Caracterização espectrorradiométrica do minério magnesítico da porção Centro-Sul do Estado do Ceará

Detalhes bibliográficos
Ano de defesa: 2020
Autor(a) principal: Souza, Cassiano Dias de
Orientador(a): Duarte, Cynthia Romariz
Banca de defesa: Não Informado pela instituição
Tipo de documento: Dissertação
Tipo de acesso: Acesso aberto
Idioma: por
Instituição de defesa: Não Informado pela instituição
Programa de Pós-Graduação: Não Informado pela instituição
Departamento: Não Informado pela instituição
País: Não Informado pela instituição
Palavras-chave em Português:
Link de acesso: http://www.repositorio.ufc.br/handle/riufc/57570
Resumo: This work has as objective the spectroradiometric characterization of magnesitic ore of the south-central portion of the state of Ceará through reflectance spectroradiometry. The samples collected from the mines of Torto, Riacho Fundo and Cabeça de Negro, located between the municipalities of Orós and Jucás, were cut ad polished, in order to obtain uniform surfaces, and to minimize the effect of the relief and any weather effects of surface. The data were obtained through the FieldSpec Pro FR 3 which collects data in the range between 350nmand 2500nm. The collection procedure was performed in the laboratory, without any interference from external lighting. Three measurements were made in different sample location, each measurement representing the averageof 50 spectra collected. The spectral features found are related to iron ions, to the groups CO32-, H2O, OH-, and Mg –OH bond. Seven of these features stood out for their frequency and intensity, being called Band 1 to Band 7. The spectral behavior at the shortest wavelengths is associated with the electronic transitional processes of iron, as well as the intense and wide absorption band between 1000nmand 1300nm(Band 1), and the band at 1700nm(Band 3). Due to the spectral features at 1390nm(Band 2), 1440nmand 1940nm(Band 5) characteristics, except for the CN –05 sample, it could be said that there is the presence of H2Oinserted as a fluid inclusion or as part of crystalline structure of the samples from the Cabeça de Negro mine,with the features at 950nm, 2070nmand 2390nmbeing attributed to hydroxyl and Mg –OH bond. In the spectra of the samples from Torto, Riacho Fundo, and the CN –05 sample from Cabeça de Negro mine, there are only spectral features related to the hydroxyl and the Mg –OH bond. The spectral features related to the transitional vibrational processes of CO32-are centered at 1850nm(Band 4), 1970nm(Band 5), 2130nm(Band 6) and 2300nm(Band 7) . In the spectra of samples from Cabeça de Negro mine, with the exception of the CN -05 sample, the absorption featureof the Band 5 is masked and shifted to 1940nmdue to H2O absorption. The Band 7 is intense and well-markedin the samples from the three mines, sometimes presenting a double feature.The albedo of the spectra and the intensity of the features are influenced by the presence of organic matter and granulometry. The technique of removing the continuum helped in the better visualization of the spectral features, as well as in the characteristics ofthe features, however it does not, in fact, cancel out the effects of organic matter and/or granulometry
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spelling Souza, Cassiano Dias deDuarte, Cynthia Romariz2021-04-05T17:56:23Z2021-04-05T17:56:23Z2020SOUZA, Cassiano Dias de. Caracterização espectrorradiométrica do minério magnesítico da porção Centro-Sul do Estado do Ceará. 2020. 99 f. Dissertação (Mestrado em Geologia) - Universidade Federal do Ceará, Fortaleza, 2020.http://www.repositorio.ufc.br/handle/riufc/57570This work has as objective the spectroradiometric characterization of magnesitic ore of the south-central portion of the state of Ceará through reflectance spectroradiometry. The samples collected from the mines of Torto, Riacho Fundo and Cabeça de Negro, located between the municipalities of Orós and Jucás, were cut ad polished, in order to obtain uniform surfaces, and to minimize the effect of the relief and any weather effects of surface. The data were obtained through the FieldSpec Pro FR 3 which collects data in the range between 350nmand 2500nm. The collection procedure was performed in the laboratory, without any interference from external lighting. Three measurements were made in different sample location, each measurement representing the averageof 50 spectra collected. The spectral features found are related to iron ions, to the groups CO32-, H2O, OH-, and Mg –OH bond. Seven of these features stood out for their frequency and intensity, being called Band 1 to Band 7. The spectral behavior at the shortest wavelengths is associated with the electronic transitional processes of iron, as well as the intense and wide absorption band between 1000nmand 1300nm(Band 1), and the band at 1700nm(Band 3). Due to the spectral features at 1390nm(Band 2), 1440nmand 1940nm(Band 5) characteristics, except for the CN –05 sample, it could be said that there is the presence of H2Oinserted as a fluid inclusion or as part of crystalline structure of the samples from the Cabeça de Negro mine,with the features at 950nm, 2070nmand 2390nmbeing attributed to hydroxyl and Mg –OH bond. In the spectra of the samples from Torto, Riacho Fundo, and the CN –05 sample from Cabeça de Negro mine, there are only spectral features related to the hydroxyl and the Mg –OH bond. The spectral features related to the transitional vibrational processes of CO32-are centered at 1850nm(Band 4), 1970nm(Band 5), 2130nm(Band 6) and 2300nm(Band 7) . In the spectra of samples from Cabeça de Negro mine, with the exception of the CN -05 sample, the absorption featureof the Band 5 is masked and shifted to 1940nmdue to H2O absorption. The Band 7 is intense and well-markedin the samples from the three mines, sometimes presenting a double feature.The albedo of the spectra and the intensity of the features are influenced by the presence of organic matter and granulometry. The technique of removing the continuum helped in the better visualization of the spectral features, as well as in the characteristics ofthe features, however it does not, in fact, cancel out the effects of organic matter and/or granulometryEste trabalho teve como objetivo a caracterização espectrorradiométrica do minério magnesítico da porção centro-sul doestado do Ceará através de espectrorradiometria de reflectância. As amostras coletadasdas minas do Torto, Riacho Fundo e Cabeça de Negro, localizadas entre os municípios de Orós e Jucás,foram cortadas e polidas, afim de se obter superfícies uniformizadas, e de minimizar o efeito do relevo e de eventuais efeitos intempéricos de superfície. Para a aquisição dos dados, utilizou-se o espectrorradiômetro FieldSpec Pro FR, que coleta dados na faixa entre 350nm e 2500nm.O procedimento de coleta foi feito emlaboratório, sem qualquer interferência oriunda de iluminação externa.Foram realizadastrês medidas em pontos distintos da amostra, cada medida representando a média de 50 espectros coletados. As feições espectrais encontradas estão relacionadas a íons de ferro, aos grupos CO32, H2O, OH-e ligação Mg –OH. Sete dessas feições se destacaram por sua frequência e intensidade, sendo denominadas de Banda 1 a Banda 7. O comportamento espectralnos menores comprimentos de onda estáassociado aos processos transicionais eletrônicos do ferro, assim como a intensa e larga banda de absorção entre 1000nm e 1300nm (Banda 1), e a banda em 1700nm (Banda 3). Devido as feições espectrais em 1390nm(Banda 2), 1440nm e 1940nm(Banda 5)características, excetuando-se a amostra CN –05, pôde-se afirmar que há a presença de H2O inserido como inclusão fluída ou como parte da estrutura cristalina das amostras da mina Cabeça de Negro,com as feições em 950nm, e em 2070 nme 2390nm sendo atribuídas à hidroxila e/ouà ligaçãoMg –OH. Nos espectros das amostras das minas do Torto, Riacho Fundo, e da amostra CN –05 da mina Cabeça de Negro, há somente as feições espectrais relacionadas à hidroxila e à ligação Mg –OH. As feições espectrais relacionadas aos processos transicionais vibracionais do CO32-estão centrados em 1850nm(Banda 4), 1970nm(Banda 5), 2130nm(Banda 6)e 2300nm(Banda 7). Nos espectros das amostras da mina Cabeça de Negro, com exceção da amostra CN –05, a feição de absorção da Banda 5μm encontra-se mascarada e deslocada para 1940nm devido à absorção do H2O. A Banda 7é intensa e bem marcada nas amostras das três minas, por vezes apresentando feição dupla. O albedo dos espectros e a intensidade das feições são influenciadas pela presença de matéria orgânica e pela granulometria. A técnica de remoção do contínuo auxiliou na melhor visualização das feições espectrais, assim como nas características das feições, porém não anula de fato os efeitos da matéria orgânica e/ou granulometria.EspectrorradiometriaMagnesitaSensoriamento RemotoCaracterização espectrorradiométrica do minério magnesítico da porção Centro-Sul do Estado do CearáSpectroradiometric characterization of magnesitic ore in the Center-South portion of the State of Cearáinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisporreponame:Repositório Institucional da Universidade Federal do Ceará (UFC)instname:Universidade Federal do Ceará (UFC)instacron:UFCinfo:eu-repo/semantics/openAccessLICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://repositorio.ufc.br/bitstream/riufc/57570/6/license.txt8a4605be74aa9ea9d79846c1fba20a33MD56ORIGINAL2020_dis_cdsouza.pdf2020_dis_cdsouza.pdfapplication/pdf10123100http://repositorio.ufc.br/bitstream/riufc/57570/5/2020_dis_cdsouza.pdfa6e39f3e6354cd80337533cdd388b9f4MD55riufc/575702021-04-05 14:56:56.726oai:repositorio.ufc.br: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Repositório InstitucionalPUBhttp://www.repositorio.ufc.br/ri-oai/requestbu@ufc.br || repositorio@ufc.bropendoar:2021-04-05T17:56:56Repositório Institucional da Universidade Federal do Ceará (UFC) - Universidade Federal do Ceará (UFC)false
dc.title.pt_BR.fl_str_mv Caracterização espectrorradiométrica do minério magnesítico da porção Centro-Sul do Estado do Ceará
dc.title.en.pt_BR.fl_str_mv Spectroradiometric characterization of magnesitic ore in the Center-South portion of the State of Ceará
title Caracterização espectrorradiométrica do minério magnesítico da porção Centro-Sul do Estado do Ceará
spellingShingle Caracterização espectrorradiométrica do minério magnesítico da porção Centro-Sul do Estado do Ceará
Souza, Cassiano Dias de
Espectrorradiometria
Magnesita
Sensoriamento Remoto
title_short Caracterização espectrorradiométrica do minério magnesítico da porção Centro-Sul do Estado do Ceará
title_full Caracterização espectrorradiométrica do minério magnesítico da porção Centro-Sul do Estado do Ceará
title_fullStr Caracterização espectrorradiométrica do minério magnesítico da porção Centro-Sul do Estado do Ceará
title_full_unstemmed Caracterização espectrorradiométrica do minério magnesítico da porção Centro-Sul do Estado do Ceará
title_sort Caracterização espectrorradiométrica do minério magnesítico da porção Centro-Sul do Estado do Ceará
author Souza, Cassiano Dias de
author_facet Souza, Cassiano Dias de
author_role author
dc.contributor.author.fl_str_mv Souza, Cassiano Dias de
dc.contributor.advisor1.fl_str_mv Duarte, Cynthia Romariz
contributor_str_mv Duarte, Cynthia Romariz
dc.subject.por.fl_str_mv Espectrorradiometria
Magnesita
Sensoriamento Remoto
topic Espectrorradiometria
Magnesita
Sensoriamento Remoto
description This work has as objective the spectroradiometric characterization of magnesitic ore of the south-central portion of the state of Ceará through reflectance spectroradiometry. The samples collected from the mines of Torto, Riacho Fundo and Cabeça de Negro, located between the municipalities of Orós and Jucás, were cut ad polished, in order to obtain uniform surfaces, and to minimize the effect of the relief and any weather effects of surface. The data were obtained through the FieldSpec Pro FR 3 which collects data in the range between 350nmand 2500nm. The collection procedure was performed in the laboratory, without any interference from external lighting. Three measurements were made in different sample location, each measurement representing the averageof 50 spectra collected. The spectral features found are related to iron ions, to the groups CO32-, H2O, OH-, and Mg –OH bond. Seven of these features stood out for their frequency and intensity, being called Band 1 to Band 7. The spectral behavior at the shortest wavelengths is associated with the electronic transitional processes of iron, as well as the intense and wide absorption band between 1000nmand 1300nm(Band 1), and the band at 1700nm(Band 3). Due to the spectral features at 1390nm(Band 2), 1440nmand 1940nm(Band 5) characteristics, except for the CN –05 sample, it could be said that there is the presence of H2Oinserted as a fluid inclusion or as part of crystalline structure of the samples from the Cabeça de Negro mine,with the features at 950nm, 2070nmand 2390nmbeing attributed to hydroxyl and Mg –OH bond. In the spectra of the samples from Torto, Riacho Fundo, and the CN –05 sample from Cabeça de Negro mine, there are only spectral features related to the hydroxyl and the Mg –OH bond. The spectral features related to the transitional vibrational processes of CO32-are centered at 1850nm(Band 4), 1970nm(Band 5), 2130nm(Band 6) and 2300nm(Band 7) . In the spectra of samples from Cabeça de Negro mine, with the exception of the CN -05 sample, the absorption featureof the Band 5 is masked and shifted to 1940nmdue to H2O absorption. The Band 7 is intense and well-markedin the samples from the three mines, sometimes presenting a double feature.The albedo of the spectra and the intensity of the features are influenced by the presence of organic matter and granulometry. The technique of removing the continuum helped in the better visualization of the spectral features, as well as in the characteristics ofthe features, however it does not, in fact, cancel out the effects of organic matter and/or granulometry
publishDate 2020
dc.date.issued.fl_str_mv 2020
dc.date.accessioned.fl_str_mv 2021-04-05T17:56:23Z
dc.date.available.fl_str_mv 2021-04-05T17:56:23Z
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dc.identifier.citation.fl_str_mv SOUZA, Cassiano Dias de. Caracterização espectrorradiométrica do minério magnesítico da porção Centro-Sul do Estado do Ceará. 2020. 99 f. Dissertação (Mestrado em Geologia) - Universidade Federal do Ceará, Fortaleza, 2020.
dc.identifier.uri.fl_str_mv http://www.repositorio.ufc.br/handle/riufc/57570
identifier_str_mv SOUZA, Cassiano Dias de. Caracterização espectrorradiométrica do minério magnesítico da porção Centro-Sul do Estado do Ceará. 2020. 99 f. Dissertação (Mestrado em Geologia) - Universidade Federal do Ceará, Fortaleza, 2020.
url http://www.repositorio.ufc.br/handle/riufc/57570
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