Interação entre líquidos iônicos imidazolíneos e os alginatos de sódio e hidroxâmico
Ano de defesa: | 2019 |
---|---|
Autor(a) principal: | |
Orientador(a): | |
Banca de defesa: | , , , |
Tipo de documento: | Tese |
Tipo de acesso: | Acesso aberto |
Idioma: | por |
Instituição de defesa: |
Universidade Federal de Santa Maria
Centro de Ciências Naturais e Exatas |
Programa de Pós-Graduação: |
Programa de Pós-Graduação em Química
|
Departamento: |
Química
|
País: |
Brasil
|
Palavras-chave em Português: | |
Palavras-chave em Inglês: | |
Área do conhecimento CNPq: | |
Link de acesso: | http://repositorio.ufsm.br/handle/1/17546 |
Resumo: | This work describes the interactions between sodium alginate (ALG) and hydroxamic alginate (AHX) with the monocationic imidazolium ionic liquids series (CnMIMBr). From the surface tension, electrical conductivity, isothermal titration calorimetry (ITC), surface plasmon resonance (SPR), zeta potential, rheology and atomic force microscopy (AFM) techniques, we evaluated the effect of the alkyl chain length (n = 10, 12, 14 and 16), the concentration of the ILs and the polyelectrolytes, the charge density of the polyelectrolytes, on the formation of complexes AHX/CnMIMBr and ALG/CnMIMBr. The critical aggregation concentrations (C1, C2, CS and Cm) and the thermodynamic parameters of micellization and aggregation were calculated by these techniques. It was observed that the interactions with AHX are favored by the increase in the alkyl chain length of IL, whereas the interactions with ALG were more favorable with the more hydrophilic ionic liquids. The increase in the concentration of polyelectrolytes disadvantage the formation of free micelles of ILs as consequence of their aggregation in the chains of AHX and ALG. From the different techniques, the aggregation processes were determined in different concentrations of CnMIMBr. At low concentrations, electrostatic interactions are predominant and, when the concentration of ILs is increased, hydrophobic and ion-dipole interactions become more pronounced. By dividing the aggregation processes into different IL concentration ranges, it was possible to experimentally determine several thermodynamic parameters of the interaction and micellization processes. The hydrophobic interaction is discussed in detail, in particular by the Kagg2 equilibrium constant, related to cooperative aggregation processes. The morphology of the AHX/CnMIMBr and ALG/CnMIMBr were determined by AFM technique and the size of the aggregates, morphology, topology, hardness, Young's modulus, deformation, adhesion, roughness and electrostatic potential were determined. These studies show that blends of polylelectrolytes with LIs present potential applications in different areas of chemistry, medicine and materials science. |
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2019-07-24T14:30:39Z2019-07-24T14:30:39Z2019-01-30http://repositorio.ufsm.br/handle/1/17546This work describes the interactions between sodium alginate (ALG) and hydroxamic alginate (AHX) with the monocationic imidazolium ionic liquids series (CnMIMBr). From the surface tension, electrical conductivity, isothermal titration calorimetry (ITC), surface plasmon resonance (SPR), zeta potential, rheology and atomic force microscopy (AFM) techniques, we evaluated the effect of the alkyl chain length (n = 10, 12, 14 and 16), the concentration of the ILs and the polyelectrolytes, the charge density of the polyelectrolytes, on the formation of complexes AHX/CnMIMBr and ALG/CnMIMBr. The critical aggregation concentrations (C1, C2, CS and Cm) and the thermodynamic parameters of micellization and aggregation were calculated by these techniques. It was observed that the interactions with AHX are favored by the increase in the alkyl chain length of IL, whereas the interactions with ALG were more favorable with the more hydrophilic ionic liquids. The increase in the concentration of polyelectrolytes disadvantage the formation of free micelles of ILs as consequence of their aggregation in the chains of AHX and ALG. From the different techniques, the aggregation processes were determined in different concentrations of CnMIMBr. At low concentrations, electrostatic interactions are predominant and, when the concentration of ILs is increased, hydrophobic and ion-dipole interactions become more pronounced. By dividing the aggregation processes into different IL concentration ranges, it was possible to experimentally determine several thermodynamic parameters of the interaction and micellization processes. The hydrophobic interaction is discussed in detail, in particular by the Kagg2 equilibrium constant, related to cooperative aggregation processes. The morphology of the AHX/CnMIMBr and ALG/CnMIMBr were determined by AFM technique and the size of the aggregates, morphology, topology, hardness, Young's modulus, deformation, adhesion, roughness and electrostatic potential were determined. These studies show that blends of polylelectrolytes with LIs present potential applications in different areas of chemistry, medicine and materials science.Este trabalho descreve as interações entre o alginato de sódio (ALG) e o alginato hidroxâmico (AHX) com a série de líquidos iônicos (LIs) imidazolíneos monocatiônicos (CnMIMBr). A partir das técnicas de tensão superficial, condutividade elétrica, titulação calorimétrica isotérmica (ITC), ressonância plasmônica de superfície (SPR), potencial zeta, reologia e microscopia de força atômica (AFM), se avaliou o efeito do comprimento da cadeia alquílica (n = 10, 12, 14 e 16), da concentração dos LIs e dos polieletrólitos, da densidade de carga dos polieletrólitos, sobre a formação de complexos AHX/CnMIMBr e ALG/CnMIMBr. Foram calculadas por essas técnicas as concentrações de agregação críticas (C1, C2, CS e Cm) e os parâmetros termodinâmicos de micelização e agregação. Observou-se que as interações com AHX são favorecidas com o aumento do comprimento da cadeia alquílica do LI, enquanto que as interações com o ALG foram mais favoráveis com os líquidos iônicos mais hidrofílicos. O aumento na concentração de polieletrólitos desfavorece a formação de micelas livres de LIs em função de sua agregação nas cadeias de AHX e ALG. A partir das diferentes técnicas, se determinou os processos de agregação em diferentes concentrações de CnMIMBr. Em baixas concentrações, as interações eletrostáticas são predominantes e, quando se aumenta a concentração dos LIs, interações hidrofóbicas e do tipo íon-dipolo passam a ser mais pronunciadas. Pela divisão dos processos de agregação em diferentes faixas de concentração de LI, foi possível determinar experimentalmente vários parâmetros termodinâmicos dos processos de interação e micelização. A interação hidrofóbica é discutida em detalhe, em especial pela constante de equilíbrio Kagg2, relacionada aos processos cooperativos de agregação. Pela técnica de AFM avaliou-se a morfologia das superfícies de AHX/CnMIMBr e ALG/CnMIMBr e determinou-se o tamanho dos agregados, morfologia, topologia, dureza, módulo de Young, deformação, adesão, rugosidade e potencial eletrostático. Esses estudos mostram que as misturas de polieletrólitos com LIs apresentam potenciais aplicações em diferentes áreas da química, medicina e ciência dos materiais.Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPESporUniversidade Federal de Santa MariaCentro de Ciências Naturais e ExatasPrograma de Pós-Graduação em QuímicaUFSMBrasilQuímicaAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessAlginato hidroxâmicoLíquidos iônicos imidazolíneosTensão superficialCondutividade elétricaTitulação calorimétrica isotérmicaRessonância plasmônica de superfícieProcessos de agregaçãoHydroxamic alginateImidazolium ionic liquidsSurface tensionElectrical conductivityIsothermal titration calorimetrySurface plasmon resonanceAggregation processesCNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICAInteração entre líquidos iônicos imidazolíneos e os alginatos de sódio e hidroxâmicoInteraction between imidazolium ionic liquids with sodium and hydroxamic alginatesinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesisVilletti, Marcos Antoniohttp://lattes.cnpq.br/8504489050993642Frizzo, Clarissa Piccininhttp://lattes.cnpq.br/0029279904716491Kloster, Carmen Luisahttp://lattes.cnpq.br/3218958424322612Garcia, Irene Teresinha Santoshttp://lattes.cnpq.br/2296402907146130Baierle, Rogério Joséhttp://lattes.cnpq.br/7565203547830128Vendrame, Zilda Barattohttp://lattes.cnpq.br/4900675368665056http://lattes.cnpq.br/1183745711715261Freitas, Darcson Vieira de100600000000600606f8835-e936-4079-89b9-60e12681def40f360a87-001a-4aff-a1b1-b19c5736d5af34c6d2e6-1cc5-4638-a14a-6ba61387c7d80534d4d2-1e98-446f-9b07-ce24ea5c8e52eac5d940-ee23-4a12-9898-34396e823d36bbc1fe65-2bf5-4f96-9f37-ec61001b640b4889749d-cbe7-414e-853b-dfdd53d36938reponame:Manancial - Repositório Digital da UFSMinstname:Universidade Federal de Santa Maria (UFSM)instacron:UFSMORIGINALTES_PPGQUIMICA_2019_FREITAS DARCSON.pdfTES_PPGQUIMICA_2019_FREITAS DARCSON.pdfTese de Doutoradoapplication/pdf8927286http://repositorio.ufsm.br/bitstream/1/17546/1/TES_PPGQUIMICA_2019_FREITAS%20DARCSON.pdf76da0825242175485fd310be8035b5a7MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; 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dc.title.por.fl_str_mv |
Interação entre líquidos iônicos imidazolíneos e os alginatos de sódio e hidroxâmico |
dc.title.alternative.eng.fl_str_mv |
Interaction between imidazolium ionic liquids with sodium and hydroxamic alginates |
title |
Interação entre líquidos iônicos imidazolíneos e os alginatos de sódio e hidroxâmico |
spellingShingle |
Interação entre líquidos iônicos imidazolíneos e os alginatos de sódio e hidroxâmico Freitas, Darcson Vieira de Alginato hidroxâmico Líquidos iônicos imidazolíneos Tensão superficial Condutividade elétrica Titulação calorimétrica isotérmica Ressonância plasmônica de superfície Processos de agregação Hydroxamic alginate Imidazolium ionic liquids Surface tension Electrical conductivity Isothermal titration calorimetry Surface plasmon resonance Aggregation processes CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA |
title_short |
Interação entre líquidos iônicos imidazolíneos e os alginatos de sódio e hidroxâmico |
title_full |
Interação entre líquidos iônicos imidazolíneos e os alginatos de sódio e hidroxâmico |
title_fullStr |
Interação entre líquidos iônicos imidazolíneos e os alginatos de sódio e hidroxâmico |
title_full_unstemmed |
Interação entre líquidos iônicos imidazolíneos e os alginatos de sódio e hidroxâmico |
title_sort |
Interação entre líquidos iônicos imidazolíneos e os alginatos de sódio e hidroxâmico |
author |
Freitas, Darcson Vieira de |
author_facet |
Freitas, Darcson Vieira de |
author_role |
author |
dc.contributor.advisor1.fl_str_mv |
Villetti, Marcos Antonio |
dc.contributor.advisor1Lattes.fl_str_mv |
http://lattes.cnpq.br/8504489050993642 |
dc.contributor.advisor-co1.fl_str_mv |
Frizzo, Clarissa Piccinin |
dc.contributor.advisor-co1Lattes.fl_str_mv |
http://lattes.cnpq.br/0029279904716491 |
dc.contributor.referee1.fl_str_mv |
Kloster, Carmen Luisa |
dc.contributor.referee1Lattes.fl_str_mv |
http://lattes.cnpq.br/3218958424322612 |
dc.contributor.referee2.fl_str_mv |
Garcia, Irene Teresinha Santos |
dc.contributor.referee2Lattes.fl_str_mv |
http://lattes.cnpq.br/2296402907146130 |
dc.contributor.referee3.fl_str_mv |
Baierle, Rogério José |
dc.contributor.referee3Lattes.fl_str_mv |
http://lattes.cnpq.br/7565203547830128 |
dc.contributor.referee4.fl_str_mv |
Vendrame, Zilda Baratto |
dc.contributor.referee4Lattes.fl_str_mv |
http://lattes.cnpq.br/4900675368665056 |
dc.contributor.authorLattes.fl_str_mv |
http://lattes.cnpq.br/1183745711715261 |
dc.contributor.author.fl_str_mv |
Freitas, Darcson Vieira de |
contributor_str_mv |
Villetti, Marcos Antonio Frizzo, Clarissa Piccinin Kloster, Carmen Luisa Garcia, Irene Teresinha Santos Baierle, Rogério José Vendrame, Zilda Baratto |
dc.subject.por.fl_str_mv |
Alginato hidroxâmico Líquidos iônicos imidazolíneos Tensão superficial Condutividade elétrica Titulação calorimétrica isotérmica Ressonância plasmônica de superfície Processos de agregação |
topic |
Alginato hidroxâmico Líquidos iônicos imidazolíneos Tensão superficial Condutividade elétrica Titulação calorimétrica isotérmica Ressonância plasmônica de superfície Processos de agregação Hydroxamic alginate Imidazolium ionic liquids Surface tension Electrical conductivity Isothermal titration calorimetry Surface plasmon resonance Aggregation processes CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA |
dc.subject.eng.fl_str_mv |
Hydroxamic alginate Imidazolium ionic liquids Surface tension Electrical conductivity Isothermal titration calorimetry Surface plasmon resonance Aggregation processes |
dc.subject.cnpq.fl_str_mv |
CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA |
description |
This work describes the interactions between sodium alginate (ALG) and hydroxamic alginate (AHX) with the monocationic imidazolium ionic liquids series (CnMIMBr). From the surface tension, electrical conductivity, isothermal titration calorimetry (ITC), surface plasmon resonance (SPR), zeta potential, rheology and atomic force microscopy (AFM) techniques, we evaluated the effect of the alkyl chain length (n = 10, 12, 14 and 16), the concentration of the ILs and the polyelectrolytes, the charge density of the polyelectrolytes, on the formation of complexes AHX/CnMIMBr and ALG/CnMIMBr. The critical aggregation concentrations (C1, C2, CS and Cm) and the thermodynamic parameters of micellization and aggregation were calculated by these techniques. It was observed that the interactions with AHX are favored by the increase in the alkyl chain length of IL, whereas the interactions with ALG were more favorable with the more hydrophilic ionic liquids. The increase in the concentration of polyelectrolytes disadvantage the formation of free micelles of ILs as consequence of their aggregation in the chains of AHX and ALG. From the different techniques, the aggregation processes were determined in different concentrations of CnMIMBr. At low concentrations, electrostatic interactions are predominant and, when the concentration of ILs is increased, hydrophobic and ion-dipole interactions become more pronounced. By dividing the aggregation processes into different IL concentration ranges, it was possible to experimentally determine several thermodynamic parameters of the interaction and micellization processes. The hydrophobic interaction is discussed in detail, in particular by the Kagg2 equilibrium constant, related to cooperative aggregation processes. The morphology of the AHX/CnMIMBr and ALG/CnMIMBr were determined by AFM technique and the size of the aggregates, morphology, topology, hardness, Young's modulus, deformation, adhesion, roughness and electrostatic potential were determined. These studies show that blends of polylelectrolytes with LIs present potential applications in different areas of chemistry, medicine and materials science. |
publishDate |
2019 |
dc.date.accessioned.fl_str_mv |
2019-07-24T14:30:39Z |
dc.date.available.fl_str_mv |
2019-07-24T14:30:39Z |
dc.date.issued.fl_str_mv |
2019-01-30 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/doctoralThesis |
format |
doctoralThesis |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://repositorio.ufsm.br/handle/1/17546 |
url |
http://repositorio.ufsm.br/handle/1/17546 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.cnpq.fl_str_mv |
100600000000 |
dc.relation.confidence.fl_str_mv |
600 |
dc.relation.authority.fl_str_mv |
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dc.rights.driver.fl_str_mv |
Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ |
eu_rights_str_mv |
openAccess |
dc.publisher.none.fl_str_mv |
Universidade Federal de Santa Maria Centro de Ciências Naturais e Exatas |
dc.publisher.program.fl_str_mv |
Programa de Pós-Graduação em Química |
dc.publisher.initials.fl_str_mv |
UFSM |
dc.publisher.country.fl_str_mv |
Brasil |
dc.publisher.department.fl_str_mv |
Química |
publisher.none.fl_str_mv |
Universidade Federal de Santa Maria Centro de Ciências Naturais e Exatas |
dc.source.none.fl_str_mv |
reponame:Manancial - Repositório Digital da UFSM instname:Universidade Federal de Santa Maria (UFSM) instacron:UFSM |
instname_str |
Universidade Federal de Santa Maria (UFSM) |
instacron_str |
UFSM |
institution |
UFSM |
reponame_str |
Manancial - Repositório Digital da UFSM |
collection |
Manancial - Repositório Digital da UFSM |
bitstream.url.fl_str_mv |
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