Nanocomp?sitos de matriz polim?rica e cargas h?bridas baseadas em grafeno decorado com nanopart?culas met?licas
Ano de defesa: | 2021 |
---|---|
Autor(a) principal: | |
Orientador(a): | |
Banca de defesa: | |
Tipo de documento: | Tese |
Tipo de acesso: | Acesso aberto |
Idioma: | por |
Instituição de defesa: |
Pontif?cia Universidade Cat?lica do Rio Grande do Sul
|
Programa de Pós-Graduação: |
Programa de P?s-Gradua??o em Engenharia e Tecnologia de Materiais
|
Departamento: |
Escola Polit?cnica
|
País: |
Brasil
|
Palavras-chave em Português: | |
Palavras-chave em Inglês: | |
Área do conhecimento CNPq: | |
Link de acesso: | http://tede2.pucrs.br/tede2/handle/tede/10076 |
Resumo: | Graphene and metallic nanoparticles (MNPs) hybrid systems have been studied due to their conductive, magnetic, and adsorbent properties. However, the deposition of MNPs on graphene in powder form, without the need for substrates to stabilize these compounds, is poorly explored. Thus, this work presents an effective method for obtaining hybrid reduced graphene oxide (rGO) nanoparticles decorated with 5 % and 10 % of Ni, Fe and permalloy. The few layers rGO was obtained from the oxidation route followed by thermal reduction. MNPs were deposited by the sputtering technique. The TEM showed nanoparticles of Ni, Fe and permalloy evenly distributed throughout the rGO. TGA and RBS results confirm the amount and composition of MNPs deposited. The interaction between MNPs and rGO was studied by FT-IR. According to the XPS result, the hybrids have a decrease in the relative amount of oxygen regarding the rGO. The addition of MNPs generated ferromagnetic properties in the MNPs/rGO samples, and the electrical conductivities values were doubled with the addition of 10% Ni and Fe, and tripled in the systems containing permalloy. The addition of MNPs/rGO systems into polyethylene (PE) was also evaluated in this work. PE-MNPs/rGO nanocomposites were obtained by in situ polymerization. The addition of 0.1 % and 0.5 % of the hybrids in the PE matrix did not change the catalytic activity, thermal properties, and degree of crystallinity. PE-MNPs/rGO exhibited electrical and diamagnetic insulating properties. Based on these results, a promising route to obtain graphene decorated with MNPs was obtained for the first time from the sputtering technique using powdered graphene. The approach described in this work is promise for the preparation of hybrid rGO/MNP materials for application in catalysts, electrodes, filters and in electromagnetic shielding. |
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Basso, Nara Regina de Souzahttp://lattes.cnpq.br/9015401653501831Galland, Griselda Ligia Barrera dehttp://lattes.cnpq.br/8631049006610349http://lattes.cnpq.br/9255959768478990Maraschin, Thuany Garcia2022-02-07T17:35:23Z2021-09-30http://tede2.pucrs.br/tede2/handle/tede/10076Graphene and metallic nanoparticles (MNPs) hybrid systems have been studied due to their conductive, magnetic, and adsorbent properties. However, the deposition of MNPs on graphene in powder form, without the need for substrates to stabilize these compounds, is poorly explored. Thus, this work presents an effective method for obtaining hybrid reduced graphene oxide (rGO) nanoparticles decorated with 5 % and 10 % of Ni, Fe and permalloy. The few layers rGO was obtained from the oxidation route followed by thermal reduction. MNPs were deposited by the sputtering technique. The TEM showed nanoparticles of Ni, Fe and permalloy evenly distributed throughout the rGO. TGA and RBS results confirm the amount and composition of MNPs deposited. The interaction between MNPs and rGO was studied by FT-IR. According to the XPS result, the hybrids have a decrease in the relative amount of oxygen regarding the rGO. The addition of MNPs generated ferromagnetic properties in the MNPs/rGO samples, and the electrical conductivities values were doubled with the addition of 10% Ni and Fe, and tripled in the systems containing permalloy. The addition of MNPs/rGO systems into polyethylene (PE) was also evaluated in this work. PE-MNPs/rGO nanocomposites were obtained by in situ polymerization. The addition of 0.1 % and 0.5 % of the hybrids in the PE matrix did not change the catalytic activity, thermal properties, and degree of crystallinity. PE-MNPs/rGO exhibited electrical and diamagnetic insulating properties. Based on these results, a promising route to obtain graphene decorated with MNPs was obtained for the first time from the sputtering technique using powdered graphene. The approach described in this work is promise for the preparation of hybrid rGO/MNP materials for application in catalysts, electrodes, filters and in electromagnetic shielding.Sistemas h?bridos de grafeno e nanopart?culas met?licas (NMPs) t?m sido estudados devido ?s suas propriedades condutoras, magn?ticas e adsorventes. Por?m, a deposi??o de NPMs sobre grafeno na forma de p?, sem a necessidade de substratos para estabiliza??o destes compostos ? pouco explorada. Assim, este trabalho apresenta um m?todo eficaz para a obten??o de nanopart?culas h?bridas de ?xido de grafeno reduzido (OGR) com concentra??es de 5 % e 10 % de Ni, Fe e de permalloy. O OGR com poucas camadas foi obtido a partir da rota de oxida??o seguida de redu??o t?rmica. As NPMs foram depositadas pela t?cnica de sputtering. O MET mostrou nanopart?culas de Ni, Fe e permalloy distribu?das uniformemente por todo OGR. Resultados de TGA e RBS confirmam a quantidade e a composi??o das NPMs depositadas. A intera??o entre os NPMs e OGR foi estudada por FT-IR. Conforme o resultado de XPS, os h?bridos t?m diminui??o da quantidade relativa de oxig?nio com respeito ao OGR. A adi??o das NMPs gerou propriedades ferromagn?ticas nas amostras NPMs/OGR e os valores das condutividades el?tricas foram duplicados com a adi??o de 10 % de Ni e de Fe, e triplicados nos sistemas contendo permalloy. A adi??o dos sistemas NPMs/OGR em polietileno (PE) tamb?m foi avaliada nesse trabalho. Nanocomp?sitos de PE-NPMs/OGR foram obtidos por polimeriza??o in situ. A adi??o de 0,1 % e 0,5 % dos h?bridos na matriz de PE n?o modificou a atividade catal?tica, as propriedades t?rmicas e o grau de cristalinidade. Os PE-NPMS/OGR exibiram propriedades isolantes eletricamente e diamagn?ticas. Com base nesses resultados, uma rota promissora para a obten??o de grafenos decorados com NPMs foi obtida pela primeira vez a partir da t?cnica de sputtering utilizando grafeno em p?. A abordagem descrita neste trabalho ? promissora para a prepara??o de materiais h?bridos de OGR/NPMs visando a aplica??o em catalisadores, eletrodos, filtros e em blindagem eletromagn?tica.Submitted by PPG Engenharia e Tecnologia de Materiais (engenharia.pg.materiais@pucrs.br) on 2022-02-01T12:38:09Z No. of bitstreams: 1 THUANY_GARCIA_MARASCHIN_TES.pdf: 5315899 bytes, checksum: 1edec6f3d4d1c61a9420343a2b12e030 (MD5)Approved for entry into archive by Sheila Dias (sheila.dias@pucrs.br) on 2022-02-07T14:56:17Z (GMT) No. of bitstreams: 1 THUANY_GARCIA_MARASCHIN_TES.pdf: 5315899 bytes, checksum: 1edec6f3d4d1c61a9420343a2b12e030 (MD5)Made available in DSpace on 2022-02-07T17:35:23Z (GMT). No. of bitstreams: 1 THUANY_GARCIA_MARASCHIN_TES.pdf: 5315899 bytes, checksum: 1edec6f3d4d1c61a9420343a2b12e030 (MD5) Previous issue date: 2021-09-30Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior - CAPESapplication/pdfhttp://tede2.pucrs.br:80/tede2/retrieve/183236/THUANY_GARCIA_MARASCHIN_TES.pdf.jpgporPontif?cia Universidade Cat?lica do Rio Grande do SulPrograma de P?s-Gradua??o em Engenharia e Tecnologia de MateriaisPUCRSBrasilEscola Polit?cnicaGrafenoNanopart?culas Met?licasSputteringPolietilenoGrapheneMetallic NanoparticlesSputteringPolyethyleneENGENHARIASNanocomp?sitos de matriz polim?rica e cargas h?bridas baseadas em grafeno decorado com nanopart?culas met?licasinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesisTrabalho n?o apresenta restri??o para publica??o495391460509391966550050060045189710564848268253590462550136975366info:eu-repo/semantics/openAccessreponame:Biblioteca Digital de Teses e Dissertações da PUC_RSinstname:Pontifícia Universidade Católica do Rio Grande do Sul (PUCRS)instacron:PUC_RSTHUMBNAILTHUANY_GARCIA_MARASCHIN_TES.pdf.jpgTHUANY_GARCIA_MARASCHIN_TES.pdf.jpgimage/jpeg5944http://tede2.pucrs.br/tede2/bitstream/tede/10076/4/THUANY_GARCIA_MARASCHIN_TES.pdf.jpg858b606c4717457fccecbd678a701c55MD54TEXTTHUANY_GARCIA_MARASCHIN_TES.pdf.txtTHUANY_GARCIA_MARASCHIN_TES.pdf.txttext/plain164351http://tede2.pucrs.br/tede2/bitstream/tede/10076/3/THUANY_GARCIA_MARASCHIN_TES.pdf.txt543f8b097b410c952c793b887129f090MD53ORIGINALTHUANY_GARCIA_MARASCHIN_TES.pdfTHUANY_GARCIA_MARASCHIN_TES.pdfapplication/pdf5315899http://tede2.pucrs.br/tede2/bitstream/tede/10076/2/THUANY_GARCIA_MARASCHIN_TES.pdf1edec6f3d4d1c61a9420343a2b12e030MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-8590http://tede2.pucrs.br/tede2/bitstream/tede/10076/1/license.txt220e11f2d3ba5354f917c7035aadef24MD51tede/100762022-02-07 20:00:28.062oai:tede2.pucrs.br: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Biblioteca Digital de Teses e Dissertaçõeshttp://tede2.pucrs.br/tede2/PRIhttps://tede2.pucrs.br/oai/requestbiblioteca.central@pucrs.br||opendoar:2022-02-07T22:00:28Biblioteca Digital de Teses e Dissertações da PUC_RS - Pontifícia Universidade Católica do Rio Grande do Sul (PUCRS)false |
dc.title.por.fl_str_mv |
Nanocomp?sitos de matriz polim?rica e cargas h?bridas baseadas em grafeno decorado com nanopart?culas met?licas |
title |
Nanocomp?sitos de matriz polim?rica e cargas h?bridas baseadas em grafeno decorado com nanopart?culas met?licas |
spellingShingle |
Nanocomp?sitos de matriz polim?rica e cargas h?bridas baseadas em grafeno decorado com nanopart?culas met?licas Maraschin, Thuany Garcia Grafeno Nanopart?culas Met?licas Sputtering Polietileno Graphene Metallic Nanoparticles Sputtering Polyethylene ENGENHARIAS |
title_short |
Nanocomp?sitos de matriz polim?rica e cargas h?bridas baseadas em grafeno decorado com nanopart?culas met?licas |
title_full |
Nanocomp?sitos de matriz polim?rica e cargas h?bridas baseadas em grafeno decorado com nanopart?culas met?licas |
title_fullStr |
Nanocomp?sitos de matriz polim?rica e cargas h?bridas baseadas em grafeno decorado com nanopart?culas met?licas |
title_full_unstemmed |
Nanocomp?sitos de matriz polim?rica e cargas h?bridas baseadas em grafeno decorado com nanopart?culas met?licas |
title_sort |
Nanocomp?sitos de matriz polim?rica e cargas h?bridas baseadas em grafeno decorado com nanopart?culas met?licas |
author |
Maraschin, Thuany Garcia |
author_facet |
Maraschin, Thuany Garcia |
author_role |
author |
dc.contributor.advisor1.fl_str_mv |
Basso, Nara Regina de Souza |
dc.contributor.advisor1Lattes.fl_str_mv |
http://lattes.cnpq.br/9015401653501831 |
dc.contributor.advisor-co1.fl_str_mv |
Galland, Griselda Ligia Barrera de |
dc.contributor.advisor-co1Lattes.fl_str_mv |
http://lattes.cnpq.br/8631049006610349 |
dc.contributor.authorLattes.fl_str_mv |
http://lattes.cnpq.br/9255959768478990 |
dc.contributor.author.fl_str_mv |
Maraschin, Thuany Garcia |
contributor_str_mv |
Basso, Nara Regina de Souza Galland, Griselda Ligia Barrera de |
dc.subject.por.fl_str_mv |
Grafeno Nanopart?culas Met?licas Sputtering Polietileno |
topic |
Grafeno Nanopart?culas Met?licas Sputtering Polietileno Graphene Metallic Nanoparticles Sputtering Polyethylene ENGENHARIAS |
dc.subject.eng.fl_str_mv |
Graphene Metallic Nanoparticles Sputtering Polyethylene |
dc.subject.cnpq.fl_str_mv |
ENGENHARIAS |
description |
Graphene and metallic nanoparticles (MNPs) hybrid systems have been studied due to their conductive, magnetic, and adsorbent properties. However, the deposition of MNPs on graphene in powder form, without the need for substrates to stabilize these compounds, is poorly explored. Thus, this work presents an effective method for obtaining hybrid reduced graphene oxide (rGO) nanoparticles decorated with 5 % and 10 % of Ni, Fe and permalloy. The few layers rGO was obtained from the oxidation route followed by thermal reduction. MNPs were deposited by the sputtering technique. The TEM showed nanoparticles of Ni, Fe and permalloy evenly distributed throughout the rGO. TGA and RBS results confirm the amount and composition of MNPs deposited. The interaction between MNPs and rGO was studied by FT-IR. According to the XPS result, the hybrids have a decrease in the relative amount of oxygen regarding the rGO. The addition of MNPs generated ferromagnetic properties in the MNPs/rGO samples, and the electrical conductivities values were doubled with the addition of 10% Ni and Fe, and tripled in the systems containing permalloy. The addition of MNPs/rGO systems into polyethylene (PE) was also evaluated in this work. PE-MNPs/rGO nanocomposites were obtained by in situ polymerization. The addition of 0.1 % and 0.5 % of the hybrids in the PE matrix did not change the catalytic activity, thermal properties, and degree of crystallinity. PE-MNPs/rGO exhibited electrical and diamagnetic insulating properties. Based on these results, a promising route to obtain graphene decorated with MNPs was obtained for the first time from the sputtering technique using powdered graphene. The approach described in this work is promise for the preparation of hybrid rGO/MNP materials for application in catalysts, electrodes, filters and in electromagnetic shielding. |
publishDate |
2021 |
dc.date.issued.fl_str_mv |
2021-09-30 |
dc.date.accessioned.fl_str_mv |
2022-02-07T17:35:23Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/doctoralThesis |
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doctoralThesis |
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publishedVersion |
dc.identifier.uri.fl_str_mv |
http://tede2.pucrs.br/tede2/handle/tede/10076 |
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http://tede2.pucrs.br/tede2/handle/tede/10076 |
dc.language.iso.fl_str_mv |
por |
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por |
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4953914605093919665 |
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500 500 600 |
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4518971056484826825 |
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3590462550136975366 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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Pontif?cia Universidade Cat?lica do Rio Grande do Sul |
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Programa de P?s-Gradua??o em Engenharia e Tecnologia de Materiais |
dc.publisher.initials.fl_str_mv |
PUCRS |
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Brasil |
dc.publisher.department.fl_str_mv |
Escola Polit?cnica |
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Pontif?cia Universidade Cat?lica do Rio Grande do Sul |
dc.source.none.fl_str_mv |
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