X por monocristal. As propriedades magnéticas de 8 mostram que a unidade de Cu9 se comporta como um trímero de trímeros com diversos caminhos de interação magnética entre os íons Cu(II). As propriedades magnéticas dos polímeros 10-13 revelam o comportamento de íons lantanídeos magneticamente isolados com termos fundamentais 6H15/2 (DyIII), 4I15/2 (ErIII), 5I8 (HoIII) e 7F6(TbIII); com Mj= ±½ (10 e 11) e Mj= 0 (12 e 13). Além disso os polímeros 10 e 11 apresentam relaxação lenta da magnetização com Ea e  determinado pela lei de Arrhenius.Submitted by Marlene Santos (marlene.bc.ufg@gmail.com) on 2021-02-22T15:32:56Z No. of bitstreams: 2 license_rdf: 805 bytes, checksum: 4460e5956bc1d1639be9ae6146a50347 (MD5) Tese - Lucas Hoffmann Greghi Kalinke - 2019.pdf: 7120647 bytes, checksum: 084b298c4612d04ae960cb75f33d392e (MD5)Approved for entry into archive by Luciana Ferreira (lucgeral@gmail.com) on 2021-02-22T15:56:57Z (GMT) No. of bitstreams: 2 license_rdf: 805 bytes, checksum: 4460e5956bc1d1639be9ae6146a50347 (MD5) Tese - Lucas Hoffmann Greghi Kalinke - 2019.pdf: 7120647 bytes, checksum: 084b298c4612d04ae960cb75f33d392e (MD5)Made available in DSpace on 2021-02-22T15:56:57Z (GMT). No. of bitstreams: 2 license_rdf: 805 bytes, checksum: 4460e5956bc1d1639be9ae6146a50347 (MD5) Tese - Lucas Hoffmann Greghi Kalinke - 2019.pdf: 7120647 bytes, checksum: 084b298c4612d04ae960cb75f33d392e (MD5) Previous issue date: 2019-04-11Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPESporUniversidade Federal de GoiásPrograma de Pós-graduação em Química (IQ)UFGBrasilInstituto de Química - IQ (RG)Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessPolímeros de coordenaçãoOxamatoMagnetismoCoordination polymersOxamateMagnetismCIENCIAS EXATAS E DA TERRA::QUIMICA::QUIMICA INORGANICAPolímeros de coordenação: estratégias, design de ligantes oxamato, síntese e caracterizaçãoCoordination polymers: strategies, oxamate ligands design, synthesis and characterizationinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesis805005005005002910941reponame:Repositório Institucional da UFGinstname:Universidade Federal de Goiás (UFG)instacron:UFGLICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://repositorio.bc.ufg.br/tede/bitstreams/b8f3908e-1e85-4eec-96bc-c8e6fa5913b1/download8a4605be74aa9ea9d79846c1fba20a33MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8805http://repositorio.bc.ufg.br/tede/bitstreams/88c84db0-6dcd-4c1e-a3fb-cb11c106bb54/download4460e5956bc1d1639be9ae6146a50347MD52ORIGINALTese - Lucas Hoffmann Greghi Kalinke - 2019.pdfTese - Lucas Hoffmann Greghi Kalinke - 2019.pdfapplication/pdf7120647http://repositorio.bc.ufg.br/tede/bitstreams/1f671d30-ee68-4243-90d9-3d58e3e9b498/download084b298c4612d04ae960cb75f33d392eMD53tede/111082021-02-22 12:56:58.054http://creativecommons.org/licenses/by-nc-nd/4.0/Attribution-NonCommercial-NoDerivatives 4.0 Internationalopen.accessoai:repositorio.bc.ufg.br:tede/11108http://repositorio.bc.ufg.br/tedeRepositório InstitucionalPUBhttp://repositorio.bc.ufg.br/oai/requesttasesdissertacoes.bc@ufg.bropendoar:2021-02-22T15:56:58Repositório Institucional da UFG - Universidade Federal de Goiás (UFG)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
dc.title.pt_BR.fl_str_mv Polímeros de coordenação: estratégias, design de ligantes oxamato, síntese e caracterização
dc.title.alternative.eng.fl_str_mv Coordination polymers: strategies, oxamate ligands design, synthesis and characterization
title Polímeros de coordenação: estratégias, design de ligantes oxamato, síntese e caracterização
spellingShingle Polímeros de coordenação: estratégias, design de ligantes oxamato, síntese e caracterização
Kalinke, Lucas Hoffmann Greghi
Polímeros de coordenação
Oxamato
Magnetismo
Coordination polymers
Oxamate
Magnetism
CIENCIAS EXATAS E DA TERRA::QUIMICA::QUIMICA INORGANICA
title_short Polímeros de coordenação: estratégias, design de ligantes oxamato, síntese e caracterização
title_full Polímeros de coordenação: estratégias, design de ligantes oxamato, síntese e caracterização
title_fullStr Polímeros de coordenação: estratégias, design de ligantes oxamato, síntese e caracterização
title_full_unstemmed Polímeros de coordenação: estratégias, design de ligantes oxamato, síntese e caracterização
title_sort Polímeros de coordenação: estratégias, design de ligantes oxamato, síntese e caracterização
author Kalinke, Lucas Hoffmann Greghi
author_facet Kalinke, Lucas Hoffmann Greghi
author_role author
dc.contributor.advisor1.fl_str_mv Gomes, Danielle Cangussu de Castro
dc.contributor.advisor1Lattes.fl_str_mv http://lattes.cnpq.br/5709288358367849
dc.contributor.referee1.fl_str_mv Gomes, Danielle Cangussu de Castro
dc.contributor.referee2.fl_str_mv Barros, Wdeson Pereira
dc.contributor.referee3.fl_str_mv Oliveira, Cecília Maria Alves de
dc.contributor.referee4.fl_str_mv Santana, Ricardo Costa de
dc.contributor.referee5.fl_str_mv Martins, Felipe Terra
dc.contributor.authorLattes.fl_str_mv http://lattes.cnpq.br/5183988899625863
dc.contributor.author.fl_str_mv Kalinke, Lucas Hoffmann Greghi
contributor_str_mv Gomes, Danielle Cangussu de Castro
Gomes, Danielle Cangussu de Castro
Barros, Wdeson Pereira
Oliveira, Cecília Maria Alves de
Santana, Ricardo Costa de
Martins, Felipe Terra
dc.subject.por.fl_str_mv Polímeros de coordenação
Oxamato
Magnetismo
topic Polímeros de coordenação
Oxamato
Magnetismo
Coordination polymers
Oxamate
Magnetism
CIENCIAS EXATAS E DA TERRA::QUIMICA::QUIMICA INORGANICA
dc.subject.eng.fl_str_mv Coordination polymers
Oxamate
Magnetism
dc.subject.cnpq.fl_str_mv CIENCIAS EXATAS E DA TERRA::QUIMICA::QUIMICA INORGANICA
description This present work presents the synthesis and characterization of some coordination compounds containing oxamato ligands with different topologies. The precursor 1 and the chain (1D) Mn-Cu (7) with the H2Et2npbo ligand [npbo= N,N’-(naphtalene-1,8-diyl)-bis(oxamato)], the plane (2D) Ca3-Cu9 (8) with the H2Et2dabtzo ligand [dabtzo= N,N'-(4,4'-bithiazole-2,2'-diyl)-bis(oxamato)] and the 3D polymers M6-Co4 [M= Ca (9), Dy (10), Er (11) Ho(12) e Tb(13)] all of them with the H3Et3tpatox ligand [tpatox= N,N',N''-(nitrilotris(phenilene-4,1-diyl))-tris(oxamato)]. In addition were prepared precursor complexes of Cu(II) (2 and 3) and Co(II) (4) also with the H2Et2dabtzo ligand and the Ni(II) complex (6) with the H4Et4topp ligand [topp= N,N’,N’’,N’’’-tetrakis(4-aminophenyl)porphyrin-tetrakis(oxamato)]. The crystal structures of 2, 4, 7-12 were determined by single-crystal X ray diffraction. The magnetic properties of 8 have shown that Cu9 unit behaves as a trimer of trimers with different magnetic exchange paths between the Cu(II) ions. The magnetic properties for the polymers 10-13 reveal the behavior as magnetically isolated lanthanide ion with ground 6H15/2 (DyIII), 4I15/2 (ErIII), 5I8 (HoIII) e 7F6(TbIII); with Mj= ±½ (10 e 11) and Mj= 0 (12 e 13). Furthermore, the polymeric compounds 10 e 11 have shown slow magnetic relaxation with Ea and  been determined by the Arrhenius law.
publishDate 2019
dc.date.issued.fl_str_mv 2019-04-11
dc.date.accessioned.fl_str_mv 2021-02-22T15:56:57Z
dc.date.available.fl_str_mv 2021-02-22T15:56:57Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/doctoralThesis
format doctoralThesis
status_str publishedVersion
dc.identifier.citation.fl_str_mv KALINKE, L. H. G. Polímeros de coordenação: estratégias, design de ligantes oxamato, síntese e caracterização. 2019. 134 f. Tese (Doutorado em Química) - Universidade Federal de Goiás, Goiânia, 2019.
dc.identifier.uri.fl_str_mv http://repositorio.bc.ufg.br/tede/handle/tede/11108
identifier_str_mv KALINKE, L. H. G. Polímeros de coordenação: estratégias, design de ligantes oxamato, síntese e caracterização. 2019. 134 f. Tese (Doutorado em Química) - Universidade Federal de Goiás, Goiânia, 2019.
url http://repositorio.bc.ufg.br/tede/handle/tede/11108
dc.language.iso.fl_str_mv por
language por
dc.relation.program.fl_str_mv 80
dc.relation.confidence.fl_str_mv 500
500
500
500
dc.relation.department.fl_str_mv 29
dc.relation.cnpq.fl_str_mv 1094
dc.relation.sponsorship.fl_str_mv 1
dc.rights.driver.fl_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Universidade Federal de Goiás
dc.publisher.program.fl_str_mv Programa de Pós-graduação em Química (IQ)
dc.publisher.initials.fl_str_mv UFG
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv Instituto de Química - IQ (RG)
publisher.none.fl_str_mv Universidade Federal de Goiás
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFG
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