Transformação estrutural no estado sólido de polímeros de coordenação de duas e três dimensões contendo o ligante flexível 4-α,α’-xilenodiilabis(fenilfosfinato)

Detalhes bibliográficos
Ano de defesa: 2018
Autor(a) principal: Duarte, Rafael lattes
Orientador(a): Burrow, Robert Alan lattes
Banca de defesa: Santos, Sailer Santos dos lattes, Tirloni, Bárbara lattes, Silva, Rubia Mara Siqueira da lattes, Bortoluzzi, Adailton João lattes
Tipo de documento: Tese
Tipo de acesso: Acesso aberto
Idioma: por
Instituição de defesa: Universidade Federal de Santa Maria
Centro de Ciências Naturais e Exatas
Programa de Pós-Graduação: Programa de Pós-Graduação em Química
Departamento: Química
País: Brasil
Palavras-chave em Português:
Polímeros de coordenação
Transformação estrutural
Fosfinatos
Adsorção
Palavras-chave em Inglês:
Coordination polymers
Structural transformations
Phosphinates
Adsorption
Área do conhecimento CNPq:
CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA
Link de acesso: http://repositorio.ufsm.br/handle/1/17194
Resumo: Cobalt, nickel, copper and zinc acetate salts were reacted with the 1,4-α, α'- xylenediylabis(phenylphosphinate) (XBPP) ligand and two-dimensional CoII and ZnII coordination polymers were reacted with temperature control: by heating at reflux [Co (XBPP)]-aP (1-aP, triclinic) and [Zn(XBPP)]-aP (3-aP, triclinic); hydrothermal reaction (170 ° C and slow cooling) [Co(XBPP)]-mP (1-mP, monoclinic) and [Zn(XBPP)]-mP (3- mP, monoclinic); dehydration (desiccator with concentrated sulfuric acid) [Co(XBPP)]- am (1-am) from the compound [Co(OH2)6](XBPP)·2H2O. The reaction conditions did not influence the synthesis with CuII and the compound [Cu(XBPP)] (2) was obtained. The 4,4'-bipyridine bidentate co-ligand was used to increase the dimensionality of the structures in relation to compounds already synthesized by the work group and the coordination polymers of CoII and NiII, [Co(XBPP)(bpy)(OH2)2]·2H2O-mC (4-mC, monoclinic), [Ni(XBPP)(bpy)(OH2)2]·2H2O-mC (5-mC, monoclinic), [Ni(XBPP)(bpy)(OH2)2](bpy)(OH2)2]·2H2O-aP (5-aP, triclinic) and [Co(XBPP)(bpy)(OH2)2]·2H2O-mC (4-aP, triclinic). The bipyridine-containing compounds were subjected to two types of treatment for the removal of the bipyridine group - oven heat treatment at 300 ° C or methanol extraction treatment - in order to remove the bipyridine group and activate them for gas adsorption N2 ([Co(XBPP)-APL, 6-APL, [Co(XBPP)-APA, 6-APA and [Ni(XBPP)]-APA, 7-APA), with little adsorption capacity observed.
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spelling 2019-06-28T12:58:39Z2019-06-28T12:58:39Z2018-02-27http://repositorio.ufsm.br/handle/1/17194Cobalt, nickel, copper and zinc acetate salts were reacted with the 1,4-α, α'- xylenediylabis(phenylphosphinate) (XBPP) ligand and two-dimensional CoII and ZnII coordination polymers were reacted with temperature control: by heating at reflux [Co (XBPP)]-aP (1-aP, triclinic) and [Zn(XBPP)]-aP (3-aP, triclinic); hydrothermal reaction (170 ° C and slow cooling) [Co(XBPP)]-mP (1-mP, monoclinic) and [Zn(XBPP)]-mP (3- mP, monoclinic); dehydration (desiccator with concentrated sulfuric acid) [Co(XBPP)]- am (1-am) from the compound [Co(OH2)6](XBPP)·2H2O. The reaction conditions did not influence the synthesis with CuII and the compound [Cu(XBPP)] (2) was obtained. The 4,4'-bipyridine bidentate co-ligand was used to increase the dimensionality of the structures in relation to compounds already synthesized by the work group and the coordination polymers of CoII and NiII, [Co(XBPP)(bpy)(OH2)2]·2H2O-mC (4-mC, monoclinic), [Ni(XBPP)(bpy)(OH2)2]·2H2O-mC (5-mC, monoclinic), [Ni(XBPP)(bpy)(OH2)2](bpy)(OH2)2]·2H2O-aP (5-aP, triclinic) and [Co(XBPP)(bpy)(OH2)2]·2H2O-mC (4-aP, triclinic). The bipyridine-containing compounds were subjected to two types of treatment for the removal of the bipyridine group - oven heat treatment at 300 ° C or methanol extraction treatment - in order to remove the bipyridine group and activate them for gas adsorption N2 ([Co(XBPP)-APL, 6-APL, [Co(XBPP)-APA, 6-APA and [Ni(XBPP)]-APA, 7-APA), with little adsorption capacity observed.Foram reagidos sais de acetato de cobalto, níquel, cobre e zinco com o ligante 1,4- α,α'-xilenodiilabis(fenilfosfinato) (XBPP) e obtidos compostos de polímeros de coordenação bidimensionais de CoII e ZnII com controle da temperatura: por aquecimento em refluxo [Co(XBPP)]-aP (1-aP, triclínico) e [Zn(XBPP)]-aP (3-aP, triclínico); reação hidrotermal (170 °C e resfriamento lento) [Co(XBPP)]-mP (1-mP, monoclínico) e [Zn(XBPP)]-mP (3-mP, monoclínico); desidratação (dessecador com ácido sulfúrico concentrado) [Co(XBPP)]-am (1-am, amorfo) a partir do composto [Co(OH2)6](XBPP)·2H2O. As condições de reação não influenciam na síntese com CuII e foi obtido o composto [Cu(XBPP)] (2). O co-ligante bidentado 4,4’-bipiridina foi utilizado com o objetivo de aumentar a dimensionalidade das estruturas em relação a compostos já sintetizados pelo grupo de trabalho e foram obtidos os polímeros de coordenação de CoII e NiII, [Co(XBPP)(bpy)(OH2)2]·2H2O-mC (4-mC, monoclínico), [Ni(XBPP)(bpy)(OH2)2]·2H2O-mC (5-mC, monoclínico), [Ni(XBPP)(bpy)(OH2)2]·2H2OaP (5-aP, triclínico) e [Co(XBPP)(bpy)(OH2)2]·2H2O-mC (4-aP, triclínico). Os compostos contendo bipiridina foram submetidos a dois tipos de tratamento para a retirada do grupo bipiridina - tratamento térmico em forno a 300 °C ou tratamento por extração com metanol – com o objetivo de retirar o grupo bipiridina e ativá-los para a adsorção de gás N2 ([Co(XBPP)-APL, 6-APL, [Co(XBPP)-APA, 6-APA e [Ni(XBPP)]- APA, 7-APA), sendo observada pouca capacidade de adsorção.Conselho Nacional de Pesquisa e Desenvolvimento Científico e Tecnológico - CNPqporUniversidade Federal de Santa MariaCentro de Ciências Naturais e ExatasPrograma de Pós-Graduação em QuímicaUFSMBrasilQuímicaAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessPolímeros de coordenaçãoTransformação estruturalFosfinatosAdsorçãoCoordination polymersStructural transformationsPhosphinatesAdsorptionCNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICATransformação estrutural no estado sólido de polímeros de coordenação de duas e três dimensões contendo o ligante flexível 4-α,α’-xilenodiilabis(fenilfosfinato)Structural transformation in the solid state of coordination polymers of two and three dimensions containing the flexible ligant 4-α, α'-xylenodiilabis (phenylphosphinate)info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesisBurrow, Robert Alanhttp://lattes.cnpq.br/5452385625669684Santos, Sailer Santos doshttp://lattes.cnpq.br/2079205451835841Tirloni, Bárbarahttp://lattes.cnpq.br/2866324870100182Silva, Rubia Mara Siqueira dahttp://lattes.cnpq.br/1215582603223545Bortoluzzi, Adailton Joãohttp://lattes.cnpq.br/6445841478978597http://lattes.cnpq.br/3214771717837549Duarte, Rafael100600000000600da77a491-2340-4bec-afed-a9ed5dd5092a052c7cb3-6463-4906-9c1d-8eb9bc6cb600154b67c8-6e3c-4ed7-b40a-9e4669543386c1e37583-819e-4d38-bfe8-27059d8abef69138f2fd-9a67-43d6-ad6d-e8b21cb2b8cfb790c99c-a609-48b7-b612-af3c69649bcdreponame:Manancial - Repositório Digital da UFSMinstname:Universidade Federal de Santa Maria (UFSM)instacron:UFSMORIGINALTES_PPGQUIMICA_2018_DUARTE_RAFAEL.pdfTES_PPGQUIMICA_2018_DUARTE_RAFAEL.pdfTese de Doutoradoapplication/pdf14766803http://repositorio.ufsm.br/bitstream/1/17194/1/TES_PPGQUIMICA_2018_DUARTE_RAFAEL.pdf0a9ca437bb70a08667d1014ba312233fMD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; 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dc.title.por.fl_str_mv Transformação estrutural no estado sólido de polímeros de coordenação de duas e três dimensões contendo o ligante flexível 4-α,α’-xilenodiilabis(fenilfosfinato)
dc.title.alternative.eng.fl_str_mv Structural transformation in the solid state of coordination polymers of two and three dimensions containing the flexible ligant 4-α, α'-xylenodiilabis (phenylphosphinate)
title Transformação estrutural no estado sólido de polímeros de coordenação de duas e três dimensões contendo o ligante flexível 4-α,α’-xilenodiilabis(fenilfosfinato)
spellingShingle Transformação estrutural no estado sólido de polímeros de coordenação de duas e três dimensões contendo o ligante flexível 4-α,α’-xilenodiilabis(fenilfosfinato)
Duarte, Rafael
Polímeros de coordenação
Transformação estrutural
Fosfinatos
Adsorção
Coordination polymers
Structural transformations
Phosphinates
Adsorption
CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA
title_short Transformação estrutural no estado sólido de polímeros de coordenação de duas e três dimensões contendo o ligante flexível 4-α,α’-xilenodiilabis(fenilfosfinato)
title_full Transformação estrutural no estado sólido de polímeros de coordenação de duas e três dimensões contendo o ligante flexível 4-α,α’-xilenodiilabis(fenilfosfinato)
title_fullStr Transformação estrutural no estado sólido de polímeros de coordenação de duas e três dimensões contendo o ligante flexível 4-α,α’-xilenodiilabis(fenilfosfinato)
title_full_unstemmed Transformação estrutural no estado sólido de polímeros de coordenação de duas e três dimensões contendo o ligante flexível 4-α,α’-xilenodiilabis(fenilfosfinato)
title_sort Transformação estrutural no estado sólido de polímeros de coordenação de duas e três dimensões contendo o ligante flexível 4-α,α’-xilenodiilabis(fenilfosfinato)
author Duarte, Rafael
author_facet Duarte, Rafael
author_role author
dc.contributor.advisor1.fl_str_mv Burrow, Robert Alan
dc.contributor.advisor1Lattes.fl_str_mv http://lattes.cnpq.br/5452385625669684
dc.contributor.referee1.fl_str_mv Santos, Sailer Santos dos
dc.contributor.referee1Lattes.fl_str_mv http://lattes.cnpq.br/2079205451835841
dc.contributor.referee2.fl_str_mv Tirloni, Bárbara
dc.contributor.referee2Lattes.fl_str_mv http://lattes.cnpq.br/2866324870100182
dc.contributor.referee3.fl_str_mv Silva, Rubia Mara Siqueira da
dc.contributor.referee3Lattes.fl_str_mv http://lattes.cnpq.br/1215582603223545
dc.contributor.referee4.fl_str_mv Bortoluzzi, Adailton João
dc.contributor.referee4Lattes.fl_str_mv http://lattes.cnpq.br/6445841478978597
dc.contributor.authorLattes.fl_str_mv http://lattes.cnpq.br/3214771717837549
dc.contributor.author.fl_str_mv Duarte, Rafael
contributor_str_mv Burrow, Robert Alan
Santos, Sailer Santos dos
Tirloni, Bárbara
Silva, Rubia Mara Siqueira da
Bortoluzzi, Adailton João
dc.subject.por.fl_str_mv Polímeros de coordenação
Transformação estrutural
Fosfinatos
Adsorção
topic Polímeros de coordenação
Transformação estrutural
Fosfinatos
Adsorção
Coordination polymers
Structural transformations
Phosphinates
Adsorption
CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA
dc.subject.eng.fl_str_mv Coordination polymers
Structural transformations
Phosphinates
Adsorption
dc.subject.cnpq.fl_str_mv CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA
description Cobalt, nickel, copper and zinc acetate salts were reacted with the 1,4-α, α'- xylenediylabis(phenylphosphinate) (XBPP) ligand and two-dimensional CoII and ZnII coordination polymers were reacted with temperature control: by heating at reflux [Co (XBPP)]-aP (1-aP, triclinic) and [Zn(XBPP)]-aP (3-aP, triclinic); hydrothermal reaction (170 ° C and slow cooling) [Co(XBPP)]-mP (1-mP, monoclinic) and [Zn(XBPP)]-mP (3- mP, monoclinic); dehydration (desiccator with concentrated sulfuric acid) [Co(XBPP)]- am (1-am) from the compound [Co(OH2)6](XBPP)·2H2O. The reaction conditions did not influence the synthesis with CuII and the compound [Cu(XBPP)] (2) was obtained. The 4,4'-bipyridine bidentate co-ligand was used to increase the dimensionality of the structures in relation to compounds already synthesized by the work group and the coordination polymers of CoII and NiII, [Co(XBPP)(bpy)(OH2)2]·2H2O-mC (4-mC, monoclinic), [Ni(XBPP)(bpy)(OH2)2]·2H2O-mC (5-mC, monoclinic), [Ni(XBPP)(bpy)(OH2)2](bpy)(OH2)2]·2H2O-aP (5-aP, triclinic) and [Co(XBPP)(bpy)(OH2)2]·2H2O-mC (4-aP, triclinic). The bipyridine-containing compounds were subjected to two types of treatment for the removal of the bipyridine group - oven heat treatment at 300 ° C or methanol extraction treatment - in order to remove the bipyridine group and activate them for gas adsorption N2 ([Co(XBPP)-APL, 6-APL, [Co(XBPP)-APA, 6-APA and [Ni(XBPP)]-APA, 7-APA), with little adsorption capacity observed.
publishDate 2018
dc.date.issued.fl_str_mv 2018-02-27
dc.date.accessioned.fl_str_mv 2019-06-28T12:58:39Z
dc.date.available.fl_str_mv 2019-06-28T12:58:39Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/doctoralThesis
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dc.rights.driver.fl_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Universidade Federal de Santa Maria
Centro de Ciências Naturais e Exatas
dc.publisher.program.fl_str_mv Programa de Pós-Graduação em Química
dc.publisher.initials.fl_str_mv UFSM
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv Química
publisher.none.fl_str_mv Universidade Federal de Santa Maria
Centro de Ciências Naturais e Exatas
dc.source.none.fl_str_mv reponame:Manancial - Repositório Digital da UFSM
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instname_str Universidade Federal de Santa Maria (UFSM)
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institution UFSM
reponame_str Manancial - Repositório Digital da UFSM
collection Manancial - Repositório Digital da UFSM
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