Comportamento físico e mecânico de compósitos feitos de matriz de polietileno verde reforçados por longas fibras de bambu: influência do tratamento físico e químico das fibras nas fibras e nos compósitos

Detalhes bibliográficos
Ano de defesa: 2019
Autor(a) principal: Costa, Milene Muniz Eloy da
Orientador(a): Deus, Ênio Pontes de
Banca de defesa: Não Informado pela instituição
Tipo de documento: Tese
Tipo de acesso: Acesso aberto
Idioma: eng
Instituição de defesa: Não Informado pela instituição
Programa de Pós-Graduação: Não Informado pela instituição
Departamento: Não Informado pela instituição
País: Não Informado pela instituição
Palavras-chave em Português:
Link de acesso: http://www.repositorio.ufc.br/handle/riufc/53164
Resumo: The environmental concern with the unregulated use of non-renewable resources, as well as the inadequate disposal of waste in the environment, encourage the development of awareness measures and technological alternatives. Faced with this problem, there is a need to manufacture products that are less aggressive to the environment, either according to their raw material or according to their post-use. The use of natural fibers applied as reinforcement in polymeric matrices is an alternative for the manufacture of industrial products in various areas, from household utensils and packaging to civil construction products. The choice of bamboo fibers was motivated by the use of a long fiber vegetable source reinforcement, with good mechanical strength, low density and low cost. In addition, the work proposes the use of a polymeric matrix produced from a renewable plant source, sugar cane. In this context, the proposal of this thesis was to develop a composite produced entirely from renewable sources, evaluating its applicability through characterization and investigation of some morphological, physicochemical and mechanical properties of bamboo fibers, green polyethylene matrix and produced composites, and, mainly, evaluating the effect of different treatments performed on fibers on the composites mechanical properties. The morphological and physicochemical characterizations revealed a decrease in fiber mass after treatments, as well as variations in density, porosity and pore size. Also an increase of roughness at the fibers surface was observed, suggesting an improved mechanical anchorage by the polymeric matrix. The tensile tests showed that the mechanical properties (modulus of elasticity and tensile strength) of the fibers were improved with some treatments. The mechanical characterization of the composites highlighted that the treatments were effective for a good adhesion between fiber and polymer matrix. To conclude, the experimental investigations showed that the best treatments were mercerization and acetylation, indicating that the produced composites have applicability for projects which, at a high loading rate, they support fragile fracture.
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spelling Costa, Milene Muniz Eloy daDeus, Ênio Pontes de2020-07-28T19:05:19Z2020-07-28T19:05:19Z2019COSTA, M. M. E. Physical and mechanical behavior of composites made of green polyethylene matrix reinforced by long bamboo fibers: influence of the physical and chemical treatment of the fibers on the fibers and on the composites. 2019. 164 f. Tese (Doutorado em Engenharia e Ciência de Materiais) – Centro de Tecnologia, Universidade Federal do Ceará, Fortaleza, 2019.http://www.repositorio.ufc.br/handle/riufc/53164The environmental concern with the unregulated use of non-renewable resources, as well as the inadequate disposal of waste in the environment, encourage the development of awareness measures and technological alternatives. Faced with this problem, there is a need to manufacture products that are less aggressive to the environment, either according to their raw material or according to their post-use. The use of natural fibers applied as reinforcement in polymeric matrices is an alternative for the manufacture of industrial products in various areas, from household utensils and packaging to civil construction products. The choice of bamboo fibers was motivated by the use of a long fiber vegetable source reinforcement, with good mechanical strength, low density and low cost. In addition, the work proposes the use of a polymeric matrix produced from a renewable plant source, sugar cane. In this context, the proposal of this thesis was to develop a composite produced entirely from renewable sources, evaluating its applicability through characterization and investigation of some morphological, physicochemical and mechanical properties of bamboo fibers, green polyethylene matrix and produced composites, and, mainly, evaluating the effect of different treatments performed on fibers on the composites mechanical properties. The morphological and physicochemical characterizations revealed a decrease in fiber mass after treatments, as well as variations in density, porosity and pore size. Also an increase of roughness at the fibers surface was observed, suggesting an improved mechanical anchorage by the polymeric matrix. The tensile tests showed that the mechanical properties (modulus of elasticity and tensile strength) of the fibers were improved with some treatments. The mechanical characterization of the composites highlighted that the treatments were effective for a good adhesion between fiber and polymer matrix. To conclude, the experimental investigations showed that the best treatments were mercerization and acetylation, indicating that the produced composites have applicability for projects which, at a high loading rate, they support fragile fracture.A preocupação ambiental com o uso desregrado de recursos não-renováveis, bem como a disposição inadequada de resíduos no meio, incentivam o desenvolvimento de medidas de conscientização e de alternativas tecnológicas. Diante dessa problemática, surge a necessidade de manufatura de produtos menos agressivos ao meio, seja de acordo com sua matéria-prima ou de acordo com sua pós-utilização. O uso de fibras vegetais aplicadas como reforço em matrizes poliméricas apresenta-se como uma alternativa para a fabricação de produtos industriais em diversas áreas, desde utensílios domésticos e embalagens a produtos da construção civil. A escolha das fibras de bambu foi motivada pela utilização de um reforço de fonte vegetal de fibras longas, com boa resistência mecânica, baixa densidade e baixo custo. Além disso, o trabalho propôs a utilização de uma matriz polimérica produzida a partir de uma fonte renovável vegetal, a cana-de-açúcar. Nesse contexto, a proposta dessa tese foi desenvolver um compósito produzido totalmente por fontes renováveis, avaliando sua aplicabilidade através de caracterização e investigação de algumas propriedades morfológicas, físico-químicas e mecânicas das fibras de bambu, da matriz de polietileno verde e dos compósitos produzidos, e, principalmente, avaliando o efeito de diferentes tratamentos realizados nas fibras sobre as propriedades mecânicas dos compósitos. As caracterizações morfológicas e físico-químicas revelaram uma diminuição de massa das fibras após os tratamentos, bem como variações na densidade, porosidade e tamanho de poros. Também foi observado um aumento de rugosidade na superfície das fibras, sugerindo uma melhor ancoragem mecânica pela matriz polimérica. Os testes de tração mostraram que as propriedades mecânicas (modulo de elasticidade e resistência à tração) das fibras foram melhoradas com alguns tratamentos. A caracterização mecânica dos compósitos destacou que os tratamentos foram eficazes para uma boa adesão entre fibra e matriz polimérica. Para concluir, as investigações experimentais mostraram que os melhores tratamentos foram mercerização e acetilação, indicando que os compósitos produzidos apresentam aplicabilidade para projetos em que, a uma alta taxa de carregamento, suportem fratura frágil.Bamboo fibers BambuGreen polyethylene PolietilenoPolymeric composites Compósitos poliméricosFiber/matrix adhesion Adesão matricialComportamento físico e mecânico de compósitos feitos de matriz de polietileno verde reforçados por longas fibras de bambu: influência do tratamento físico e químico das fibras nas fibras e nos compósitosPhysical and mechanical behavior of composites made of green polyethylene matrix reinforced by long bamboo fibers: influence of the physical and chemical treatment of the fibers on the fibers and on the compositesinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesisengreponame:Repositório Institucional da Universidade Federal do Ceará (UFC)instname:Universidade Federal do Ceará (UFC)instacron:UFCinfo:eu-repo/semantics/openAccessLICENSElicense.txtlicense.txttext/plain; charset=utf-81978http://repositorio.ufc.br/bitstream/riufc/53164/4/license.txt4247602db8c5bb0eb5b2dc93ccdf9494MD54ORIGINAL2019_tese_mmecosta.pdf2019_tese_mmecosta.pdfapplication/pdf76268550http://repositorio.ufc.br/bitstream/riufc/53164/3/2019_tese_mmecosta.pdfb979985eba9866c3911f362c76870c6fMD53riufc/531642020-08-25 13:38:25.106oai:repositorio.ufc.br:riufc/53164TElDRU7Dh0EgREUgRElTVFJJQlVJw4fDg08gTsODTy1FWENMVVNJVkENCg0KQW8gYWNlaXRhciBlc3RhIGxpY2Vuw6dhLCBvIGF1dG9yIChvdSBkZXRlbnRvciBkb3MgZGlyZWl0b3MgZGUgYXV0b3JpYSkgZG8gZG9jdW1lbnRvIHF1ZSBlc3TDoSBzZW5kbyBkZXBvc2l0YWRvOg0KDQoxLiBEZWNsYXJhIHF1ZTogDQphKSBvIGRvY3VtZW50byDDqSBzZXUgdHJhYmFsaG8gb3JpZ2luYWw7DQpiKSBkZXTDqW0gbyBkaXJlaXRvIGRlIGNvbmNlZGVyIG9zIHByaXZpbMOpZ2lvcyBtZW5jaW9uYWRvcyBuZXN0YSBsaWNlbsOnYTsNCmMpIG8gZGVww7NzaXRvIGRvIGRvY3VtZW50byBuw6NvIGluZnJpbmdlLCBwZWxvIG1lbm9zIHF1ZSBzZWphIGRvIHNldSBjb25oZWNpbWVudG8sIG9zIGRpcmVpdG9zIGRlIHF1YWxxdWVyIG91dHJhIHBlc3NvYSBvdSBlbnRpZGFkZTsNCmQpIGNhc28gbyBkb2N1bWVudG8gY29udGVuaGEgbWF0ZXJpYWwgc3VqZWl0byBhIGRpcmVpdG9zIGF1dG9yaWFpcyBkZSB0ZXJjZWlyb3MsIHF1ZSBvYnRldmUgYXV0b3JpemHDp8OjbyBkbyBhdXRvciBvdSBkZXRlbnRvciBwYXJhIGNvbmNlZGVyIGFvIFJlcG9zaXTDs3JpbyBJbnN0aXR1Y2lvbmFsIGRhIFVuaXZlcnNpZGFkZSBGZWRlcmFsIGRvIENlYXLDoSBvcyBwcml2aWzDqWdpb3MgcmVxdWVyaWRvcyBwb3IgZXN0YSBsaWNlbsOnYTsNCmUpIG8gbWF0ZXJpYWwgc3VqZWl0byBhIGRpcmVpdG9zIGF1dG9yaWFpcyBkZSB0ZXJjZWlyb3MgZXN0w6EgY2xhcmFtZW50ZSBpZGVudGlmaWNhZG8gZSB2aW5jdWxhZG8gYW8ocykgbm9tZShzKSBkZSBzZXUocykgcmVzcGVjdGl2byhzKSBkZXRlbnRvcihlcyksIHNlamEgbm8gdGV4dG8gb3UgZW0gb3V0cmEgcGFydGUgZG8gY29udGXDumRvOyBlDQpmKSBjYXNvIG8gZG9jdW1lbnRvIHNlamEgcmVzdWx0YWRvIGRlIHRyYWJhbGhvIHBhdHJvY2luYWRvIG91IGFwb2lhZG8gcG9yIG91dHJhIGluc3RpdHVpw6fDo28gb3Ugw7NyZ8OjbyBxdWUgbsOjbyBhIFVuaXZlcnNpZGFkZSBGZWRlcmFsIGRvIENlYXLDoSwgcXVlIHNhdGlzZmV6IHF1YWxxdWVyIGRpcmVpdG8gZGUgcmV2aXPDo28gb3Ugb3V0cm9zIGNvbXByb21pc3NvcyByZXF1ZXJpZG9zIHBlbG9zIHJlc3BlY3Rpdm9zIGNvbnRyYXRvcyBvdSBhY29yZG9zLg0KDQoyLiBPdXRvcmdhIGFvIFJlcG9zaXTDs3JpbyBJbnN0aXR1Y2lvbmFsIGRhIFVuaXZlcnNpZGFkZSBGZWRlcmFsIGRvIENlYXLDoSBvIGRpcmVpdG8gbsOjby1leGNsdXNpdm8gZGU6DQphKSByZXByb2R1emlyLCBhbHRlcmFyIG8gZm9ybWF0bywgZSBvdSBkaXN0cmlidWlyIG8gZG9jdW1lbnRvIGFxdWkgZGVwb3NpdGFkbzsNCmIpIGVtIG1laW8gaW1wcmVzc28gb3UgZWxldHLDtG5pY28sIG91IGVtIHF1YWxxdWVyIG3DrWRpYSwgaW5jbHVzaXZlIMOhdWRpbyBlIHbDrWRlbyBwYXJhIGZpbnMgZGUgZGl2dWxnYcOnw6NvOw0KYykgY29udmVydGVyIG8gZG9jdW1lbnRvIGRlcG9zaXRhZG8sIHNlbSBhbHRlcmFyIHNldSBjb250ZcO6ZG8sIHBhcmEgcXVhbHF1ZXIgbcOtZGlhIG91IGZvcm1hdG8sIHBhcmEgZmlucyBkZSBwcmVzZXJ2YcOnw6NvIGRlIHNldSBjb250ZcO6ZG87IGUNCmQpIG1hbnRlciBtYWlzIHVtYSBjw7NwaWEgZGVzc2UgZm9ybWF0byBwYXJhIGZpbnMgZGUgc2VndXJhbsOnYSwgYmFja3VwIGUgcHJlc2VydmHDp8OjbyBlbSBmb3JtYXRvIGRpZ2l0YWwuDQoNCk8gUmVwb3NpdMOzcmlvIEluc3RpdHVjaW9uYWwgZGEgVW5pdmVyc2lkYWRlIEZlZGVyYWwgZG8gQ2VhcsOhLCBpZGVudGlmaWNhcsOhIGNsYXJhbWVudGUgc2V1IG5vbWUgY29tbyBhdXRvciBvdSBwcm9wcmlldMOhcmlvIGRlc3NlIGRvY3VtZW50byBlIG7Do28gZmFyw6EgbmVuaHVtIGFsdGVyYcOnw6NvLCBhbMOpbSBkbyBwZXJtaXRvIHBvciBlc3RhIGxpY2Vuw6dhLg0KDQpFbSBjYXNvIGRlIGTDunZpZGFzIG5vc3NvIGNvbnRhdG8gw6k6IHJlcG9zaXTDs3Jpb0B1ZmMuYnINCg==Repositório InstitucionalPUBhttp://www.repositorio.ufc.br/ri-oai/requestbu@ufc.br || repositorio@ufc.bropendoar:2020-08-25T16:38:25Repositório Institucional da Universidade Federal do Ceará (UFC) - Universidade Federal do Ceará (UFC)false
dc.title.pt_BR.fl_str_mv Comportamento físico e mecânico de compósitos feitos de matriz de polietileno verde reforçados por longas fibras de bambu: influência do tratamento físico e químico das fibras nas fibras e nos compósitos
dc.title.en.pt_BR.fl_str_mv Physical and mechanical behavior of composites made of green polyethylene matrix reinforced by long bamboo fibers: influence of the physical and chemical treatment of the fibers on the fibers and on the composites
title Comportamento físico e mecânico de compósitos feitos de matriz de polietileno verde reforçados por longas fibras de bambu: influência do tratamento físico e químico das fibras nas fibras e nos compósitos
spellingShingle Comportamento físico e mecânico de compósitos feitos de matriz de polietileno verde reforçados por longas fibras de bambu: influência do tratamento físico e químico das fibras nas fibras e nos compósitos
Costa, Milene Muniz Eloy da
Bamboo fibers Bambu
Green polyethylene Polietileno
Polymeric composites Compósitos poliméricos
Fiber/matrix adhesion Adesão matricial
title_short Comportamento físico e mecânico de compósitos feitos de matriz de polietileno verde reforçados por longas fibras de bambu: influência do tratamento físico e químico das fibras nas fibras e nos compósitos
title_full Comportamento físico e mecânico de compósitos feitos de matriz de polietileno verde reforçados por longas fibras de bambu: influência do tratamento físico e químico das fibras nas fibras e nos compósitos
title_fullStr Comportamento físico e mecânico de compósitos feitos de matriz de polietileno verde reforçados por longas fibras de bambu: influência do tratamento físico e químico das fibras nas fibras e nos compósitos
title_full_unstemmed Comportamento físico e mecânico de compósitos feitos de matriz de polietileno verde reforçados por longas fibras de bambu: influência do tratamento físico e químico das fibras nas fibras e nos compósitos
title_sort Comportamento físico e mecânico de compósitos feitos de matriz de polietileno verde reforçados por longas fibras de bambu: influência do tratamento físico e químico das fibras nas fibras e nos compósitos
author Costa, Milene Muniz Eloy da
author_facet Costa, Milene Muniz Eloy da
author_role author
dc.contributor.author.fl_str_mv Costa, Milene Muniz Eloy da
dc.contributor.advisor1.fl_str_mv Deus, Ênio Pontes de
contributor_str_mv Deus, Ênio Pontes de
dc.subject.por.fl_str_mv Bamboo fibers Bambu
Green polyethylene Polietileno
Polymeric composites Compósitos poliméricos
Fiber/matrix adhesion Adesão matricial
topic Bamboo fibers Bambu
Green polyethylene Polietileno
Polymeric composites Compósitos poliméricos
Fiber/matrix adhesion Adesão matricial
description The environmental concern with the unregulated use of non-renewable resources, as well as the inadequate disposal of waste in the environment, encourage the development of awareness measures and technological alternatives. Faced with this problem, there is a need to manufacture products that are less aggressive to the environment, either according to their raw material or according to their post-use. The use of natural fibers applied as reinforcement in polymeric matrices is an alternative for the manufacture of industrial products in various areas, from household utensils and packaging to civil construction products. The choice of bamboo fibers was motivated by the use of a long fiber vegetable source reinforcement, with good mechanical strength, low density and low cost. In addition, the work proposes the use of a polymeric matrix produced from a renewable plant source, sugar cane. In this context, the proposal of this thesis was to develop a composite produced entirely from renewable sources, evaluating its applicability through characterization and investigation of some morphological, physicochemical and mechanical properties of bamboo fibers, green polyethylene matrix and produced composites, and, mainly, evaluating the effect of different treatments performed on fibers on the composites mechanical properties. The morphological and physicochemical characterizations revealed a decrease in fiber mass after treatments, as well as variations in density, porosity and pore size. Also an increase of roughness at the fibers surface was observed, suggesting an improved mechanical anchorage by the polymeric matrix. The tensile tests showed that the mechanical properties (modulus of elasticity and tensile strength) of the fibers were improved with some treatments. The mechanical characterization of the composites highlighted that the treatments were effective for a good adhesion between fiber and polymer matrix. To conclude, the experimental investigations showed that the best treatments were mercerization and acetylation, indicating that the produced composites have applicability for projects which, at a high loading rate, they support fragile fracture.
publishDate 2019
dc.date.issued.fl_str_mv 2019
dc.date.accessioned.fl_str_mv 2020-07-28T19:05:19Z
dc.date.available.fl_str_mv 2020-07-28T19:05:19Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/doctoralThesis
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dc.identifier.citation.fl_str_mv COSTA, M. M. E. Physical and mechanical behavior of composites made of green polyethylene matrix reinforced by long bamboo fibers: influence of the physical and chemical treatment of the fibers on the fibers and on the composites. 2019. 164 f. Tese (Doutorado em Engenharia e Ciência de Materiais) – Centro de Tecnologia, Universidade Federal do Ceará, Fortaleza, 2019.
dc.identifier.uri.fl_str_mv http://www.repositorio.ufc.br/handle/riufc/53164
identifier_str_mv COSTA, M. M. E. Physical and mechanical behavior of composites made of green polyethylene matrix reinforced by long bamboo fibers: influence of the physical and chemical treatment of the fibers on the fibers and on the composites. 2019. 164 f. Tese (Doutorado em Engenharia e Ciência de Materiais) – Centro de Tecnologia, Universidade Federal do Ceará, Fortaleza, 2019.
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