Two-phase amoc recovery controlled by ocean-atmospheric coupling gateway in the western South Atlantic during the last interglacial
| Ano de defesa: | 2025 |
|---|---|
| Autor(a) principal: | |
| Orientador(a): | |
| Banca de defesa: | , , |
| Tipo de documento: | Dissertação |
| Tipo de acesso: | Acesso aberto |
| Idioma: | eng |
| Instituição de defesa: |
Não Informado pela instituição
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| Programa de Pós-Graduação: |
Não Informado pela instituição
|
| Departamento: |
Não Informado pela instituição
|
| País: |
Não Informado pela instituição
|
| Link de acesso: | https://app.uff.br/riuff/handle/1/40029 |
Resumo: | The Agulhas current retroflection process is linked to the formation of edges and filaments (Agulhas rings) through instabilities in the current, where part of these waters invades South Atlantic being incorporated into supertropical gyre (STG). The Agulhas Leakage (AL) provides an important source of density forcing the Atlantic meridional overturning circulation (AMOC) and their related waters-masses be carried towards the subpolar North Atlantic as the upper limb of the meridional circulation. The input of heat and salt throughout this route plays a key role in maintaining salinity, recovering the strength and stability of meridional circulation. The AL intensification during glacial Terminations has long been proposed as a required mechanism to return the AMOC to its interglacial mode and has a crucial role to occur the climate changes that precedes the deglaciation processes. However, the lack of records showing the downstream evolution of the AL signal and the large temporal differences between AL intensification and AMOC resumption cast doubt on this mechanism. The main objective of this study is to evaluate the extension and the role of the AL on AMOC recovery during glacial Termination II. Mg/Ca analyses were performed using ICP-OES applied in foraminiferal tests of Globorotalia inflata specie, aiming to reconstruct millenial- scale termocline paleotemperatures and paleosalinities from the western South Atlantic. During glacial Termination II, AL waters recirculated in the surface and thermocline subtropical South Atlantic until they were abruptly released to the North Atlantic in two pulses. These pulses were synchronous to two intervals of AMOC recovering recorded in 129 ka BP in the Labrador Sea, and after in 124 ka BP in the Nordic Sea during part of the Last Interglacial, both sites of North Atlantic Deep Water production. The mechanism proposed here suggests that the position of the South Equatorial current (SEC) bifurcation and the subtropical cells expansion and contraction are modulated by the Intertropical Convergence Zone (ITCZ) positioning. During glacial Terminations the ITCZ is positioned in the further southern position favoring the transport via Brazil Current, hence recirculating AL waters in the STG. At early MIS 5e the ITCZ shift to further northern positioning and favors the transport via North Brazil Current, releasing these waters toward North Atlantic. This energy partition between the northward and the southward branch of the South Atlantic western contour currents has an important role in the communication of the signal between southern and northern hemisphere and to modulate the AMOC intensity. Our hypothesis proposes connect AL intensification and the two-phase AMOC recovery during the Last Interglacial period. The SEC bifurcation acts as an ocean-atmospheric gateway controlling the northward transmission of salty anomalies from tropical regions in South Atlantic across the Equator, allowing the flux of dense AL waters to reach the sites of deep-water convection in the North Hemisphere. |
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Ballalai, João MarceloAlbuquerque, Ana Luiza Spadanohttp://lattes.cnpq.br/4016720596063058Santos, Thiago Pereira doshttp://lattes.cnpq.br/4183946723439928Pivel, María Alejandra Gómezhttp://lattes.cnpq.br/5411189668632895Strikís1948, Nicolas Misailidishttp://lattes.cnpq.br/3472432536871948Carvalho, Carla Regina Alveshttp://lattes.cnpq.br/8978430252253325http://lattes.cnpq.br/72710732034744092025-09-03T13:07:25Z2025-09-03T13:07:25ZBALLALAI, João Marcelo. Two-phase amoc recovery controlled by ocean-atmospheric coupling gateway in the western South Atlantic during the last interglacial. 2019. 71 f. Dissertação (Mestrado em Geociências - Geoquímica ambiental) - Universidade Federal Fluminense, Niterói, 2019.https://app.uff.br/riuff/handle/1/40029The Agulhas current retroflection process is linked to the formation of edges and filaments (Agulhas rings) through instabilities in the current, where part of these waters invades South Atlantic being incorporated into supertropical gyre (STG). The Agulhas Leakage (AL) provides an important source of density forcing the Atlantic meridional overturning circulation (AMOC) and their related waters-masses be carried towards the subpolar North Atlantic as the upper limb of the meridional circulation. The input of heat and salt throughout this route plays a key role in maintaining salinity, recovering the strength and stability of meridional circulation. The AL intensification during glacial Terminations has long been proposed as a required mechanism to return the AMOC to its interglacial mode and has a crucial role to occur the climate changes that precedes the deglaciation processes. However, the lack of records showing the downstream evolution of the AL signal and the large temporal differences between AL intensification and AMOC resumption cast doubt on this mechanism. The main objective of this study is to evaluate the extension and the role of the AL on AMOC recovery during glacial Termination II. Mg/Ca analyses were performed using ICP-OES applied in foraminiferal tests of Globorotalia inflata specie, aiming to reconstruct millenial- scale termocline paleotemperatures and paleosalinities from the western South Atlantic. During glacial Termination II, AL waters recirculated in the surface and thermocline subtropical South Atlantic until they were abruptly released to the North Atlantic in two pulses. These pulses were synchronous to two intervals of AMOC recovering recorded in 129 ka BP in the Labrador Sea, and after in 124 ka BP in the Nordic Sea during part of the Last Interglacial, both sites of North Atlantic Deep Water production. The mechanism proposed here suggests that the position of the South Equatorial current (SEC) bifurcation and the subtropical cells expansion and contraction are modulated by the Intertropical Convergence Zone (ITCZ) positioning. During glacial Terminations the ITCZ is positioned in the further southern position favoring the transport via Brazil Current, hence recirculating AL waters in the STG. At early MIS 5e the ITCZ shift to further northern positioning and favors the transport via North Brazil Current, releasing these waters toward North Atlantic. This energy partition between the northward and the southward branch of the South Atlantic western contour currents has an important role in the communication of the signal between southern and northern hemisphere and to modulate the AMOC intensity. Our hypothesis proposes connect AL intensification and the two-phase AMOC recovery during the Last Interglacial period. The SEC bifurcation acts as an ocean-atmospheric gateway controlling the northward transmission of salty anomalies from tropical regions in South Atlantic across the Equator, allowing the flux of dense AL waters to reach the sites of deep-water convection in the North Hemisphere.Conselho Nacional de Desenvolvimento Científico e TecnológicoCoordenação de Aperfeiçoamento de Pessoal de Nível SuperiorO processo de retroflexão da corrente das Agulhas está associado à formação de anéis e filamentos causados por instabilidades na corrente, onde parte de suas águas invade o Atlântico Sul sendo incorporadas no giro subtropical (do inglês, Subtropical Gyre, STG). As águas do vazamento das Agulhas (do inglês, Agulhas Leakage, AL) são uma importante fonte de densidade que força a Célula de Revolvimento Meridional do Atlântico (do inglês, Atlantic Meridional Overturning Circulation, AMOC) e as massas d’água associadas a serem carreadas para a região subpolar do Atlântico Norte como parte superior da circulação meridional. A entrada de calor e sal através dessa rota desempenha um papel importante na manutenção da salinidade, reestabelecendo a força e a estabilidade da circulação. A intensificação do AL durante as Terminações glaciais tem sido proposta como um mecanismo necessário para que haja a retomada do modo interglacial da AMOC e é parte fundamental para que ocorram as mudanças climáticas que precedem os processos de deglaciação. No entanto, a falta de registros mostrando a progressão do sinal do AL em seu curso e, a grande diferença temporal existente entre a intensificação do vazamento e a retomada da AMOC coloca em duvida este mecanismo. Este trabalho tem como objetivo central avaliar a extensão e o papel do AL no retorno da AMOC ao redor da Terminação glacial II. Foram desempenhadas análises da razão Mg/Ca através de ICP-OES aplicadas em testas do foraminífero planctônico da espécie Globorotalia inflata, afim de reconstituir em escala milenar as paleotemperaturas e paleosalinidades de termoclina da porção oeste do Atlântico Sul. Durante a Terminação glacial II, as águas do AL recircularam na região subtropical do Atlântico Sul até serem abruptamente liberadas em dois pulsos para o Atlântico Norte. Os dois pulsos ocorreram de forma sincrônica com os dois intervalos de reativação da AMOC registrados em 129 ka AP no Mar do Labrador, e depois em 124 ka AP no Mar Nórdico durante parte do Último Interglacial (MIS 5e), duas regiões produtoras de Água Profunda do Atlântico Norte (APAN). O mecanismo proposto neste trabalho sugere que a posição da bifurcação da Corrente Sul Equatorial (CSE) e a expansão e contração das células subtropicais são moduladas pela posição da Zona de Convergência Intertropical (do inglês, Intertropical Convergence Zone, ITCZ). Durante as Terminações glaciais, a ITCZ estaria em sua posição mais a sul, favorecendo o transporte via Corrente do Brasil e, consequentemente, recirculando as águas do AL no STG. No início do MIS 5e, a ITCZ se deslocaria para sua posição mais ao norte e favoreceria o transporte via Corrente Norte do Brasil (CNB), liberando essas águas em direção ao Atlântico Norte. Essa partição da energia entre os ramos norte e sul da corrente de contorno oeste do Atlântico Sul tem um importante papel na comunicação do sinal entre os hemisférios e na modulação da intensidade da AMOC. Nossa hipótese propõe conectar a intensificação do AL com o retorno da AMOC em duas fases durante parte do Último Interglacial. A bifurcação da CSE atua como um portão oceânico- atmosfera mediado pelo posicionamento médio da ITCZ que controla a transmissão para o norte das anomalias de salinidade através do Equador, permitindo que o fluxo de águas salinas do AL chegue aos locais de convecção de águas profundas no Hemisfério Norte.71 f.CC-BY-SAinfo:eu-repo/semantics/openAccessTwo-phase amoc recovery controlled by ocean-atmospheric coupling gateway in the western South Atlantic during the last interglacialinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisAgulhas LeakageSouth Atlantic thermoclineSouth Atlantic subtropical gyreInterhemispheric heat transferPaleoclimatologiaVariabilidade climáticaBiogeoquímica marinhaCirculação oceânica globalForaminíferos planctônicosAquecimento interglacialEventos de deglaciaçãoVazamento das AgulhasGiro subtropical do Atlântico SulTransferência de calor inter-hemisféricaTermoclina no Atlântico SulMestrado acadêmicoUniversidade Federal FluminenseInstituto de QuímicaPrograma de Pós-Graduação em Geociências (Geoquímica)2019Niterói, RJengreponame:Repositório Institucional da Universidade Federal Fluminense (RIUFF)instname:Universidade Federal Fluminense (UFF)instacron:UFFORIGINALDissertação - João Marcelo Ballalai.pdfDissertação - João Marcelo Ballalai.pdfapplication/pdf3266738https://app.uff.br/riuff/bitstream/1/40029/1/Disserta%c3%a7%c3%a3o%20-%20Jo%c3%a3o%20Marcelo%20Ballalai.pdfb94ceaedf95ce07394c76dc74c696219MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81866https://app.uff.br/riuff/bitstream/1/40029/2/license.txt43cd690d6a359e86c1fe3d5b7cba0c9bMD521/400292025-09-03 10:07:26.58oai:app.uff.br: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ório InstitucionalPUBhttps://app.uff.br/oai/requestriuff@id.uff.bropendoar:21202025-09-03T13:07:26Repositório Institucional da Universidade Federal Fluminense (RIUFF) - Universidade Federal Fluminense (UFF)false |
| dc.title.pt_BR.fl_str_mv |
Two-phase amoc recovery controlled by ocean-atmospheric coupling gateway in the western South Atlantic during the last interglacial |
| title |
Two-phase amoc recovery controlled by ocean-atmospheric coupling gateway in the western South Atlantic during the last interglacial |
| spellingShingle |
Two-phase amoc recovery controlled by ocean-atmospheric coupling gateway in the western South Atlantic during the last interglacial Ballalai, João Marcelo Agulhas Leakage South Atlantic thermocline South Atlantic subtropical gyre Interhemispheric heat transfer Paleoclimatologia Variabilidade climática Biogeoquímica marinha Circulação oceânica global Foraminíferos planctônicos Aquecimento interglacial Eventos de deglaciação Vazamento das Agulhas Giro subtropical do Atlântico Sul Transferência de calor inter-hemisférica Termoclina no Atlântico Sul |
| title_short |
Two-phase amoc recovery controlled by ocean-atmospheric coupling gateway in the western South Atlantic during the last interglacial |
| title_full |
Two-phase amoc recovery controlled by ocean-atmospheric coupling gateway in the western South Atlantic during the last interglacial |
| title_fullStr |
Two-phase amoc recovery controlled by ocean-atmospheric coupling gateway in the western South Atlantic during the last interglacial |
| title_full_unstemmed |
Two-phase amoc recovery controlled by ocean-atmospheric coupling gateway in the western South Atlantic during the last interglacial |
| title_sort |
Two-phase amoc recovery controlled by ocean-atmospheric coupling gateway in the western South Atlantic during the last interglacial |
| author |
Ballalai, João Marcelo |
| author_facet |
Ballalai, João Marcelo |
| author_role |
author |
| dc.contributor.authorLattes.pt_BR.fl_str_mv |
http://lattes.cnpq.br/7271073203474409 |
| dc.contributor.author.fl_str_mv |
Ballalai, João Marcelo |
| dc.contributor.advisor1.fl_str_mv |
Albuquerque, Ana Luiza Spadano |
| dc.contributor.advisor1Lattes.fl_str_mv |
http://lattes.cnpq.br/4016720596063058 |
| dc.contributor.advisor-co1.fl_str_mv |
Santos, Thiago Pereira dos |
| dc.contributor.advisor-co1Lattes.fl_str_mv |
http://lattes.cnpq.br/4183946723439928 |
| dc.contributor.referee1.fl_str_mv |
Pivel, María Alejandra Gómez |
| dc.contributor.referee1Lattes.fl_str_mv |
http://lattes.cnpq.br/5411189668632895 |
| dc.contributor.referee2.fl_str_mv |
Strikís1948, Nicolas Misailidis |
| dc.contributor.referee2Lattes.fl_str_mv |
http://lattes.cnpq.br/3472432536871948 |
| dc.contributor.referee3.fl_str_mv |
Carvalho, Carla Regina Alves |
| dc.contributor.referee3Lattes.fl_str_mv |
http://lattes.cnpq.br/8978430252253325 |
| contributor_str_mv |
Albuquerque, Ana Luiza Spadano Santos, Thiago Pereira dos Pivel, María Alejandra Gómez Strikís1948, Nicolas Misailidis Carvalho, Carla Regina Alves |
| dc.subject.keyword.pt_BR.fl_str_mv |
Agulhas Leakage South Atlantic thermocline South Atlantic subtropical gyre Interhemispheric heat transfer |
| topic |
Agulhas Leakage South Atlantic thermocline South Atlantic subtropical gyre Interhemispheric heat transfer Paleoclimatologia Variabilidade climática Biogeoquímica marinha Circulação oceânica global Foraminíferos planctônicos Aquecimento interglacial Eventos de deglaciação Vazamento das Agulhas Giro subtropical do Atlântico Sul Transferência de calor inter-hemisférica Termoclina no Atlântico Sul |
| dc.subject.descriptor.pt_BR.fl_str_mv |
Paleoclimatologia Variabilidade climática Biogeoquímica marinha Circulação oceânica global Foraminíferos planctônicos Aquecimento interglacial Eventos de deglaciação |
| dc.subject.keywordother.pt_BR.fl_str_mv |
Vazamento das Agulhas Giro subtropical do Atlântico Sul Transferência de calor inter-hemisférica Termoclina no Atlântico Sul |
| description |
The Agulhas current retroflection process is linked to the formation of edges and filaments (Agulhas rings) through instabilities in the current, where part of these waters invades South Atlantic being incorporated into supertropical gyre (STG). The Agulhas Leakage (AL) provides an important source of density forcing the Atlantic meridional overturning circulation (AMOC) and their related waters-masses be carried towards the subpolar North Atlantic as the upper limb of the meridional circulation. The input of heat and salt throughout this route plays a key role in maintaining salinity, recovering the strength and stability of meridional circulation. The AL intensification during glacial Terminations has long been proposed as a required mechanism to return the AMOC to its interglacial mode and has a crucial role to occur the climate changes that precedes the deglaciation processes. However, the lack of records showing the downstream evolution of the AL signal and the large temporal differences between AL intensification and AMOC resumption cast doubt on this mechanism. The main objective of this study is to evaluate the extension and the role of the AL on AMOC recovery during glacial Termination II. Mg/Ca analyses were performed using ICP-OES applied in foraminiferal tests of Globorotalia inflata specie, aiming to reconstruct millenial- scale termocline paleotemperatures and paleosalinities from the western South Atlantic. During glacial Termination II, AL waters recirculated in the surface and thermocline subtropical South Atlantic until they were abruptly released to the North Atlantic in two pulses. These pulses were synchronous to two intervals of AMOC recovering recorded in 129 ka BP in the Labrador Sea, and after in 124 ka BP in the Nordic Sea during part of the Last Interglacial, both sites of North Atlantic Deep Water production. The mechanism proposed here suggests that the position of the South Equatorial current (SEC) bifurcation and the subtropical cells expansion and contraction are modulated by the Intertropical Convergence Zone (ITCZ) positioning. During glacial Terminations the ITCZ is positioned in the further southern position favoring the transport via Brazil Current, hence recirculating AL waters in the STG. At early MIS 5e the ITCZ shift to further northern positioning and favors the transport via North Brazil Current, releasing these waters toward North Atlantic. This energy partition between the northward and the southward branch of the South Atlantic western contour currents has an important role in the communication of the signal between southern and northern hemisphere and to modulate the AMOC intensity. Our hypothesis proposes connect AL intensification and the two-phase AMOC recovery during the Last Interglacial period. The SEC bifurcation acts as an ocean-atmospheric gateway controlling the northward transmission of salty anomalies from tropical regions in South Atlantic across the Equator, allowing the flux of dense AL waters to reach the sites of deep-water convection in the North Hemisphere. |
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2025 |
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2025-09-03T13:07:25Z |
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2025-09-03T13:07:25Z |
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BALLALAI, João Marcelo. Two-phase amoc recovery controlled by ocean-atmospheric coupling gateway in the western South Atlantic during the last interglacial. 2019. 71 f. Dissertação (Mestrado em Geociências - Geoquímica ambiental) - Universidade Federal Fluminense, Niterói, 2019. |
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https://app.uff.br/riuff/handle/1/40029 |
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BALLALAI, João Marcelo. Two-phase amoc recovery controlled by ocean-atmospheric coupling gateway in the western South Atlantic during the last interglacial. 2019. 71 f. Dissertação (Mestrado em Geociências - Geoquímica ambiental) - Universidade Federal Fluminense, Niterói, 2019. |
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