Análises de metais pesados em corpos hídricos urbanos na cidade de Cascavel

Detalhes bibliográficos
Ano de defesa: 2024
Autor(a) principal: Wolff, Paulo Sérgio lattes
Orientador(a): Sampaio, Silvio César
Banca de defesa: Dieter, Jonathan, Reis, Ralpho Rinaldo dos, Santos, Reginaldo Ferreira, Frigo, Jiam Pires
Tipo de documento: Tese
Tipo de acesso: Acesso aberto
Idioma: por
Instituição de defesa: Universidade Estadual do Oeste do Paraná
Cascavel
Programa de Pós-Graduação: Programa de Pós-Graduação em Engenharia Agrícola
Departamento: Centro de Ciências Exatas e Tecnológicas
País: Brasil
Palavras-chave em Português:
Palavras-chave em Inglês:
Área do conhecimento CNPq:
Link de acesso: https://tede.unioeste.br/handle/tede/7395
Resumo: Understanding traces of metals in urban water bodies has been crucial to comprehend the impact of anthropogenic activities, mostly in persistent pollutants context. This is especially important when these water bodies serve as the primary water supply due to their proximity to urban environments. Thus, this study aims at evaluating the potential ecological risk and their respective sources of contamination by heavy metals in urban water bodies in the of Cascavel city, Paraná. The treatments included spatial points (urban spring, urban median thalweg, and urban mouth) of six rivers in Cascavel-PR: Cascavel and Quati Rivers, Rio, Bezerra streamlet, River of Antas, Lageado Clarito, and Sanga Amambay. Samples were collected in eight replications using an Ekman dredger collector and well packaged to be transported and analyzed regarding texture, carbon dioxide, and heavy metal concentrations. Chemical elements such as cadmium (Cd), copper (Cu), lead (Pb), chromium (Cr), iron (Fe), manganese (Mn), nickel (Ni), and zinc (Zn) were quantified by atomic absorption spectrometry. While heavy metal values were compared with the ones established as limits by CONAMA. Heavy metals concentrations along the studied rivers at the spring, median thalweg, and at the river mouth were related to soil particle size, hydrodynamics, total organic carbon, and anthropogenic activities. Copper and nickel levels exceeded level-2 limit when compared to the ones established by CONAMA in all rivers, indicating a need for monitoring. In contrast, cadmium, lead, and chromium did not exceed the level 2 limit and are not a cause for concern. While cadmium, lead and chromium did not exceed the level-2 limit, thus, they are not a problem yet. Iron levels were substantially high in all studied rivers, consequently, regular and thorough monitoring must occur, likely due to geogenic effects.
id UNIOESTE-1_f5b050f3f75f19e3c5de3e2f4665b5ca
oai_identifier_str oai:tede.unioeste.br:tede/7395
network_acronym_str UNIOESTE-1
network_name_str Biblioteca Digital de Teses e Dissertações do UNIOESTE
repository_id_str
spelling Sampaio, Silvio CésarBoas, Márcio Antonio VilasDieter, JonathanReis, Ralpho Rinaldo dosSantos, Reginaldo FerreiraFrigo, Jiam Pireshttp://lattes.cnpq.br/9210122457365421Wolff, Paulo Sérgio2024-10-03T20:02:10Z2024-05-29Wolff, Paulo Sérgio. Análises de metais pesados em corpos hídricos urbanos na cidade de Cascavel. 2024. 69 f. Tese( Doutorado em Engenharia Agrícola) - Universidade Estadual do Oeste do Paraná, Cascavel.https://tede.unioeste.br/handle/tede/7395Understanding traces of metals in urban water bodies has been crucial to comprehend the impact of anthropogenic activities, mostly in persistent pollutants context. This is especially important when these water bodies serve as the primary water supply due to their proximity to urban environments. Thus, this study aims at evaluating the potential ecological risk and their respective sources of contamination by heavy metals in urban water bodies in the of Cascavel city, Paraná. The treatments included spatial points (urban spring, urban median thalweg, and urban mouth) of six rivers in Cascavel-PR: Cascavel and Quati Rivers, Rio, Bezerra streamlet, River of Antas, Lageado Clarito, and Sanga Amambay. Samples were collected in eight replications using an Ekman dredger collector and well packaged to be transported and analyzed regarding texture, carbon dioxide, and heavy metal concentrations. Chemical elements such as cadmium (Cd), copper (Cu), lead (Pb), chromium (Cr), iron (Fe), manganese (Mn), nickel (Ni), and zinc (Zn) were quantified by atomic absorption spectrometry. While heavy metal values were compared with the ones established as limits by CONAMA. Heavy metals concentrations along the studied rivers at the spring, median thalweg, and at the river mouth were related to soil particle size, hydrodynamics, total organic carbon, and anthropogenic activities. Copper and nickel levels exceeded level-2 limit when compared to the ones established by CONAMA in all rivers, indicating a need for monitoring. In contrast, cadmium, lead, and chromium did not exceed the level 2 limit and are not a cause for concern. While cadmium, lead and chromium did not exceed the level-2 limit, thus, they are not a problem yet. Iron levels were substantially high in all studied rivers, consequently, regular and thorough monitoring must occur, likely due to geogenic effects.O conhecimento acerca de traços de metais em corpos hídricos urbanos é muito importante para entender o impacto das atividades antrópicas no contexto de poluentes persistentes. Principalmente, quando estes corpos hídricos se caracterizam como a principal fonte de abastecimento devido à proximidade desses com o meio urbano. Neste contexto, este estudo tem como objetivo avaliar o potencial de risco ecológico e as respectivas fontes de contaminação de metais pesados de corpos hídricos urbanos na cidade de Cascavel-PR. Os tratamentos foram pontos espaciais (nascente urbana, talvegue mediano urbano e foz urbana) de seis rios da cidade de Cascavel-PR, são eles: Rio Cascavel, Rio Quati, Córrego Bezerra, Rio das Antas, Lageado Clarito e o Rio Sanga Amambay. As amostras foram coletadas com oito repetições usando coletor Ekman dredger, as quais foram acondicionadas adequadamente para transporte e análise da textura dos sedimentos, do teor de carbono e teor de concentração de metais pesados. Os elementos cádmio (Cd), cobre (Cu), chumbo (Pb), cromo (Cr), ferro (Fe), manganês (Mn), níquel (Ni) e zinco (Zn) foram quantificados por espectrometria de absorção atômica. Os valores de metais pesados foram comparados com os limites dos determinados pelo CONAMA. As concentrações dos metais pesados estudados ao longo dos rios pesquisados, tanto na nascente, como no talvegue mediano e na foz, foram dependentes da granulometria do solo, da hidrodinâmica, do carbono orgânico total e das ações antrópicas. Os metais pesados cobre e níquel estiveram presentes em todos os rios acima do limite do nível 2, determinados pelo CONAMA, dados que sugerem monitoramento. Enquanto cádmio, chumbo e cromo não ultrapassaram o limite do nível 2 e não geram preocupações. Os níveis observados do elemento químico ferro foram substancialmente elevados em todos os rios, por conseguinte, faz-se necessário o monitoramento regular e minucioso, provavelmente em função de efeitos geogênicos.Submitted by Edineia Teixeira (edineia.teixeira@unioeste.br) on 2024-10-03T20:02:10Z No. of bitstreams: 1 Paulo sérgio Wolff.pdf: 4532078 bytes, checksum: 10bccccf6065e558527575edb9627a19 (MD5)Made available in DSpace on 2024-10-03T20:02:10Z (GMT). No. of bitstreams: 1 Paulo sérgio Wolff.pdf: 4532078 bytes, checksum: 10bccccf6065e558527575edb9627a19 (MD5) Previous issue date: 2024-05-29application/pdfpor6588633818200016417500Universidade Estadual do Oeste do ParanáCascavelPrograma de Pós-Graduação em Engenharia AgrícolaUNIOESTEBrasilCentro de Ciências Exatas e Tecnológicashttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessÁguaMetais pesadosSaúdeSedimentoUrbanização.Heavy metalsHealthSedimentUrbanizationWater.RECURSOS HÍDRICOS E SANEAMENTO AMBIENTALAnálises de metais pesados em corpos hídricos urbanos na cidade de CascavelAnalysis of heavy metals in urban water bodies in the city of Cascavelinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesis-53476924504160521296006002214374442868382015reponame:Biblioteca Digital de Teses e Dissertações do UNIOESTEinstname:Universidade Estadual do Oeste do Paraná (UNIOESTE)instacron:UNIOESTEORIGINALPaulo sérgio Wolff.pdfPaulo sérgio Wolff.pdfapplication/pdf4532078http://tede.unioeste.br:8080/tede/bitstream/tede/7395/2/Paulo+s%C3%A9rgio+Wolff.pdf10bccccf6065e558527575edb9627a19MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-82165http://tede.unioeste.br:8080/tede/bitstream/tede/7395/1/license.txtbd3efa91386c1718a7f26a329fdcb468MD51tede/73952024-10-03 17:02:10.956oai:tede.unioeste.br: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Biblioteca Digital de Teses e Dissertaçõeshttp://tede.unioeste.br/PUBhttp://tede.unioeste.br/oai/requestbiblioteca.repositorio@unioeste.bropendoar:2024-10-03T20:02:10Biblioteca Digital de Teses e Dissertações do UNIOESTE - Universidade Estadual do Oeste do Paraná (UNIOESTE)false
dc.title.por.fl_str_mv Análises de metais pesados em corpos hídricos urbanos na cidade de Cascavel
dc.title.alternative.eng.fl_str_mv Analysis of heavy metals in urban water bodies in the city of Cascavel
title Análises de metais pesados em corpos hídricos urbanos na cidade de Cascavel
spellingShingle Análises de metais pesados em corpos hídricos urbanos na cidade de Cascavel
Wolff, Paulo Sérgio
Água
Metais pesados
Saúde
Sedimento
Urbanização.
Heavy metals
Health
Sediment
Urbanization
Water.
RECURSOS HÍDRICOS E SANEAMENTO AMBIENTAL
title_short Análises de metais pesados em corpos hídricos urbanos na cidade de Cascavel
title_full Análises de metais pesados em corpos hídricos urbanos na cidade de Cascavel
title_fullStr Análises de metais pesados em corpos hídricos urbanos na cidade de Cascavel
title_full_unstemmed Análises de metais pesados em corpos hídricos urbanos na cidade de Cascavel
title_sort Análises de metais pesados em corpos hídricos urbanos na cidade de Cascavel
author Wolff, Paulo Sérgio
author_facet Wolff, Paulo Sérgio
author_role author
dc.contributor.advisor1.fl_str_mv Sampaio, Silvio César
dc.contributor.advisor-co1.fl_str_mv Boas, Márcio Antonio Vilas
dc.contributor.referee1.fl_str_mv Dieter, Jonathan
dc.contributor.referee2.fl_str_mv Reis, Ralpho Rinaldo dos
dc.contributor.referee3.fl_str_mv Santos, Reginaldo Ferreira
dc.contributor.referee4.fl_str_mv Frigo, Jiam Pires
dc.contributor.authorLattes.fl_str_mv http://lattes.cnpq.br/9210122457365421
dc.contributor.author.fl_str_mv Wolff, Paulo Sérgio
contributor_str_mv Sampaio, Silvio César
Boas, Márcio Antonio Vilas
Dieter, Jonathan
Reis, Ralpho Rinaldo dos
Santos, Reginaldo Ferreira
Frigo, Jiam Pires
dc.subject.por.fl_str_mv Água
Metais pesados
Saúde
Sedimento
Urbanização.
topic Água
Metais pesados
Saúde
Sedimento
Urbanização.
Heavy metals
Health
Sediment
Urbanization
Water.
RECURSOS HÍDRICOS E SANEAMENTO AMBIENTAL
dc.subject.eng.fl_str_mv Heavy metals
Health
Sediment
Urbanization
Water.
dc.subject.cnpq.fl_str_mv RECURSOS HÍDRICOS E SANEAMENTO AMBIENTAL
description Understanding traces of metals in urban water bodies has been crucial to comprehend the impact of anthropogenic activities, mostly in persistent pollutants context. This is especially important when these water bodies serve as the primary water supply due to their proximity to urban environments. Thus, this study aims at evaluating the potential ecological risk and their respective sources of contamination by heavy metals in urban water bodies in the of Cascavel city, Paraná. The treatments included spatial points (urban spring, urban median thalweg, and urban mouth) of six rivers in Cascavel-PR: Cascavel and Quati Rivers, Rio, Bezerra streamlet, River of Antas, Lageado Clarito, and Sanga Amambay. Samples were collected in eight replications using an Ekman dredger collector and well packaged to be transported and analyzed regarding texture, carbon dioxide, and heavy metal concentrations. Chemical elements such as cadmium (Cd), copper (Cu), lead (Pb), chromium (Cr), iron (Fe), manganese (Mn), nickel (Ni), and zinc (Zn) were quantified by atomic absorption spectrometry. While heavy metal values were compared with the ones established as limits by CONAMA. Heavy metals concentrations along the studied rivers at the spring, median thalweg, and at the river mouth were related to soil particle size, hydrodynamics, total organic carbon, and anthropogenic activities. Copper and nickel levels exceeded level-2 limit when compared to the ones established by CONAMA in all rivers, indicating a need for monitoring. In contrast, cadmium, lead, and chromium did not exceed the level 2 limit and are not a cause for concern. While cadmium, lead and chromium did not exceed the level-2 limit, thus, they are not a problem yet. Iron levels were substantially high in all studied rivers, consequently, regular and thorough monitoring must occur, likely due to geogenic effects.
publishDate 2024
dc.date.accessioned.fl_str_mv 2024-10-03T20:02:10Z
dc.date.issued.fl_str_mv 2024-05-29
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/doctoralThesis
format doctoralThesis
status_str publishedVersion
dc.identifier.citation.fl_str_mv Wolff, Paulo Sérgio. Análises de metais pesados em corpos hídricos urbanos na cidade de Cascavel. 2024. 69 f. Tese( Doutorado em Engenharia Agrícola) - Universidade Estadual do Oeste do Paraná, Cascavel.
dc.identifier.uri.fl_str_mv https://tede.unioeste.br/handle/tede/7395
identifier_str_mv Wolff, Paulo Sérgio. Análises de metais pesados em corpos hídricos urbanos na cidade de Cascavel. 2024. 69 f. Tese( Doutorado em Engenharia Agrícola) - Universidade Estadual do Oeste do Paraná, Cascavel.
url https://tede.unioeste.br/handle/tede/7395
dc.language.iso.fl_str_mv por
language por
dc.relation.program.fl_str_mv -5347692450416052129
dc.relation.confidence.fl_str_mv 600
600
dc.relation.department.fl_str_mv 2214374442868382015
dc.rights.driver.fl_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Estadual do Oeste do Paraná
Cascavel
dc.publisher.program.fl_str_mv Programa de Pós-Graduação em Engenharia Agrícola
dc.publisher.initials.fl_str_mv UNIOESTE
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv Centro de Ciências Exatas e Tecnológicas
publisher.none.fl_str_mv Universidade Estadual do Oeste do Paraná
Cascavel
dc.source.none.fl_str_mv reponame:Biblioteca Digital de Teses e Dissertações do UNIOESTE
instname:Universidade Estadual do Oeste do Paraná (UNIOESTE)
instacron:UNIOESTE
instname_str Universidade Estadual do Oeste do Paraná (UNIOESTE)
instacron_str UNIOESTE
institution UNIOESTE
reponame_str Biblioteca Digital de Teses e Dissertações do UNIOESTE
collection Biblioteca Digital de Teses e Dissertações do UNIOESTE
bitstream.url.fl_str_mv http://tede.unioeste.br:8080/tede/bitstream/tede/7395/2/Paulo+s%C3%A9rgio+Wolff.pdf
http://tede.unioeste.br:8080/tede/bitstream/tede/7395/1/license.txt
bitstream.checksum.fl_str_mv 10bccccf6065e558527575edb9627a19
bd3efa91386c1718a7f26a329fdcb468
bitstream.checksumAlgorithm.fl_str_mv MD5
MD5
repository.name.fl_str_mv Biblioteca Digital de Teses e Dissertações do UNIOESTE - Universidade Estadual do Oeste do Paraná (UNIOESTE)
repository.mail.fl_str_mv biblioteca.repositorio@unioeste.br
_version_ 1851949242265894912