Separa??o e purifica??o de compostos de antocianina a partir do res?duo da fermenta??o de casca da uva variedade Alicante Bouschet utilizando resinas macroporosas

Detalhes bibliográficos
Ano de defesa: 2019
Autor(a) principal: Mohammad, Siraj Salman
Orientador(a): Barbosa Junior, Jos? Lucena
Banca de defesa: Barbosa Junior, Jos? Lucena, Vicente, Juarez, Rodrigues, Nath?lia da Rocha
Tipo de documento: Dissertação
Tipo de acesso: Acesso aberto
Idioma: por
Instituição de defesa: Universidade Federal Rural do Rio de Janeiro
Programa de Pós-Graduação: Programa de P?s-Gradua??o em Ci?ncia e Tecnologia de Alimentos
Departamento: Instituto de Tecnologia
País: Brasil
Palavras-chave em Português:
purifica??o
polifen?is
extra??o
antioxidante
Palavras-chave em Inglês:
purification
polyphenol
extraction
antioxidant
Área do conhecimento CNPq:
Ci?ncia e Tecnologia de Alimentos
Link de acesso: https://tede.ufrrj.br/jspui/handle/jspui/5509
Resumo: Grapes are one of the most commonly produced fruit crops in the world. Consequently, the grape industry produces large quantities of grape pomace which is a rich source of health promoting polyphenols such as proanthocyanidins, flavones and flavan-3-ols, in this context, there are many types of adsorbents available, but macroporous resins are reported to be the most efficient for polyphenol recovery because of its characteristics like low cost, high recuperative capacity and long term-validity. Therefore; in this study, the raw material used was the residue from grape fermentation of Alicante Bouschet from the production of red wine, (1 g) of dry GP was weighed and extracted with 12.5 mL of 50% water and 50% ethanol, the residue was extracted again by the same volume of solution, the adsorption/desorption characteristics of grape wine peel pomace (GWPP) anthocyanins on six types of macroporous resins (XAD 2, XAD 4, XAD 7HP, XAD 8, XAD 11 and XAD 16 were investigated. On basis of static adsorption test, XAD-7HP and DAX 8 showed higher adsorption/desorption capacities. The adsorption mechanism indicated that the process was better explained by pseudo-first-order kinetics and the Langmuir isotherm model. Adsorption isotherm tests showed that the adsorption process was exothermic on XAD 7HP and DAX 8 when performed at 30? C, 40 ?C and 50 ?C. The results of antioxidant tests indicate that purified anthocyanin extract showed high antioxidant capacity in the both methods of FRAP and DPPH Regarding to high-performance liquid chromatography analysis, acylated Peonidin, Peonidin-3-glucoside, acylated malvidin and malvidine-3-glucoside are the four main anthocyanin compounds in the initial and purified extract of GWPP. Overall, macroporous resins can be an effective tool to purificate anthocyanin instead of using organic solvents and supply pharmaceutical and food industry with safe and cheap process.
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spelling Barbosa Junior, Jos? LucenaCPF: 043.024.047-36Barbosa Junior, Jos? LucenaVicente, JuarezRodrigues, Nath?lia da RochaCPF: 064.339.277-77Mohammad, Siraj Salman2022-03-31T23:20:12Z2019-08-02MOHAMMAD, Siraj Salman. Separa??o e purifica??o de compostos de antocianina a partir do res?duo da fermenta??o de casca da uva variedade Alicante Bouschet utilizando resinas macroporosas. 2019. Disserta??o (Mestrado em Ci?ncia e Tecnologia de Alimentos) - Instituto de Tecnologia, Departamento de Tecnologia de Alimentos, Universidade Federal Rural do Rio de Janeiro, Serop?dica, 2019.https://tede.ufrrj.br/jspui/handle/jspui/5509Grapes are one of the most commonly produced fruit crops in the world. Consequently, the grape industry produces large quantities of grape pomace which is a rich source of health promoting polyphenols such as proanthocyanidins, flavones and flavan-3-ols, in this context, there are many types of adsorbents available, but macroporous resins are reported to be the most efficient for polyphenol recovery because of its characteristics like low cost, high recuperative capacity and long term-validity. Therefore; in this study, the raw material used was the residue from grape fermentation of Alicante Bouschet from the production of red wine, (1 g) of dry GP was weighed and extracted with 12.5 mL of 50% water and 50% ethanol, the residue was extracted again by the same volume of solution, the adsorption/desorption characteristics of grape wine peel pomace (GWPP) anthocyanins on six types of macroporous resins (XAD 2, XAD 4, XAD 7HP, XAD 8, XAD 11 and XAD 16 were investigated. On basis of static adsorption test, XAD-7HP and DAX 8 showed higher adsorption/desorption capacities. The adsorption mechanism indicated that the process was better explained by pseudo-first-order kinetics and the Langmuir isotherm model. Adsorption isotherm tests showed that the adsorption process was exothermic on XAD 7HP and DAX 8 when performed at 30? C, 40 ?C and 50 ?C. The results of antioxidant tests indicate that purified anthocyanin extract showed high antioxidant capacity in the both methods of FRAP and DPPH Regarding to high-performance liquid chromatography analysis, acylated Peonidin, Peonidin-3-glucoside, acylated malvidin and malvidine-3-glucoside are the four main anthocyanin compounds in the initial and purified extract of GWPP. Overall, macroporous resins can be an effective tool to purificate anthocyanin instead of using organic solvents and supply pharmaceutical and food industry with safe and cheap process.As uvas s?o uma das culturas frut?feras mais comumente produzidas no mundo. Consequentemente, a ind?stria da uva produz grandes quantidades de baga?o, que ? uma fonte rica em polifen?is que promovem a sa?de, como proantocianidinas, flavonas e flavan-3-ols. Neste contexto, existem muitos tipos de adsorventes dispon?veis, como as resinas macroporosas (MARs), as quais s?o relatadas como sendo mais eficiente para a recupera??o de polifen?is devido ?s suas caracter?sticas e por apresentarem baixo custo, alta capacidade de recupera??o e longo prazo de validade. Portanto, neste estudo, a mat?ria prima utilizada foi o res?duo da fermenta??o de casca de uva Alicante Bouschet da produ??o de vinho tinto, (1 g) de baga?o de uva seco foi pesado e extra?do com 12,5 mL de 50% de ?gua e 50% de etanol, o res?duo foi extra?do novamente pelo mesmo volume de solu??o, as caracter?sticas de adsor??o desor??o de antocianinas de res?duo da fermenta??o de casca da uva Alicante Bouschet (RFCU) em seis tipos de resinas macroporosas (XAD 2, XAD 4, XAD 7HP, XAD 8, XAD 11 e XAD 16) foram investigadas. Nos testes de adsor??o est?ticos, XAD 7HP e DAX 8 apresentaram os melhores desempenhos para a antocianina total (AT). Os estudos das isotermas indicaram que o mecanismo de adsor??o foi melhor explicado pelo modelo de isoterma de Langmuir. Por sua vez, as cin?ticas de adsor??o foram melhor explicados pelo modelo de pseudo-segunda ordem. O processo de adsor??o utilizando as resinas XAD 7HP e DAX 8 foram isot?rmicos nas temperaturas avaliadas (30 ?C, 40 ?C e 50 ?C). Os extratos purificados apresentaram alta capacidade antioxidante acessadas pelos m?todos FRAP e DPPH. Em rela??o ? an?lise por cromatografia l?quida de alta efici?ncia (CLAE), Peonidina, Peonidina-3-glicos?deo acilada, malvidina acilada e malvidina-3-glicos?deo foram os quatro principais compostos antoci?nicos tanto no extrato inicial quanto no purificado. No geral, as resinas macroporosas demonstraram potencial como alternativa na purifica??o e separa??o de antocianinas de res?duo de vin?colas, ao uso solventes org?nicos.Submitted by Jorge Silva (jorgelmsilva@ufrrj.br) on 2022-03-31T23:20:12Z No. of bitstreams: 1 2019 - Siraj Salman Mohammad.pdf: 1202962 bytes, checksum: 2ac4f48abf05ea32f269c1b12f7f022b (MD5)Made available in DSpace on 2022-03-31T23:20:12Z (GMT). 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dc.title.por.fl_str_mv Separa??o e purifica??o de compostos de antocianina a partir do res?duo da fermenta??o de casca da uva variedade Alicante Bouschet utilizando resinas macroporosas
dc.title.alternative.eng.fl_str_mv Separation and purification of anthocyanin compounds from grape wine pele pomace (Alicante Bouschet) using macroporous resin
title Separa??o e purifica??o de compostos de antocianina a partir do res?duo da fermenta??o de casca da uva variedade Alicante Bouschet utilizando resinas macroporosas
spellingShingle Separa??o e purifica??o de compostos de antocianina a partir do res?duo da fermenta??o de casca da uva variedade Alicante Bouschet utilizando resinas macroporosas
Mohammad, Siraj Salman
purifica??o
polifen?is
extra??o
antioxidante
purification
polyphenol
extraction
antioxidant
Ci?ncia e Tecnologia de Alimentos
title_short Separa??o e purifica??o de compostos de antocianina a partir do res?duo da fermenta??o de casca da uva variedade Alicante Bouschet utilizando resinas macroporosas
title_full Separa??o e purifica??o de compostos de antocianina a partir do res?duo da fermenta??o de casca da uva variedade Alicante Bouschet utilizando resinas macroporosas
title_fullStr Separa??o e purifica??o de compostos de antocianina a partir do res?duo da fermenta??o de casca da uva variedade Alicante Bouschet utilizando resinas macroporosas
title_full_unstemmed Separa??o e purifica??o de compostos de antocianina a partir do res?duo da fermenta??o de casca da uva variedade Alicante Bouschet utilizando resinas macroporosas
title_sort Separa??o e purifica??o de compostos de antocianina a partir do res?duo da fermenta??o de casca da uva variedade Alicante Bouschet utilizando resinas macroporosas
author Mohammad, Siraj Salman
author_facet Mohammad, Siraj Salman
author_role author
dc.contributor.advisor1.fl_str_mv Barbosa Junior, Jos? Lucena
dc.contributor.advisor1ID.fl_str_mv CPF: 043.024.047-36
dc.contributor.referee1.fl_str_mv Barbosa Junior, Jos? Lucena
dc.contributor.referee2.fl_str_mv Vicente, Juarez
dc.contributor.referee3.fl_str_mv Rodrigues, Nath?lia da Rocha
dc.contributor.authorID.fl_str_mv CPF: 064.339.277-77
dc.contributor.author.fl_str_mv Mohammad, Siraj Salman
contributor_str_mv Barbosa Junior, Jos? Lucena
Barbosa Junior, Jos? Lucena
Vicente, Juarez
Rodrigues, Nath?lia da Rocha
dc.subject.por.fl_str_mv purifica??o
polifen?is
extra??o
antioxidante
topic purifica??o
polifen?is
extra??o
antioxidante
purification
polyphenol
extraction
antioxidant
Ci?ncia e Tecnologia de Alimentos
dc.subject.eng.fl_str_mv purification
polyphenol
extraction
antioxidant
dc.subject.cnpq.fl_str_mv Ci?ncia e Tecnologia de Alimentos
description Grapes are one of the most commonly produced fruit crops in the world. Consequently, the grape industry produces large quantities of grape pomace which is a rich source of health promoting polyphenols such as proanthocyanidins, flavones and flavan-3-ols, in this context, there are many types of adsorbents available, but macroporous resins are reported to be the most efficient for polyphenol recovery because of its characteristics like low cost, high recuperative capacity and long term-validity. Therefore; in this study, the raw material used was the residue from grape fermentation of Alicante Bouschet from the production of red wine, (1 g) of dry GP was weighed and extracted with 12.5 mL of 50% water and 50% ethanol, the residue was extracted again by the same volume of solution, the adsorption/desorption characteristics of grape wine peel pomace (GWPP) anthocyanins on six types of macroporous resins (XAD 2, XAD 4, XAD 7HP, XAD 8, XAD 11 and XAD 16 were investigated. On basis of static adsorption test, XAD-7HP and DAX 8 showed higher adsorption/desorption capacities. The adsorption mechanism indicated that the process was better explained by pseudo-first-order kinetics and the Langmuir isotherm model. Adsorption isotherm tests showed that the adsorption process was exothermic on XAD 7HP and DAX 8 when performed at 30? C, 40 ?C and 50 ?C. The results of antioxidant tests indicate that purified anthocyanin extract showed high antioxidant capacity in the both methods of FRAP and DPPH Regarding to high-performance liquid chromatography analysis, acylated Peonidin, Peonidin-3-glucoside, acylated malvidin and malvidine-3-glucoside are the four main anthocyanin compounds in the initial and purified extract of GWPP. Overall, macroporous resins can be an effective tool to purificate anthocyanin instead of using organic solvents and supply pharmaceutical and food industry with safe and cheap process.
publishDate 2019
dc.date.issued.fl_str_mv 2019-08-02
dc.date.accessioned.fl_str_mv 2022-03-31T23:20:12Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/masterThesis
format masterThesis
status_str publishedVersion
dc.identifier.citation.fl_str_mv MOHAMMAD, Siraj Salman. Separa??o e purifica??o de compostos de antocianina a partir do res?duo da fermenta??o de casca da uva variedade Alicante Bouschet utilizando resinas macroporosas. 2019. Disserta??o (Mestrado em Ci?ncia e Tecnologia de Alimentos) - Instituto de Tecnologia, Departamento de Tecnologia de Alimentos, Universidade Federal Rural do Rio de Janeiro, Serop?dica, 2019.
dc.identifier.uri.fl_str_mv https://tede.ufrrj.br/jspui/handle/jspui/5509
identifier_str_mv MOHAMMAD, Siraj Salman. Separa??o e purifica??o de compostos de antocianina a partir do res?duo da fermenta??o de casca da uva variedade Alicante Bouschet utilizando resinas macroporosas. 2019. Disserta??o (Mestrado em Ci?ncia e Tecnologia de Alimentos) - Instituto de Tecnologia, Departamento de Tecnologia de Alimentos, Universidade Federal Rural do Rio de Janeiro, Serop?dica, 2019.
url https://tede.ufrrj.br/jspui/handle/jspui/5509
dc.language.iso.fl_str_mv por
language por
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