Aplicação de técnicas físicas na paleontologia: um estudo de fósseis da formação IPUBI – Bacia Sedimentar do Araripe

Detalhes bibliográficos
Ano de defesa: 2011
Autor(a) principal: Sousa Filho, Francisco Eduardo de
Orientador(a): Freire, Paulo de Tarso Cavalcante
Banca de defesa: Não Informado pela instituição
Tipo de documento: Tese
Tipo de acesso: Acesso aberto
Idioma: por
Instituição de defesa: Não Informado pela instituição
Programa de Pós-Graduação: Não Informado pela instituição
Departamento: Não Informado pela instituição
País: Não Informado pela instituição
Palavras-chave em Português:
Link de acesso: http://www.repositorio.ufc.br/handle/riufc/13319
Resumo: In this work we have used several physical techniques to characterize four different fossils form Ipubi Formation – Araripe Basin. The techniques used were: X-ray energy dispersive spectroscopy (EDS), Raman spectroscopy, X-ray diffraction (XRD), X-ray fluorescence, infrared spectroscopy and thermogravimetric analysis. The objective is characterizing fossils through several techniques, gibing new insights on a problem of paleontology. Through data obtained from this characterization we have tried to understand diverse fossilization processes that took place in Cretaceous fossils, aged as 100 million years old. We also hope give insights on the understanding of the paleoenvironmnet at the time when fossil specimens were lived. Initially, the bone of a theropode dinosaur from Ipubi Formation was characterized through EDS, X-ray fluorescence, infrared spectroscopy and XRD. From this study it was possible to observed that the main fossil constituent is hydroxiapatite, while the main matrix rock is calcium carbonate. As a complementary analysis, the fossil and the matrix rock were investigated by thermal analysis technique. In a second study a plant fossil – Brachyphyllum castilhoi – also extracted from Ibupi Formation, was investigated through EDS, infrared, X-ray fluorescence, Raman spectroscopy an X-ray diffraction. The original content of the plant was almost completely substituted by pyrite, showing the importance of this substance in the fossil preservation. Additionally, form this study, it was possible to suggest the temperature and the pH values of the paleolake form Cretaceous period in part of the Araripe Sedimentar Basin. This work was the first evidence that pyrite is related to a fossilization process from Ipubi Formation. Finally, two fish fossils, Vicntifer comptoni and Cladocyclus gardneri, were submitted to XRD and infrared spectroscopy techniques. It was observed that the principal phases from Cladocyclus gardneri are hydroxiapatite and calcite, although small traces of calcite is also present. In the matrix, the main phases are calcite, pyrite and quartz. Related to Vicntifer comptoni the principal phase is hydroxiapatite, while in the matrix the principal phase is gypsite, although small traces of other phases are also found. In this way, it was possible to conclude from this study that at least two different fossilization processes were responsible by the production of fossils from Ipubi Formation: (i) calcification, through the gypsite and calcite; (ii) piritization, through a complex chemical process.
id UFC-7_ed9b80faacd824414eefcdfafccb8c22
oai_identifier_str oai:repositorio.ufc.br:riufc/13319
network_acronym_str UFC-7
network_name_str Repositório Institucional da Universidade Federal do Ceará (UFC)
repository_id_str
spelling Sousa Filho, Francisco Eduardo deSaraiva, Antônio Álamo FeitosaFreire, Paulo de Tarso Cavalcante2015-09-21T17:10:12Z2015-09-21T17:10:12Z2011SOUSA FILHO, F. E. Aplicação de técnicas físicas na paleontologia: um estudo de fósseis da formação IPUBI - Bacia Sedimentar do Araripe. 2011. 101 f. Tese (Doutorado em Física) - Centro de Ciências, Universidade Federal do Ceará,Fortaleza, 2011.http://www.repositorio.ufc.br/handle/riufc/13319In this work we have used several physical techniques to characterize four different fossils form Ipubi Formation – Araripe Basin. The techniques used were: X-ray energy dispersive spectroscopy (EDS), Raman spectroscopy, X-ray diffraction (XRD), X-ray fluorescence, infrared spectroscopy and thermogravimetric analysis. The objective is characterizing fossils through several techniques, gibing new insights on a problem of paleontology. Through data obtained from this characterization we have tried to understand diverse fossilization processes that took place in Cretaceous fossils, aged as 100 million years old. We also hope give insights on the understanding of the paleoenvironmnet at the time when fossil specimens were lived. Initially, the bone of a theropode dinosaur from Ipubi Formation was characterized through EDS, X-ray fluorescence, infrared spectroscopy and XRD. From this study it was possible to observed that the main fossil constituent is hydroxiapatite, while the main matrix rock is calcium carbonate. As a complementary analysis, the fossil and the matrix rock were investigated by thermal analysis technique. In a second study a plant fossil – Brachyphyllum castilhoi – also extracted from Ibupi Formation, was investigated through EDS, infrared, X-ray fluorescence, Raman spectroscopy an X-ray diffraction. The original content of the plant was almost completely substituted by pyrite, showing the importance of this substance in the fossil preservation. Additionally, form this study, it was possible to suggest the temperature and the pH values of the paleolake form Cretaceous period in part of the Araripe Sedimentar Basin. This work was the first evidence that pyrite is related to a fossilization process from Ipubi Formation. Finally, two fish fossils, Vicntifer comptoni and Cladocyclus gardneri, were submitted to XRD and infrared spectroscopy techniques. It was observed that the principal phases from Cladocyclus gardneri are hydroxiapatite and calcite, although small traces of calcite is also present. In the matrix, the main phases are calcite, pyrite and quartz. Related to Vicntifer comptoni the principal phase is hydroxiapatite, while in the matrix the principal phase is gypsite, although small traces of other phases are also found. In this way, it was possible to conclude from this study that at least two different fossilization processes were responsible by the production of fossils from Ipubi Formation: (i) calcification, through the gypsite and calcite; (ii) piritization, through a complex chemical process.No presente trabalho são utilizadas diversas técnicas físicas para caracterizar quatro diferentes fósseis da Formação Ipubi – Bacia do Araripe. As técnicas aqui empregadas são: espectroscopia Raman, espectroscopia por energia dispersiva de raios – X (EDS), difração de raios – X, fluorescência de raios – X, espectroscopia no infravermelho e análisse termogravimétricas (TG). A intenção não é resolver nenhum novo problema relacionado à física, mas sim fazer uso dessas técnicas para caracterizar fósseis. Através de dados obtidos dessa caracterização tentou-se entender como se deram os diversos processos de fossilização ocorridos em alguns fósseis do período Cretáceo, com idades da ordem de 100 milhões de anos. Também, espera-se contribuir, com esses resultados, para a compreensão de como era o paleoambiente quando os espécimes fossilizados ainda tinham vida. Inicialmente caracterizou-se o osso de um dinossauro terópoda encontrado na Formação Ipubi utilizando técnicas espectroscópicas de EDS, fluorescência de raios – X, espectroscopia no infravermelho, além de difração de raios – X; com isso, foi possível observar-se a predominância de hidroxiapatita no fóssil e de carbonato de cálcio na rocha matriz. Complementarmente, submeteram-se as amostras do fóssil e da rocha matriz à análise de medidas térmicas. Num segundo estudo investigou-se uma planta fóssil, a Brachyphyllum castilhoi, também encontrada na Formação Ipubi, pelas técnicas espectroscópicas de EDS, infravermelho, fluorescência de raios – X, espectroscopia Raman e difração de raios – X. Percebeu-se que o conteúdo original da planta foi quase completamente substituído por pirita, o que mostra a importância dessa substância para a preservação do fóssil. Além disso, a partir desse achado, foi possível sugerir os valores da temperatura e do pH do paleolago existente no período Cretáceo em parte da Bacia Sedimentar do Araripe. Essa foi a primeira evidência encontrada de que a pirita está relacionada a um processo de fossilização na Formação Ipubi. Finalmente, submeteram-se os fósseis de dois peixes extintos, Vinctifer comptoni e Cladocyclus gardneri, às técnicas de difração de raios – X e espectroscopia infravermelho. Observou-se que as fases dominantes no caso do Cladocyclus gardneri são a hidroxiapatita e a calcita, além de existirem alguns traços de pirita. Na matriz observou-se que as fases dominantes são a calcita, a pirita e o quartzo. Já para o fóssil do Vinctifer comptoni observou-se que a fase dominante é a hidroxiapatita, enquanto que na matriz a fase dominante é a gipsita, embora existam traços de outras fases em menores quantidades. Assim, concluiu-se deste estudo que no mínimo dois diferentes processos de fossilização foram responsáveis pela produção de fósseis da Formação Ipubi: (i) calcificação, envolvendo tanto a gipsita quanto a calcita; (ii) piritização, via um complexo processo químico.FísicaPaleontologiaBacia Sedimentar do AraripeFósseisAplicação de técnicas físicas na paleontologia: um estudo de fósseis da formação IPUBI – Bacia Sedimentar do Araripeinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesisporreponame:Repositório Institucional da Universidade Federal do Ceará (UFC)instname:Universidade Federal do Ceará (UFC)instacron:UFCinfo:eu-repo/semantics/openAccessLICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://repositorio.ufc.br/bitstream/riufc/13319/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52ORIGINAL2011_tese_fedsousafilho.pdf2011_tese_fedsousafilho.pdfapplication/pdf2273151http://repositorio.ufc.br/bitstream/riufc/13319/3/2011_tese_fedsousafilho.pdf2eaf6bbd5e791bc52cbe48a7d5542c51MD53riufc/133192021-09-15 14:16:23.924oai:repositorio.ufc.br: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Repositório InstitucionalPUBhttp://www.repositorio.ufc.br/ri-oai/requestbu@ufc.br || repositorio@ufc.bropendoar:2021-09-15T17:16:23Repositório Institucional da Universidade Federal do Ceará (UFC) - Universidade Federal do Ceará (UFC)false
dc.title.pt_BR.fl_str_mv Aplicação de técnicas físicas na paleontologia: um estudo de fósseis da formação IPUBI – Bacia Sedimentar do Araripe
title Aplicação de técnicas físicas na paleontologia: um estudo de fósseis da formação IPUBI – Bacia Sedimentar do Araripe
spellingShingle Aplicação de técnicas físicas na paleontologia: um estudo de fósseis da formação IPUBI – Bacia Sedimentar do Araripe
Sousa Filho, Francisco Eduardo de
Física
Paleontologia
Bacia Sedimentar do Araripe
Fósseis
title_short Aplicação de técnicas físicas na paleontologia: um estudo de fósseis da formação IPUBI – Bacia Sedimentar do Araripe
title_full Aplicação de técnicas físicas na paleontologia: um estudo de fósseis da formação IPUBI – Bacia Sedimentar do Araripe
title_fullStr Aplicação de técnicas físicas na paleontologia: um estudo de fósseis da formação IPUBI – Bacia Sedimentar do Araripe
title_full_unstemmed Aplicação de técnicas físicas na paleontologia: um estudo de fósseis da formação IPUBI – Bacia Sedimentar do Araripe
title_sort Aplicação de técnicas físicas na paleontologia: um estudo de fósseis da formação IPUBI – Bacia Sedimentar do Araripe
author Sousa Filho, Francisco Eduardo de
author_facet Sousa Filho, Francisco Eduardo de
author_role author
dc.contributor.co-advisor.none.fl_str_mv Saraiva, Antônio Álamo Feitosa
dc.contributor.author.fl_str_mv Sousa Filho, Francisco Eduardo de
dc.contributor.advisor1.fl_str_mv Freire, Paulo de Tarso Cavalcante
contributor_str_mv Freire, Paulo de Tarso Cavalcante
dc.subject.por.fl_str_mv Física
Paleontologia
Bacia Sedimentar do Araripe
Fósseis
topic Física
Paleontologia
Bacia Sedimentar do Araripe
Fósseis
description In this work we have used several physical techniques to characterize four different fossils form Ipubi Formation – Araripe Basin. The techniques used were: X-ray energy dispersive spectroscopy (EDS), Raman spectroscopy, X-ray diffraction (XRD), X-ray fluorescence, infrared spectroscopy and thermogravimetric analysis. The objective is characterizing fossils through several techniques, gibing new insights on a problem of paleontology. Through data obtained from this characterization we have tried to understand diverse fossilization processes that took place in Cretaceous fossils, aged as 100 million years old. We also hope give insights on the understanding of the paleoenvironmnet at the time when fossil specimens were lived. Initially, the bone of a theropode dinosaur from Ipubi Formation was characterized through EDS, X-ray fluorescence, infrared spectroscopy and XRD. From this study it was possible to observed that the main fossil constituent is hydroxiapatite, while the main matrix rock is calcium carbonate. As a complementary analysis, the fossil and the matrix rock were investigated by thermal analysis technique. In a second study a plant fossil – Brachyphyllum castilhoi – also extracted from Ibupi Formation, was investigated through EDS, infrared, X-ray fluorescence, Raman spectroscopy an X-ray diffraction. The original content of the plant was almost completely substituted by pyrite, showing the importance of this substance in the fossil preservation. Additionally, form this study, it was possible to suggest the temperature and the pH values of the paleolake form Cretaceous period in part of the Araripe Sedimentar Basin. This work was the first evidence that pyrite is related to a fossilization process from Ipubi Formation. Finally, two fish fossils, Vicntifer comptoni and Cladocyclus gardneri, were submitted to XRD and infrared spectroscopy techniques. It was observed that the principal phases from Cladocyclus gardneri are hydroxiapatite and calcite, although small traces of calcite is also present. In the matrix, the main phases are calcite, pyrite and quartz. Related to Vicntifer comptoni the principal phase is hydroxiapatite, while in the matrix the principal phase is gypsite, although small traces of other phases are also found. In this way, it was possible to conclude from this study that at least two different fossilization processes were responsible by the production of fossils from Ipubi Formation: (i) calcification, through the gypsite and calcite; (ii) piritization, through a complex chemical process.
publishDate 2011
dc.date.issued.fl_str_mv 2011
dc.date.accessioned.fl_str_mv 2015-09-21T17:10:12Z
dc.date.available.fl_str_mv 2015-09-21T17:10:12Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/doctoralThesis
format doctoralThesis
status_str publishedVersion
dc.identifier.citation.fl_str_mv SOUSA FILHO, F. E. Aplicação de técnicas físicas na paleontologia: um estudo de fósseis da formação IPUBI - Bacia Sedimentar do Araripe. 2011. 101 f. Tese (Doutorado em Física) - Centro de Ciências, Universidade Federal do Ceará,Fortaleza, 2011.
dc.identifier.uri.fl_str_mv http://www.repositorio.ufc.br/handle/riufc/13319
identifier_str_mv SOUSA FILHO, F. E. Aplicação de técnicas físicas na paleontologia: um estudo de fósseis da formação IPUBI - Bacia Sedimentar do Araripe. 2011. 101 f. Tese (Doutorado em Física) - Centro de Ciências, Universidade Federal do Ceará,Fortaleza, 2011.
url http://www.repositorio.ufc.br/handle/riufc/13319
dc.language.iso.fl_str_mv por
language por
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.none.fl_str_mv reponame:Repositório Institucional da Universidade Federal do Ceará (UFC)
instname:Universidade Federal do Ceará (UFC)
instacron:UFC
instname_str Universidade Federal do Ceará (UFC)
instacron_str UFC
institution UFC
reponame_str Repositório Institucional da Universidade Federal do Ceará (UFC)
collection Repositório Institucional da Universidade Federal do Ceará (UFC)
bitstream.url.fl_str_mv http://repositorio.ufc.br/bitstream/riufc/13319/2/license.txt
http://repositorio.ufc.br/bitstream/riufc/13319/3/2011_tese_fedsousafilho.pdf
bitstream.checksum.fl_str_mv 8a4605be74aa9ea9d79846c1fba20a33
2eaf6bbd5e791bc52cbe48a7d5542c51
bitstream.checksumAlgorithm.fl_str_mv MD5
MD5
repository.name.fl_str_mv Repositório Institucional da Universidade Federal do Ceará (UFC) - Universidade Federal do Ceará (UFC)
repository.mail.fl_str_mv bu@ufc.br || repositorio@ufc.br
_version_ 1847793150885625856