Elabora??o e caracteriza??o f?sico-qu?mica de filmes de amido adicionados de a?a? (Euterpe oleracea mart.) liofilizado

Detalhes bibliográficos
Ano de defesa: 2016
Autor(a) principal: Pessanha, K?nia Let?cia Ferreira lattes
Orientador(a): Godoy, Ronoel Luiz de Oliveira
Banca de defesa: Godoy, Ronoel Luiz de Oliveira, Gouv?a, Ana Cristina Miranda Senna, Ascheri, Jos? Luis Ramirez
Tipo de documento: Dissertação
Tipo de acesso: Acesso aberto
Idioma: por
Instituição de defesa: Universidade Federal Rural do Rio de Janeiro
Programa de Pós-Graduação: Programa de P?s-Gradua??o em Ci?ncia e Tecnologia de Alimentos
Departamento: Instituto de Tecnologia
País: Brasil
Palavras-chave em Português:
Palavras-chave em Inglês:
Área do conhecimento CNPq:
Link de acesso: https://tede.ufrrj.br/jspui/handle/jspui/1868
Resumo: The use of synthetic materials derived from non-renewable sources has generated a high environmental impact, which required from the industry, the development of polymeric materials based on biodegradable polymers. Polysaccharides such as starch, are capable of forming low cost homogeneous edible films, resulting in aggregate value to the food due to the film increased biodegradability and increased shelf life of packaged food by the possibility of adding antioxidants, nutrients and natural pigments, which raise the nutritional and organoleptic characteristics of the product. This work was aimed at developing and evaluating, chemically and physically, films from filmogenic solutions (SF) developed with cassava starch, freez-dried acai and glycerol, through spreading technique casting. After preparation under controlled conditions, SF were dried at 30 ? 5 ? C for 24 hours in an oven with forced air circulation. The resulting films were unmolded and stowed in relative humidity controlled at 52.9% for six days for further characterization. The developed films were characterized as the quantification of anthocyanins by High-Performance Liquid Chromatography (HPLC), Antioxidant Capacity by ABTS? + and ORAC, thickness, water solubility, permeability to water vapor (PVA), water activity (Aw) , contact angle, optical properties and mechanical properties. At the same time a control film was elaborated (without the addition of acai) that underwent the same physical tests. The results indicated that the addition of acai pulp enabled the development of an edible plastic rich in anthocyanins and higher antioxidant capacity (150,70 ?mol Trolox) than fruist like strawberry and raspberry. The anthocyanins had a higher interaction with the starch molecules, probably through the hydroxyl of both which established hydrogen bonds allowing immobilization of anthocyanins in the film, which was advantageous given the high instability of anthocyanins. The polymeric matrix added with freeze-dried acai had its thickness increased which caused an increase of the PVA, reduction of water solubility and water activity, the latter two being advantageous parameters for a food package. Regarding the mechanical properties, it was observed that the rupture power in drilling and deformation were reduced. In the pull test there was a reduction of stress at break and modulus of elasticity. The deformation in traction showed higher results, indicating that the addition of the freeze-dried acai increased film flexibility. As for color, the film presented a darker color compatible with the fruit, with a potential use for packaging of dark foods.
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spelling Godoy, Ronoel Luiz de Oliveira507.802.047-00Carvalho, Carlos Wanderlei Piler de009.412.587-26Godoy, Ronoel Luiz de OliveiraGouv?a, Ana Cristina Miranda SennaAscheri, Jos? Luis Ramirez112.348.277-27http://lattes.cnpq.br/8791040072071936Pessanha, K?nia Let?cia Ferreira2017-07-11T18:42:28Z2016-03-02PESSANHA, K?nia Let?cia Ferreira. Elabora??o e caracteriza??o f?sico-qu?mica de filmes de amido adicionados de a?a? (Euterpe oleracea mart.) liofilizado. 2016. 99 f. Disserta??o (Mestrado em Ci?ncia e Tecnologia de Alimentos). Instituto de Tecnologia, Departamento de Alimentos, Universidade Federal Rural do Rio de Janeiro, Serop?dica, RJ,https://tede.ufrrj.br/jspui/handle/jspui/1868The use of synthetic materials derived from non-renewable sources has generated a high environmental impact, which required from the industry, the development of polymeric materials based on biodegradable polymers. Polysaccharides such as starch, are capable of forming low cost homogeneous edible films, resulting in aggregate value to the food due to the film increased biodegradability and increased shelf life of packaged food by the possibility of adding antioxidants, nutrients and natural pigments, which raise the nutritional and organoleptic characteristics of the product. This work was aimed at developing and evaluating, chemically and physically, films from filmogenic solutions (SF) developed with cassava starch, freez-dried acai and glycerol, through spreading technique casting. After preparation under controlled conditions, SF were dried at 30 ? 5 ? C for 24 hours in an oven with forced air circulation. The resulting films were unmolded and stowed in relative humidity controlled at 52.9% for six days for further characterization. The developed films were characterized as the quantification of anthocyanins by High-Performance Liquid Chromatography (HPLC), Antioxidant Capacity by ABTS? + and ORAC, thickness, water solubility, permeability to water vapor (PVA), water activity (Aw) , contact angle, optical properties and mechanical properties. At the same time a control film was elaborated (without the addition of acai) that underwent the same physical tests. The results indicated that the addition of acai pulp enabled the development of an edible plastic rich in anthocyanins and higher antioxidant capacity (150,70 ?mol Trolox) than fruist like strawberry and raspberry. The anthocyanins had a higher interaction with the starch molecules, probably through the hydroxyl of both which established hydrogen bonds allowing immobilization of anthocyanins in the film, which was advantageous given the high instability of anthocyanins. The polymeric matrix added with freeze-dried acai had its thickness increased which caused an increase of the PVA, reduction of water solubility and water activity, the latter two being advantageous parameters for a food package. Regarding the mechanical properties, it was observed that the rupture power in drilling and deformation were reduced. In the pull test there was a reduction of stress at break and modulus of elasticity. The deformation in traction showed higher results, indicating that the addition of the freeze-dried acai increased film flexibility. As for color, the film presented a darker color compatible with the fruit, with a potential use for packaging of dark foods.O uso de materiais sint?ticos oriundos de fontes n?o renov?veis tem gerado um alto impacto a n?vel ambiental, o que demanda da ind?stria o desenvolvimento de materiais a base de pol?meros biodegrad?veis. Polissacar?deos como o amido, t?m a capacidade de formar filmes comest?veis, homog?neos e de baixo custo, gerando valor agregado aos alimentos devido ? maior biodegradabilidade dos filmes e aumento da validade comercial do alimento embalado pela possibilidade da adi??o de compostos antioxidantes, nutrientes e pigmentos naturais ao filme, o que pode elevar as caracter?sticas nutricionais e organol?pticas do alimento. Este trabalho teve como objetivo desenvolver e avaliar, qu?mica e fisicamente, filmes a partir de solu??es filmog?nicas (SF) elaboradas com amido de mandioca, a?a? liofilizado e glicerol, atrav?s da t?cnica de espalhamento casting. Ap?s o preparo sob condi??es controladas, as SF foram desidratadas a 30?C ? 5 ?C por 24h em estufa com circula??o de ar for?ada. Os filmes resultantes foram desenformados e acondicionados em umidade relativa do ar controlada a 52,9% por seis dias para posterior caracteriza??o. Os filmes foram caracterizados quanto a quantifica??o de antocianinas por Cromatografia L?quida de Alta Efici?ncia (CLAE), capacidade antioxidante por ABTS?+ e ORAC, espessura, solubilidade em ?gua, permeabilidade ao vapor de ?gua (PVA), atividade de ?gua (Aw), ?ngulo de contato, propriedades ?pticas e propriedades mec?nicas. Concomitantemente foi elaborado um filme controle (sem adi??o de a?a?) que foi submetido aos mesmos testes f?sicos. Os resultados indicaram que a adi??o do a?a? liofilizado permitiu o desenvolvimento de um filme pl?stico rico em antocianinas e com alta capacidade antioxidante (150,70 ?mol Trolox) superior a frutas como o morango e framboesa. As antocianinas tiveram uma alta intera??o com as mol?culas de amido, provavelmente atrav?s das hidroxilas de ambos que estabeleceram liga??es de hidrog?nio permitindo a imobiliza??o das antocianinas no filme, o que foi vantajoso visto a instabilidade das antocianinas. A matriz polim?rica adicionada de a?a? liofilizado teve sua espessura aumentada o que provocou aumento da PVA, redu??o da solubilidade em ?gua e da atividade de ?gua, sendo estes dois ?ltimos par?metros vantajosos para uma embalagem de alimentos. Quanto ?s propriedades mec?nicas, observou-se que a for?a de ruptura e a deforma??o na perfura??o foram reduzidas. No teste de tra??o houve redu??o da tens?o na ruptura e no m?dulo de elasticidade. A deforma??o na tra??o apresentou maior resultado, indicando que a adi??o do a?a? liofilizado aumentou a flexibilidade do filme. Quanto a cor, o filme apresentou colora??o escura compat?vel com o fruto, com potencial uso para embalagem de alimentos escuros.Submitted by Jorge Silva (jorgelmsilva@ufrrj.br) on 2017-07-11T18:42:28Z No. of bitstreams: 1 2016 - K?nia Let?cia Ferreira Pessanha.pdf: 2366902 bytes, checksum: 926a4615f4a193d9328fe681ce73019f (MD5)Made available in DSpace on 2017-07-11T18:42:28Z (GMT). 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(Euterpe oleracea mart.) liofilizadoPreparation and physicochemical characterization of starch films added a?a? 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dc.title.por.fl_str_mv Elabora??o e caracteriza??o f?sico-qu?mica de filmes de amido adicionados de a?a? (Euterpe oleracea mart.) liofilizado
dc.title.alternative.eng.fl_str_mv Preparation and physicochemical characterization of starch films added a?a? (Euterpe oleracea Mart.) lyophilized
title Elabora??o e caracteriza??o f?sico-qu?mica de filmes de amido adicionados de a?a? (Euterpe oleracea mart.) liofilizado
spellingShingle Elabora??o e caracteriza??o f?sico-qu?mica de filmes de amido adicionados de a?a? (Euterpe oleracea mart.) liofilizado
Pessanha, K?nia Let?cia Ferreira
Active packaging
biodegradable
anthocyanins
antioxidants
Embalagens ativas
biodegrad?veis
antocianinas
antioxidantes
Ci?ncia e Tecnologia de Alimentos
title_short Elabora??o e caracteriza??o f?sico-qu?mica de filmes de amido adicionados de a?a? (Euterpe oleracea mart.) liofilizado
title_full Elabora??o e caracteriza??o f?sico-qu?mica de filmes de amido adicionados de a?a? (Euterpe oleracea mart.) liofilizado
title_fullStr Elabora??o e caracteriza??o f?sico-qu?mica de filmes de amido adicionados de a?a? (Euterpe oleracea mart.) liofilizado
title_full_unstemmed Elabora??o e caracteriza??o f?sico-qu?mica de filmes de amido adicionados de a?a? (Euterpe oleracea mart.) liofilizado
title_sort Elabora??o e caracteriza??o f?sico-qu?mica de filmes de amido adicionados de a?a? (Euterpe oleracea mart.) liofilizado
author Pessanha, K?nia Let?cia Ferreira
author_facet Pessanha, K?nia Let?cia Ferreira
author_role author
dc.contributor.advisor1.fl_str_mv Godoy, Ronoel Luiz de Oliveira
dc.contributor.advisor1ID.fl_str_mv 507.802.047-00
dc.contributor.advisor-co1.fl_str_mv Carvalho, Carlos Wanderlei Piler de
dc.contributor.advisor-co1ID.fl_str_mv 009.412.587-26
dc.contributor.referee1.fl_str_mv Godoy, Ronoel Luiz de Oliveira
dc.contributor.referee2.fl_str_mv Gouv?a, Ana Cristina Miranda Senna
dc.contributor.referee3.fl_str_mv Ascheri, Jos? Luis Ramirez
dc.contributor.authorID.fl_str_mv 112.348.277-27
dc.contributor.authorLattes.fl_str_mv http://lattes.cnpq.br/8791040072071936
dc.contributor.author.fl_str_mv Pessanha, K?nia Let?cia Ferreira
contributor_str_mv Godoy, Ronoel Luiz de Oliveira
Carvalho, Carlos Wanderlei Piler de
Godoy, Ronoel Luiz de Oliveira
Gouv?a, Ana Cristina Miranda Senna
Ascheri, Jos? Luis Ramirez
dc.subject.eng.fl_str_mv Active packaging
biodegradable
anthocyanins
antioxidants
topic Active packaging
biodegradable
anthocyanins
antioxidants
Embalagens ativas
biodegrad?veis
antocianinas
antioxidantes
Ci?ncia e Tecnologia de Alimentos
dc.subject.por.fl_str_mv Embalagens ativas
biodegrad?veis
antocianinas
antioxidantes
dc.subject.cnpq.fl_str_mv Ci?ncia e Tecnologia de Alimentos
description The use of synthetic materials derived from non-renewable sources has generated a high environmental impact, which required from the industry, the development of polymeric materials based on biodegradable polymers. Polysaccharides such as starch, are capable of forming low cost homogeneous edible films, resulting in aggregate value to the food due to the film increased biodegradability and increased shelf life of packaged food by the possibility of adding antioxidants, nutrients and natural pigments, which raise the nutritional and organoleptic characteristics of the product. This work was aimed at developing and evaluating, chemically and physically, films from filmogenic solutions (SF) developed with cassava starch, freez-dried acai and glycerol, through spreading technique casting. After preparation under controlled conditions, SF were dried at 30 ? 5 ? C for 24 hours in an oven with forced air circulation. The resulting films were unmolded and stowed in relative humidity controlled at 52.9% for six days for further characterization. The developed films were characterized as the quantification of anthocyanins by High-Performance Liquid Chromatography (HPLC), Antioxidant Capacity by ABTS? + and ORAC, thickness, water solubility, permeability to water vapor (PVA), water activity (Aw) , contact angle, optical properties and mechanical properties. At the same time a control film was elaborated (without the addition of acai) that underwent the same physical tests. The results indicated that the addition of acai pulp enabled the development of an edible plastic rich in anthocyanins and higher antioxidant capacity (150,70 ?mol Trolox) than fruist like strawberry and raspberry. The anthocyanins had a higher interaction with the starch molecules, probably through the hydroxyl of both which established hydrogen bonds allowing immobilization of anthocyanins in the film, which was advantageous given the high instability of anthocyanins. The polymeric matrix added with freeze-dried acai had its thickness increased which caused an increase of the PVA, reduction of water solubility and water activity, the latter two being advantageous parameters for a food package. Regarding the mechanical properties, it was observed that the rupture power in drilling and deformation were reduced. In the pull test there was a reduction of stress at break and modulus of elasticity. The deformation in traction showed higher results, indicating that the addition of the freeze-dried acai increased film flexibility. As for color, the film presented a darker color compatible with the fruit, with a potential use for packaging of dark foods.
publishDate 2016
dc.date.issued.fl_str_mv 2016-03-02
dc.date.accessioned.fl_str_mv 2017-07-11T18:42:28Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/masterThesis
format masterThesis
status_str publishedVersion
dc.identifier.citation.fl_str_mv PESSANHA, K?nia Let?cia Ferreira. Elabora??o e caracteriza??o f?sico-qu?mica de filmes de amido adicionados de a?a? (Euterpe oleracea mart.) liofilizado. 2016. 99 f. Disserta??o (Mestrado em Ci?ncia e Tecnologia de Alimentos). Instituto de Tecnologia, Departamento de Alimentos, Universidade Federal Rural do Rio de Janeiro, Serop?dica, RJ,
dc.identifier.uri.fl_str_mv https://tede.ufrrj.br/jspui/handle/jspui/1868
identifier_str_mv PESSANHA, K?nia Let?cia Ferreira. Elabora??o e caracteriza??o f?sico-qu?mica de filmes de amido adicionados de a?a? (Euterpe oleracea mart.) liofilizado. 2016. 99 f. Disserta??o (Mestrado em Ci?ncia e Tecnologia de Alimentos). Instituto de Tecnologia, Departamento de Alimentos, Universidade Federal Rural do Rio de Janeiro, Serop?dica, RJ,
url https://tede.ufrrj.br/jspui/handle/jspui/1868
dc.language.iso.fl_str_mv por
language por
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal Rural do Rio de Janeiro
dc.publisher.program.fl_str_mv Programa de P?s-Gradua??o em Ci?ncia e Tecnologia de Alimentos
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