Síntese, estrutura cristalina e molecular de complexos nos sistemas 1,3-bis(p-azofenil)triazenido e 3-(2-flúorofenil)-1-(4-nitrofenil)triazenido/Pd(II)
Ano de defesa: | 2002 |
---|---|
Autor(a) principal: | |
Orientador(a): | |
Banca de defesa: | , |
Tipo de documento: | Dissertação |
Tipo de acesso: | Acesso aberto |
Idioma: | por |
Instituição de defesa: |
Universidade Federal de Santa Maria
Centro de Ciências Naturais e Exatas |
Programa de Pós-Graduação: |
Programa de Pós-Graduação em Química
|
Departamento: |
Química
|
País: |
Brasil
|
Palavras-chave em Português: | |
Área do conhecimento CNPq: | |
Link de acesso: | http://repositorio.ufsm.br/handle/1/27037 |
Resumo: | The reaction between palladium chloride and 1,3-bis(pazophenyl)triazenido/pyridine yields the complex trans-bis[1,3-bis(pazophenyl)triazenido]-bis(pyridine)palladium(II), complex (a), which crystallizes in the triclinic crystal system, space group P ī, Z = 2, with cell parameters a = 8,8634(7), b = 15,1791(2), c = 22,5932(2) Å, α = 109,328(6)°, β = 94,053(5)°, γ = 95,511(8)°. The final crystal structure refinement converge to R1 = 0,0780 e wR2 = 0,2503. Complex (a) shows two triazenidos ligands coordinated as terminal ligands to palladium(II), and its the coordination sphere is completed by two pyridine ligands. The coordination geometry is square planar. In these reaction the palladium chloride was dissolved in ammonium hydroxide and the triazene was dissolved in THF. The reaction between palladium chloride and 3-(2-fluorophenyl)-1-(4- nitrophenyl)triazenido/pyridine yields the complex trans-Bis[3-(2- fluorophenyl)-1-(4-nitrophenyl)triazenido]bis-(pyridine)palladium(II), complex (b), which crystallizes in the triclinic crystal system, space group P ī, Z = 1, with cell parameters a = 8,941(2), b = 9,73(2), c = 10,9449(10) Å , α = 110,058(14)°, β = 93,437(13)°, γ = 109,01(19)°. The final crystal structure refinement converge to R1 = 0,045 e wR2 = 0,105. Complex (b) shows two triazenidos ligands coordinated as terminal ligands in the palladium(II) and its the coordination sphere is completed by two pyridine ligands. The coordination geometry is square planar. In these reaction the palladium chloride was dissolved in ammonium hydroxide and the triazene was dissolved in THF. |
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2022-11-22T13:29:28Z2022-11-22T13:29:28Z2002-08-05http://repositorio.ufsm.br/handle/1/27037The reaction between palladium chloride and 1,3-bis(pazophenyl)triazenido/pyridine yields the complex trans-bis[1,3-bis(pazophenyl)triazenido]-bis(pyridine)palladium(II), complex (a), which crystallizes in the triclinic crystal system, space group P ī, Z = 2, with cell parameters a = 8,8634(7), b = 15,1791(2), c = 22,5932(2) Å, α = 109,328(6)°, β = 94,053(5)°, γ = 95,511(8)°. The final crystal structure refinement converge to R1 = 0,0780 e wR2 = 0,2503. Complex (a) shows two triazenidos ligands coordinated as terminal ligands to palladium(II), and its the coordination sphere is completed by two pyridine ligands. The coordination geometry is square planar. In these reaction the palladium chloride was dissolved in ammonium hydroxide and the triazene was dissolved in THF. The reaction between palladium chloride and 3-(2-fluorophenyl)-1-(4- nitrophenyl)triazenido/pyridine yields the complex trans-Bis[3-(2- fluorophenyl)-1-(4-nitrophenyl)triazenido]bis-(pyridine)palladium(II), complex (b), which crystallizes in the triclinic crystal system, space group P ī, Z = 1, with cell parameters a = 8,941(2), b = 9,73(2), c = 10,9449(10) Å , α = 110,058(14)°, β = 93,437(13)°, γ = 109,01(19)°. The final crystal structure refinement converge to R1 = 0,045 e wR2 = 0,105. Complex (b) shows two triazenidos ligands coordinated as terminal ligands in the palladium(II) and its the coordination sphere is completed by two pyridine ligands. The coordination geometry is square planar. In these reaction the palladium chloride was dissolved in ammonium hydroxide and the triazene was dissolved in THF.A reação entre cloreto de paládio(II) e 1,3-bis(pazofenil)triazenido/piridina originou o complexo trans-bis[1,3-bis(pazofenil)triazenido]-bis(piridina)paládio(II), complexo (a), que cristaliza no sistema cristalino triclínico, grupo espacial P ī , Z = 2, com parâmetros de cela a = 8,8634(7), b = 15,1791(2), c = 22,5932(2) Å , α = 109,328(6)°, β = 94,053(5)°, γ = 95,511(8)°. O refinamento da estrutura cristalina e molecular convergiu aos índices de discordância R1 = 0,0780 e wR2 = 0,2503. O complexo (a) apresenta dois ligantes triazenidos coordenados de forma terminal ao paládio(II). A esfera de coordenação quadrado-plana é completada com dois ligantes piridinas. Na reação o cloreto de paládio(II) foi dissolvido em hidróxido de amônia e o triazeno em THF. A reação entre cloreto de paládio(II) e 3-(2-flúorofenil)-1-(4- nitrofenil)triazenido/ piridina originou o complexo trans-bis[3-(2-flúorofenil)-1- (4-nitrofenil)triazenido]-bis(piridina)paládio(II), complexo (b), que cristaliza no sistema cristalino triclínico, grupo espacial P ī , Z = 1, com parâmetros de cela a = 8,941(2), b = 9,73(2), c = 10,9449(10) Å , α = 110,058(14)°, β = 93,437(13)°, γ = 109,01(19)°. O refinamento da estrutura cristalina e molecular convergiu aos índices de discordância R1 = 0,045 e wR2 = 0,105. O complexo (b) apresenta dois ligantes triazenidos coordenados de forma terminal ao paládio(II). A esfera de coordenação quadrada plana é completada com dois ligantes piridinas. Na reação o cloreto de paládio(II) foi dissolvido em hidróxido de amônia e o triazeno em THF.Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPESporUniversidade Federal de Santa MariaCentro de Ciências Naturais e ExatasPrograma de Pós-Graduação em QuímicaUFSMBrasilQuímicaAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessQuímicaQuímica inorgânicaEstrutura molecularEstrutura cristalinaTriazenosCNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICASíntese, estrutura cristalina e molecular de complexos nos sistemas 1,3-bis(p-azofenil)triazenido e 3-(2-flúorofenil)-1-(4-nitrofenil)triazenido/Pd(II)Synthesis, crystal and molecular structures of complexes in the systems 1,3-bis(p-azophenyl)triazenido and 3-(2-fluorophenyl)-1-(4-nitrophenyl)triazenido/Pd(II)info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisHorner, Manfredohttp://lattes.cnpq.br/8922528250830998Bordinhão, JairoCasagrande Junior, Osvaldo de Lazarohttp://lattes.cnpq.br/6602490339479877Visentin, Lorenzo do Canto1006000000006006006006006005997bd94-cd6e-43ac-8db1-93b1f40cc68417739e5c-0b7d-4576-a188-6acbfe6494301133b2aa-f7d1-4e6f-9da4-b614c677d17de3814618-6623-47f2-aa82-43758306c30freponame:Manancial - Repositório Digital da UFSMinstname:Universidade Federal de Santa Maria (UFSM)instacron:UFSMLICENSElicense.txtlicense.txttext/plain; charset=utf-81956http://repositorio.ufsm.br/bitstream/1/27037/3/license.txt2f0571ecee68693bd5cd3f17c1e075dfMD53CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8805http://repositorio.ufsm.br/bitstream/1/27037/2/license_rdf4460e5956bc1d1639be9ae6146a50347MD52ORIGINALDIS_PPGQUÍMICA_2002_VISENTIN_LORENZO.pdfDIS_PPGQUÍMICA_2002_VISENTIN_LORENZO.pdfDissertação de Mestradoapplication/pdf1342993http://repositorio.ufsm.br/bitstream/1/27037/1/DIS_PPGQU%c3%8dMICA_2002_VISENTIN_LORENZO.pdfe9fe118f457d761d123f2d06f1d71cc4MD511/270372022-11-22 10:29:28.341oai:repositorio.ufsm.br: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ório Institucionalhttp://repositorio.ufsm.br/PUBhttp://repositorio.ufsm.br/oai/requestopendoar:39132022-11-22T13:29:28Manancial - Repositório Digital da UFSM - Universidade Federal de Santa Maria (UFSM)false |
dc.title.por.fl_str_mv |
Síntese, estrutura cristalina e molecular de complexos nos sistemas 1,3-bis(p-azofenil)triazenido e 3-(2-flúorofenil)-1-(4-nitrofenil)triazenido/Pd(II) |
dc.title.alternative.eng.fl_str_mv |
Synthesis, crystal and molecular structures of complexes in the systems 1,3-bis(p-azophenyl)triazenido and 3-(2-fluorophenyl)-1-(4-nitrophenyl)triazenido/Pd(II) |
title |
Síntese, estrutura cristalina e molecular de complexos nos sistemas 1,3-bis(p-azofenil)triazenido e 3-(2-flúorofenil)-1-(4-nitrofenil)triazenido/Pd(II) |
spellingShingle |
Síntese, estrutura cristalina e molecular de complexos nos sistemas 1,3-bis(p-azofenil)triazenido e 3-(2-flúorofenil)-1-(4-nitrofenil)triazenido/Pd(II) Visentin, Lorenzo do Canto Química Química inorgânica Estrutura molecular Estrutura cristalina Triazenos CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA |
title_short |
Síntese, estrutura cristalina e molecular de complexos nos sistemas 1,3-bis(p-azofenil)triazenido e 3-(2-flúorofenil)-1-(4-nitrofenil)triazenido/Pd(II) |
title_full |
Síntese, estrutura cristalina e molecular de complexos nos sistemas 1,3-bis(p-azofenil)triazenido e 3-(2-flúorofenil)-1-(4-nitrofenil)triazenido/Pd(II) |
title_fullStr |
Síntese, estrutura cristalina e molecular de complexos nos sistemas 1,3-bis(p-azofenil)triazenido e 3-(2-flúorofenil)-1-(4-nitrofenil)triazenido/Pd(II) |
title_full_unstemmed |
Síntese, estrutura cristalina e molecular de complexos nos sistemas 1,3-bis(p-azofenil)triazenido e 3-(2-flúorofenil)-1-(4-nitrofenil)triazenido/Pd(II) |
title_sort |
Síntese, estrutura cristalina e molecular de complexos nos sistemas 1,3-bis(p-azofenil)triazenido e 3-(2-flúorofenil)-1-(4-nitrofenil)triazenido/Pd(II) |
author |
Visentin, Lorenzo do Canto |
author_facet |
Visentin, Lorenzo do Canto |
author_role |
author |
dc.contributor.advisor1.fl_str_mv |
Horner, Manfredo |
dc.contributor.advisor1Lattes.fl_str_mv |
http://lattes.cnpq.br/8922528250830998 |
dc.contributor.referee1.fl_str_mv |
Bordinhão, Jairo |
dc.contributor.referee2.fl_str_mv |
Casagrande Junior, Osvaldo de Lazaro |
dc.contributor.authorLattes.fl_str_mv |
http://lattes.cnpq.br/6602490339479877 |
dc.contributor.author.fl_str_mv |
Visentin, Lorenzo do Canto |
contributor_str_mv |
Horner, Manfredo Bordinhão, Jairo Casagrande Junior, Osvaldo de Lazaro |
dc.subject.por.fl_str_mv |
Química Química inorgânica Estrutura molecular Estrutura cristalina Triazenos |
topic |
Química Química inorgânica Estrutura molecular Estrutura cristalina Triazenos CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA |
dc.subject.cnpq.fl_str_mv |
CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA |
description |
The reaction between palladium chloride and 1,3-bis(pazophenyl)triazenido/pyridine yields the complex trans-bis[1,3-bis(pazophenyl)triazenido]-bis(pyridine)palladium(II), complex (a), which crystallizes in the triclinic crystal system, space group P ī, Z = 2, with cell parameters a = 8,8634(7), b = 15,1791(2), c = 22,5932(2) Å, α = 109,328(6)°, β = 94,053(5)°, γ = 95,511(8)°. The final crystal structure refinement converge to R1 = 0,0780 e wR2 = 0,2503. Complex (a) shows two triazenidos ligands coordinated as terminal ligands to palladium(II), and its the coordination sphere is completed by two pyridine ligands. The coordination geometry is square planar. In these reaction the palladium chloride was dissolved in ammonium hydroxide and the triazene was dissolved in THF. The reaction between palladium chloride and 3-(2-fluorophenyl)-1-(4- nitrophenyl)triazenido/pyridine yields the complex trans-Bis[3-(2- fluorophenyl)-1-(4-nitrophenyl)triazenido]bis-(pyridine)palladium(II), complex (b), which crystallizes in the triclinic crystal system, space group P ī, Z = 1, with cell parameters a = 8,941(2), b = 9,73(2), c = 10,9449(10) Å , α = 110,058(14)°, β = 93,437(13)°, γ = 109,01(19)°. The final crystal structure refinement converge to R1 = 0,045 e wR2 = 0,105. Complex (b) shows two triazenidos ligands coordinated as terminal ligands in the palladium(II) and its the coordination sphere is completed by two pyridine ligands. The coordination geometry is square planar. In these reaction the palladium chloride was dissolved in ammonium hydroxide and the triazene was dissolved in THF. |
publishDate |
2002 |
dc.date.issued.fl_str_mv |
2002-08-05 |
dc.date.accessioned.fl_str_mv |
2022-11-22T13:29:28Z |
dc.date.available.fl_str_mv |
2022-11-22T13:29:28Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/masterThesis |
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masterThesis |
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publishedVersion |
dc.identifier.uri.fl_str_mv |
http://repositorio.ufsm.br/handle/1/27037 |
url |
http://repositorio.ufsm.br/handle/1/27037 |
dc.language.iso.fl_str_mv |
por |
language |
por |
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100600000000 |
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600 600 600 600 600 |
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Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess |
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Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ |
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openAccess |
dc.publisher.none.fl_str_mv |
Universidade Federal de Santa Maria Centro de Ciências Naturais e Exatas |
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Programa de Pós-Graduação em Química |
dc.publisher.initials.fl_str_mv |
UFSM |
dc.publisher.country.fl_str_mv |
Brasil |
dc.publisher.department.fl_str_mv |
Química |
publisher.none.fl_str_mv |
Universidade Federal de Santa Maria Centro de Ciências Naturais e Exatas |
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