Estudo da hidrólise do óleo de soja catalizada pela enzima lipozyme TL IM
Ano de defesa: | 2017 |
---|---|
Autor(a) principal: | |
Orientador(a): | |
Banca de defesa: | , |
Tipo de documento: | Dissertação |
Tipo de acesso: | Acesso aberto |
Idioma: | por |
Instituição de defesa: |
Universidade Estadual do Oeste do Paraná
Toledo |
Programa de Pós-Graduação: |
Programa de Pós-Graduação em Bioenergia
|
Departamento: |
Centro de Engenharias e Ciências Exatas
|
País: |
Brasil
|
Palavras-chave em Português: | |
Palavras-chave em Inglês: | |
Área do conhecimento CNPq: | |
Link de acesso: | http://tede.unioeste.br:8080/tede/handle/tede/2898 |
Resumo: | The utilization of biodiesel as a substitute for diesel oil is one of the alternatives that aims to minimize the utilization of non-renewable fuels (petroleum) in the world energy matrix. Worldwide, biodiesel production occurs through the transesterification process. In Brazil, the most commonly used raw material for this purpose is soybean oil. A new way that has been promising for the biodiesel production is the Hidroesterification process. With that, the present work a imed to evaluate the soy oil enzymatic hydrolysis, using the comercial enzyme Lipozyme TL IM as the catalyst of the reaction. Was performed hydrolysis test of soy oil in closed and batch system, based on two experimental plannings (Placket-Burmann ad DCCR), to evaluate the effects of the variables involved in the process(pH; temperature; molar fraction water/oil; stirrings peed of the batch reactor and mass fraction enzyme/substrate). Since that, was perfomed kinetic studies with different conditions of molar fraction water/oil and different dosages of catalyst, as well as the utilization of a tip ultrasonic and a chemical agent to evaluateit’s effects on the kinetic of the reaction. To describe the kinetic of enzymatic hydrolysis of soy oil, was used a mathematical model based on the Michaelis-Menten kinetic. The results of experimental planningsindicatedthattheaciditylevelswerefavoredwhenthetemperatureof 52,2ºC, pH 6.1, stirring speed 150 rpm and molar fraction water/oil 37,7:1, getting 82,4% in the value of acidity level. The kinetic studies showed that the utilization of the probe ultrasonic did not accelerated the velocity of the enzymatic hydrolysis reaction. The kinetic involving the utilization of the chemical agent suffered a high decrease in the velocity of reaction, showing that this would be a inhibitor of enzymatic activity of Lipozyme TL IM. By the mathematical model, was verified that the model described well the experimental datas, as well made able the visualization of others components concentration (triacylglycerols, diacylglycerols, monoacylglycerols, glycerol, free fatty acids and water). It is believed that the values of the constants of the reaction velocity obtained in the model has more physical meaning and could be used to conducting the simulations in anothers conditions. |
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Borba, Carlos Eduardohttp://lattes.cnpq.br/0750048720229101Rodrigues, Maria Luiza Fernandeshttp://lattes.cnpq.br/5773105347762056Dragunski, Douglas Cardosohttp://lattes.cnpq.br/0612112281360342Baumgärtner, Tatiana Rodrigues da Silvahttp://lattes.cnpq.br/4685833009997780http://lattes.cnpq.br/6554844603606164Focking, Andriele Magarinos2017-08-11T14:43:57Z2017-03-09FOCKING, Andriele Magarinos. Estudo da hidrólise do óleo de soja catalizada pela enzima lipozyme TL IM. 2017. 103 f.. Dissertação ( Mestrado em Bioenergia) - Universidade Estadual do Oeste do Paraná, Toledo, 2017 .http://tede.unioeste.br:8080/tede/handle/tede/2898The utilization of biodiesel as a substitute for diesel oil is one of the alternatives that aims to minimize the utilization of non-renewable fuels (petroleum) in the world energy matrix. Worldwide, biodiesel production occurs through the transesterification process. In Brazil, the most commonly used raw material for this purpose is soybean oil. A new way that has been promising for the biodiesel production is the Hidroesterification process. With that, the present work a imed to evaluate the soy oil enzymatic hydrolysis, using the comercial enzyme Lipozyme TL IM as the catalyst of the reaction. Was performed hydrolysis test of soy oil in closed and batch system, based on two experimental plannings (Placket-Burmann ad DCCR), to evaluate the effects of the variables involved in the process(pH; temperature; molar fraction water/oil; stirrings peed of the batch reactor and mass fraction enzyme/substrate). Since that, was perfomed kinetic studies with different conditions of molar fraction water/oil and different dosages of catalyst, as well as the utilization of a tip ultrasonic and a chemical agent to evaluateit’s effects on the kinetic of the reaction. To describe the kinetic of enzymatic hydrolysis of soy oil, was used a mathematical model based on the Michaelis-Menten kinetic. The results of experimental planningsindicatedthattheaciditylevelswerefavoredwhenthetemperatureof 52,2ºC, pH 6.1, stirring speed 150 rpm and molar fraction water/oil 37,7:1, getting 82,4% in the value of acidity level. The kinetic studies showed that the utilization of the probe ultrasonic did not accelerated the velocity of the enzymatic hydrolysis reaction. The kinetic involving the utilization of the chemical agent suffered a high decrease in the velocity of reaction, showing that this would be a inhibitor of enzymatic activity of Lipozyme TL IM. By the mathematical model, was verified that the model described well the experimental datas, as well made able the visualization of others components concentration (triacylglycerols, diacylglycerols, monoacylglycerols, glycerol, free fatty acids and water). It is believed that the values of the constants of the reaction velocity obtained in the model has more physical meaning and could be used to conducting the simulations in anothers conditions.A utilização do biodiesel como substituto do óleo diesel é uma das alternativas que visa minimizar a utilização de combustíveis não renováveis (petróleo) na matriz energética mundial.Mundialmente, a produção de biodiesel ocorre pelo processo de transesterificação. No Brasil, a matéria-prima mais utilizada para esta finalidade é o óleo de soja. Uma nova rota que se mostra promissora para a produção de biodiesel é o processo de hidroesterificação. Desta maneira, o presente trabalho objetivou avaliar a hidrólise enzimática do óleo de soja, utilizando a enzima comercial Lipozyme TL IM como catalisador da reação. Foram realizados ensaios de hidrólise do óleo de soja em sistema fechado e batelada, baseados em dois planejamentos experimentais (Placket-Burmann e DCCR), visando avaliar os efeitos das variáveis envolvidas no processo (pH; temperatura; razão molar água/óleo; velocidade de agitação no reator batelada e razão mássica enzima/substrato). A partir disto, foram realizados estudos cinéticos com diferentes condições de razão molar água/óleo e diferentes dosagens de catalisador, bem como a utilização de ultrassom de ponta e um agente químico visando avaliar seus efeitos na cinética da reação. Para descrever a cinética da hidrólise enzimática do óleo de soja foi utilizado um modelo matemático baseado na cinética de Michaelis-Menten. Os resultados dos planejamentos experimentais indicaram que o índice de acidez foi favorecido quando temperatura de 52,2ºC, pH 6,1, velocidade de agitação de 150 rpm e razão molar água/óleo 37,7:1, obtendo 82,4% no valor do índice de acidez. Os estudos cinéticos demonstraram que a utilização do ultrassom de sonda não acelerou a velocidade da reação de hidrólise 13 enzimática. A cinética envolvendo a utilização de agente químico sofreu um alto decaimento na velocidade da reação, demonstrando que este seria um inibidor da atividade enzimática da Lipozyme TL IM. Pela modelagem matemática verificou-se que o modelo descreveu bem os dados experimentais, bem como possibilitou a visualização da concentração dos demais componentes (triacilgliceróis, diacilgliceróis, monoacilgliceróis, glicerol,ácidos graxos livreeágua). Acredita-se que os valores das constantes da velocidade de reação obtidos no modelo tenham maior significado físico e possam ser utilizados para realização de simulações em outras condições.Submitted by Marilene Donadel (marilene.donadel@unioeste.br) on 2017-08-11T14:43:57Z No. of bitstreams: 2 Andriele Magarinos Focking 2017.pdf: 2481446 bytes, checksum: 763f767d058face92edaaa394dc5b780 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5)Made available in DSpace on 2017-08-11T14:43:57Z (GMT). No. of bitstreams: 2 Andriele Magarinos Focking 2017.pdf: 2481446 bytes, checksum: 763f767d058face92edaaa394dc5b780 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) Previous issue date: 2017-03-09Conselho Nacional de Pesquisa e Desenvolvimento Científico e Tecnológico - CNPqapplication/pdfpor-2624803687637593200500Universidade Estadual do Oeste do ParanáToledoPrograma de Pós-Graduação em BioenergiaUNIOESTEBrasilCentro de Engenharias e Ciências Exatashttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessÓleos e gordurasÓleo de sojaÁcidos graxos livresHidrólise enzimáticaEnzima lipozyme TL IMOil and fatsSoy oilFree fatty acidsEnzymatic hydrolysisLipozyme TL IM enzyme.ENGENHARIASEstudo da hidrólise do óleo de soja catalizada pela enzima lipozyme TL IMStudy of hydrolysis of soy oil catalelized by enzima lipozyme TL IMinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesis-6379502553601813940600600600600-77344021240821469224518971056484826825-2555911436985713659reponame:Biblioteca Digital de Teses e Dissertações do UNIOESTEinstname:Universidade Estadual do Oeste do Paraná (UNIOESTE)instacron:UNIOESTEORIGINALAndriele Magarinos Focking 2017.pdfAndriele Magarinos Focking 2017.pdfapplication/pdf2481446http://tede.unioeste.br:8080/tede/bitstream/tede/2898/5/Andriele+Magarinos+Focking+2017.pdf763f767d058face92edaaa394dc5b780MD55CC-LICENSElicense_urllicense_urltext/plain; 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dc.title.por.fl_str_mv |
Estudo da hidrólise do óleo de soja catalizada pela enzima lipozyme TL IM |
dc.title.alternative.eng.fl_str_mv |
Study of hydrolysis of soy oil catalelized by enzima lipozyme TL IM |
title |
Estudo da hidrólise do óleo de soja catalizada pela enzima lipozyme TL IM |
spellingShingle |
Estudo da hidrólise do óleo de soja catalizada pela enzima lipozyme TL IM Focking, Andriele Magarinos Óleos e gorduras Óleo de soja Ácidos graxos livres Hidrólise enzimática Enzima lipozyme TL IM Oil and fats Soy oil Free fatty acids Enzymatic hydrolysis Lipozyme TL IM enzyme. ENGENHARIAS |
title_short |
Estudo da hidrólise do óleo de soja catalizada pela enzima lipozyme TL IM |
title_full |
Estudo da hidrólise do óleo de soja catalizada pela enzima lipozyme TL IM |
title_fullStr |
Estudo da hidrólise do óleo de soja catalizada pela enzima lipozyme TL IM |
title_full_unstemmed |
Estudo da hidrólise do óleo de soja catalizada pela enzima lipozyme TL IM |
title_sort |
Estudo da hidrólise do óleo de soja catalizada pela enzima lipozyme TL IM |
author |
Focking, Andriele Magarinos |
author_facet |
Focking, Andriele Magarinos |
author_role |
author |
dc.contributor.advisor1.fl_str_mv |
Borba, Carlos Eduardo |
dc.contributor.advisor1Lattes.fl_str_mv |
http://lattes.cnpq.br/0750048720229101 |
dc.contributor.advisor-co1.fl_str_mv |
Rodrigues, Maria Luiza Fernandes |
dc.contributor.advisor-co1Lattes.fl_str_mv |
http://lattes.cnpq.br/5773105347762056 |
dc.contributor.referee1.fl_str_mv |
Dragunski, Douglas Cardoso |
dc.contributor.referee1Lattes.fl_str_mv |
http://lattes.cnpq.br/0612112281360342 |
dc.contributor.referee2.fl_str_mv |
Baumgärtner, Tatiana Rodrigues da Silva |
dc.contributor.referee2Lattes.fl_str_mv |
http://lattes.cnpq.br/4685833009997780 |
dc.contributor.authorLattes.fl_str_mv |
http://lattes.cnpq.br/6554844603606164 |
dc.contributor.author.fl_str_mv |
Focking, Andriele Magarinos |
contributor_str_mv |
Borba, Carlos Eduardo Rodrigues, Maria Luiza Fernandes Dragunski, Douglas Cardoso Baumgärtner, Tatiana Rodrigues da Silva |
dc.subject.por.fl_str_mv |
Óleos e gorduras Óleo de soja Ácidos graxos livres Hidrólise enzimática Enzima lipozyme TL IM |
topic |
Óleos e gorduras Óleo de soja Ácidos graxos livres Hidrólise enzimática Enzima lipozyme TL IM Oil and fats Soy oil Free fatty acids Enzymatic hydrolysis Lipozyme TL IM enzyme. ENGENHARIAS |
dc.subject.eng.fl_str_mv |
Oil and fats Soy oil Free fatty acids Enzymatic hydrolysis Lipozyme TL IM enzyme. |
dc.subject.cnpq.fl_str_mv |
ENGENHARIAS |
description |
The utilization of biodiesel as a substitute for diesel oil is one of the alternatives that aims to minimize the utilization of non-renewable fuels (petroleum) in the world energy matrix. Worldwide, biodiesel production occurs through the transesterification process. In Brazil, the most commonly used raw material for this purpose is soybean oil. A new way that has been promising for the biodiesel production is the Hidroesterification process. With that, the present work a imed to evaluate the soy oil enzymatic hydrolysis, using the comercial enzyme Lipozyme TL IM as the catalyst of the reaction. Was performed hydrolysis test of soy oil in closed and batch system, based on two experimental plannings (Placket-Burmann ad DCCR), to evaluate the effects of the variables involved in the process(pH; temperature; molar fraction water/oil; stirrings peed of the batch reactor and mass fraction enzyme/substrate). Since that, was perfomed kinetic studies with different conditions of molar fraction water/oil and different dosages of catalyst, as well as the utilization of a tip ultrasonic and a chemical agent to evaluateit’s effects on the kinetic of the reaction. To describe the kinetic of enzymatic hydrolysis of soy oil, was used a mathematical model based on the Michaelis-Menten kinetic. The results of experimental planningsindicatedthattheaciditylevelswerefavoredwhenthetemperatureof 52,2ºC, pH 6.1, stirring speed 150 rpm and molar fraction water/oil 37,7:1, getting 82,4% in the value of acidity level. The kinetic studies showed that the utilization of the probe ultrasonic did not accelerated the velocity of the enzymatic hydrolysis reaction. The kinetic involving the utilization of the chemical agent suffered a high decrease in the velocity of reaction, showing that this would be a inhibitor of enzymatic activity of Lipozyme TL IM. By the mathematical model, was verified that the model described well the experimental datas, as well made able the visualization of others components concentration (triacylglycerols, diacylglycerols, monoacylglycerols, glycerol, free fatty acids and water). It is believed that the values of the constants of the reaction velocity obtained in the model has more physical meaning and could be used to conducting the simulations in anothers conditions. |
publishDate |
2017 |
dc.date.accessioned.fl_str_mv |
2017-08-11T14:43:57Z |
dc.date.issued.fl_str_mv |
2017-03-09 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/masterThesis |
format |
masterThesis |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
FOCKING, Andriele Magarinos. Estudo da hidrólise do óleo de soja catalizada pela enzima lipozyme TL IM. 2017. 103 f.. Dissertação ( Mestrado em Bioenergia) - Universidade Estadual do Oeste do Paraná, Toledo, 2017 . |
dc.identifier.uri.fl_str_mv |
http://tede.unioeste.br:8080/tede/handle/tede/2898 |
identifier_str_mv |
FOCKING, Andriele Magarinos. Estudo da hidrólise do óleo de soja catalizada pela enzima lipozyme TL IM. 2017. 103 f.. Dissertação ( Mestrado em Bioenergia) - Universidade Estadual do Oeste do Paraná, Toledo, 2017 . |
url |
http://tede.unioeste.br:8080/tede/handle/tede/2898 |
dc.language.iso.fl_str_mv |
por |
language |
por |
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-6379502553601813940 |
dc.relation.confidence.fl_str_mv |
600 600 600 600 |
dc.relation.department.fl_str_mv |
-7734402124082146922 |
dc.relation.cnpq.fl_str_mv |
4518971056484826825 |
dc.relation.sponsorship.fl_str_mv |
-2555911436985713659 |
dc.rights.driver.fl_str_mv |
http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by-nc-nd/4.0/ |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Estadual do Oeste do Paraná Toledo |
dc.publisher.program.fl_str_mv |
Programa de Pós-Graduação em Bioenergia |
dc.publisher.initials.fl_str_mv |
UNIOESTE |
dc.publisher.country.fl_str_mv |
Brasil |
dc.publisher.department.fl_str_mv |
Centro de Engenharias e Ciências Exatas |
publisher.none.fl_str_mv |
Universidade Estadual do Oeste do Paraná Toledo |
dc.source.none.fl_str_mv |
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Biblioteca Digital de Teses e Dissertações do UNIOESTE |
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Biblioteca Digital de Teses e Dissertações do UNIOESTE |
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Biblioteca Digital de Teses e Dissertações do UNIOESTE - Universidade Estadual do Oeste do Paraná (UNIOESTE) |
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biblioteca.repositorio@unioeste.br |
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