Unravelling palaeoceanographic and paleoenvironmental changes during periods of major carbon-cycle perturbations and climate warming: new insights from the late Albian-early Turonian Sergipe-Alagoas Basin (northeastern Brazil) and the middle Eocene Elaz Basin (eastern Turkey)

Detalhes bibliográficos
Ano de defesa: 2025
Autor(a) principal: Cesari, Valentina
Orientador(a): Não Informado pela instituição
Banca de defesa: Não Informado pela instituição
Tipo de documento: Tese
Tipo de acesso: Acesso aberto
Idioma: eng
Instituição de defesa: Biblioteca Digitais de Teses e Dissertações da USP
Programa de Pós-Graduação: Não Informado pela instituição
Departamento: Não Informado pela instituição
País: Não Informado pela instituição
Palavras-chave em Português:
Link de acesso: https://www.teses.usp.br/teses/disponiveis/44/44145/tde-12012026-090105/
Resumo: The climatic history of the Earth is characterized by long- and short-term variations, including extreme conditions that have profoundly impacted ecosystems. This study aims to reconstruct palaeoceanographic changes and paleoenvironmental conditions in two stratigraphic successions that record major events of intense climatic and carbon-cycle perturbations. The first case study presents new integrated geochemical, magnetic, and mineralogical data from a core drilled through late Albian to early Turonian sediments in the Sergipe-Alagoas Basin, off northeastern Brazil, which includes one of the few records of the Oceanic Anoxic Event 2 (OAE2) from the South Atlantic Ocean. The obtained results show a major change in sedimentation in the middle Cenomanian when mixed carbonate and siliciclastic deposits were replaced by chalk. This transition reflects a major change in palaeoceanographic conditions toward a more stable circulation mode, with better connection between the different oceanic basins, persistent currents, and bottom ventilation. Cyclicity in the ln(K/Al) record indicates insolation-driven fluctuations in aridity and humidity. A new age model, based on the stable 405 kyr-long eccentricity cycles, places the onset of the OAE2 carbon isotope excursion at ~94.74 Ma. Sedimentation during the OAE2 seemed to be mainly controlled by long-term processes and local effects rather than global perturbations. Variations in ln(Sr/Ca) indicate increased primary productivity persisting for two long eccentricity cycles, while transient reducing conditions, inferred from loss in magnetic susceptibility compared to Fe, persisted across the earliest long eccentricity maximum phase, at least. The second case study focuses on a detailed petrographic analysis of bioclastic carbonate turbidites from the middle Eocene Baskil section of the Neotethyan Elaz Basin, eastern Turkey. The Baskil section is a global reference for the Middle Eocene Climatic Optimum (MECO), a transient (~500 ka) warming event interrupting a long-term cooling trend. In terms of duration and isotopic signature this event is more similar to an OAE than a hyperthermal. Turbidites in the Baskil section are mainly composed of intrabasinal carbonate clasts sourced from carbonate-ramp factories. Bioclastic detrital modes document changes in sediment sources triggered by the combination of local factors and global palaeoceanographic and climatic changes. The progressive shallowing of the intrabasinal source area is related to a regression which occurred in the Neotethys from ~41 Ma until the Eocene/Oligocene boundary (~34 Ma). The permanent decrease in abundance of the orthophragminids parallels the long-term climatic trend towards cooling conditions after the MECO. However, their abrupt reduction, coinciding with increased water column stratification, was also influenced by regional changes in ocean circulation after ~40 Ma. These changes negatively impacted the specialized orthophragminids thorough increased hydrodynamism in the meso-oligophotic zone, resulting in decreased carbonate production at this depth. The preponderance of encrusting foraminifera coincided with the deterioration of environmental conditions and basin restriction within the Neotethys. In conclusion, these two case studies highlight the crucial role of regional changes in ocean circulation in modulating both sedimentary and ecological responses during periods of climatic and carbon-cycle perturbations and allow for a better understanding of the interplay between global and local palaeoceanographic and paleoclimatic processes.
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spelling Unravelling palaeoceanographic and paleoenvironmental changes during periods of major carbon-cycle perturbations and climate warming: new insights from the late Albian-early Turonian Sergipe-Alagoas Basin (northeastern Brazil) and the middle Eocene Elaz Basin (eastern Turkey)Mudanças paleoceanográficas e paleoambientais durante períodos de perturbações do ciclo do carbono e aquecimento climático: novas evidências das bacias de Sergipe-Alagoas (Albiano Superior-Turoniano Inferior, nordeste do Brasil) e Elaz (Eoceno Médio, leste da Turquia)Carbon cycleCarbonatesCarbonatosCiclo do carbonoForçantes orbitaisOrbital forcingPalaeoceanographyPaleoceanografiaPaleoclimaPaleoclimateThe climatic history of the Earth is characterized by long- and short-term variations, including extreme conditions that have profoundly impacted ecosystems. This study aims to reconstruct palaeoceanographic changes and paleoenvironmental conditions in two stratigraphic successions that record major events of intense climatic and carbon-cycle perturbations. The first case study presents new integrated geochemical, magnetic, and mineralogical data from a core drilled through late Albian to early Turonian sediments in the Sergipe-Alagoas Basin, off northeastern Brazil, which includes one of the few records of the Oceanic Anoxic Event 2 (OAE2) from the South Atlantic Ocean. The obtained results show a major change in sedimentation in the middle Cenomanian when mixed carbonate and siliciclastic deposits were replaced by chalk. This transition reflects a major change in palaeoceanographic conditions toward a more stable circulation mode, with better connection between the different oceanic basins, persistent currents, and bottom ventilation. Cyclicity in the ln(K/Al) record indicates insolation-driven fluctuations in aridity and humidity. A new age model, based on the stable 405 kyr-long eccentricity cycles, places the onset of the OAE2 carbon isotope excursion at ~94.74 Ma. Sedimentation during the OAE2 seemed to be mainly controlled by long-term processes and local effects rather than global perturbations. Variations in ln(Sr/Ca) indicate increased primary productivity persisting for two long eccentricity cycles, while transient reducing conditions, inferred from loss in magnetic susceptibility compared to Fe, persisted across the earliest long eccentricity maximum phase, at least. The second case study focuses on a detailed petrographic analysis of bioclastic carbonate turbidites from the middle Eocene Baskil section of the Neotethyan Elaz Basin, eastern Turkey. The Baskil section is a global reference for the Middle Eocene Climatic Optimum (MECO), a transient (~500 ka) warming event interrupting a long-term cooling trend. In terms of duration and isotopic signature this event is more similar to an OAE than a hyperthermal. Turbidites in the Baskil section are mainly composed of intrabasinal carbonate clasts sourced from carbonate-ramp factories. Bioclastic detrital modes document changes in sediment sources triggered by the combination of local factors and global palaeoceanographic and climatic changes. The progressive shallowing of the intrabasinal source area is related to a regression which occurred in the Neotethys from ~41 Ma until the Eocene/Oligocene boundary (~34 Ma). The permanent decrease in abundance of the orthophragminids parallels the long-term climatic trend towards cooling conditions after the MECO. However, their abrupt reduction, coinciding with increased water column stratification, was also influenced by regional changes in ocean circulation after ~40 Ma. These changes negatively impacted the specialized orthophragminids thorough increased hydrodynamism in the meso-oligophotic zone, resulting in decreased carbonate production at this depth. The preponderance of encrusting foraminifera coincided with the deterioration of environmental conditions and basin restriction within the Neotethys. In conclusion, these two case studies highlight the crucial role of regional changes in ocean circulation in modulating both sedimentary and ecological responses during periods of climatic and carbon-cycle perturbations and allow for a better understanding of the interplay between global and local palaeoceanographic and paleoclimatic processes.A história climática da Terra é marcada por variações de curta e longa duração, as vezes extremas, que impactaram profundamente os ecossistemas. Este estudo busca reconstruir mudanças paleoceanográficas e paleoambientais em duas sucessões estratigráficas que registram importantes perturbações climáticas e do ciclo do carbono. O primeiro caso apresenta dados de geoquímica, magnetismo e mineralogia de um testemunho da Bacia Sergipe-Alagoas (nordeste do Brasil), que abrange o intervalo do Albiano superior ao Turoniano inferior, incluindo um dos poucos registros do Evento Anóxico Oceânico 2 (OAE2) no Atlântico Sul. Os resultados mostram uma mudança maior na sedimentação durante o Cenomano médio, quando depósitos mistos carbonáticos e siliciclásticos foram substituídos por chalk. Essa transição reflete um modo de circulação mais estável, com melhor conexão entre bacias oceânicas, correntes persistentes e ventilação do fundo marinho. A ciclicidade no ln(K/Al) indica flutuações entre períodos áridos e úmidos. Um novo modelo de idade, construído com base em ciclos de excentricidade de 405 mil anos, data o início do OAE2 em ~94,74 Ma. A sedimentação durante o OAE2 foi controlada principalmente por processos de longa duração e fatores locais. As variações em ln(Sr/Ca) indicam um aumento da produtividade primária que se manteve por dois ciclos de longa excentricidade, enquanto condições redutoras transitórias, inferidas pela queda da suscetibilidade magnética em relação ao Fe, persistiram ao menos durante o primeiro máximo de longa excentricidade. O segundo estudo de caso se concentra em uma análise petrográfica detalhada de turbiditos da seção de Baskil (Bacia de Elaz, leste da Turquia), de idade eocênica. Essa seção constitui referência global para o Ótimo Climático do Eoceno Médio (MECO), um evento de aquecimento transitório (~500 ka) que interrompeu uma tendência de resfriamento de longa duração. Em termos de duração e assinatura isotópica, o MECO se assemelha mais a um OAE do que a um evento hipertermal. Os turbiditos da seção de Baskil são compostos principalmente por bioclastos provenientes da uma rampa carbonática. Os modos detríticos documentam mudanças nas fontes de sedimento, desencadeadas pela combinação de fatores locais e mudanças paleoceanográficas e climáticas globais. O progressivo afundamento da área-fonte intrabasinal está relacionado a uma regressão que ocorreu na Neotétis entre ~41 e 34 Ma. A diminuição permanente na abundância de ortophragminídeos reflete a tendência global de resfriamento após o MECO. Entretanto, sua redução abrupta, que ocorreu juntamente com o aumento da estratificação da coluna dágua, também foi influenciada por mudanças regionais na circulação oceânica após ~40 Ma. Essas mudanças impactaram negativamente os ortophragminídeos, devido ao maior hidrodinamismo na zona meso-oligofótica, resultando na diminuição da produção de carbonato nessa profundidade. Por outro lado, a preponderância de foraminíferos incrustantes relaciona-se à deterioração das condições ambientais durante o progressivo fechamento da Neotétis. Em conclusão, os dois estudos de caso ressaltam o papel essencial das mudanças na circulação oceânica regional na modulação das respostas sedimentares e ecológicas durante eventos importantes de perturbações climáticas e do ciclo do carbono, contribuindo também para uma melhor compreensão da interação entre processos paleoceanográficos e paleoclimáticos globais e locais.Biblioteca Digitais de Teses e Dissertações da USPJovane, LuigiCesari, Valentina2025-11-18info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesisapplication/pdfhttps://www.teses.usp.br/teses/disponiveis/44/44145/tde-12012026-090105/reponame:Biblioteca Digital de Teses e Dissertações da USPinstname:Universidade de São Paulo (USP)instacron:USPReter o conteúdo por motivos de patente, publicação e/ou direitos autoriais.info:eu-repo/semantics/openAccesseng2026-01-12T11:16:02Zoai:teses.usp.br:tde-12012026-090105Biblioteca Digital de Teses e Dissertaçõeshttp://www.teses.usp.br/PUBhttp://www.teses.usp.br/cgi-bin/mtd2br.plvirginia@if.usp.br|| atendimento@aguia.usp.br||virginia@if.usp.bropendoar:27212026-01-12T11:16:02Biblioteca Digital de Teses e Dissertações da USP - Universidade de São Paulo (USP)false
dc.title.none.fl_str_mv Unravelling palaeoceanographic and paleoenvironmental changes during periods of major carbon-cycle perturbations and climate warming: new insights from the late Albian-early Turonian Sergipe-Alagoas Basin (northeastern Brazil) and the middle Eocene Elaz Basin (eastern Turkey)
Mudanças paleoceanográficas e paleoambientais durante períodos de perturbações do ciclo do carbono e aquecimento climático: novas evidências das bacias de Sergipe-Alagoas (Albiano Superior-Turoniano Inferior, nordeste do Brasil) e Elaz (Eoceno Médio, leste da Turquia)
title Unravelling palaeoceanographic and paleoenvironmental changes during periods of major carbon-cycle perturbations and climate warming: new insights from the late Albian-early Turonian Sergipe-Alagoas Basin (northeastern Brazil) and the middle Eocene Elaz Basin (eastern Turkey)
spellingShingle Unravelling palaeoceanographic and paleoenvironmental changes during periods of major carbon-cycle perturbations and climate warming: new insights from the late Albian-early Turonian Sergipe-Alagoas Basin (northeastern Brazil) and the middle Eocene Elaz Basin (eastern Turkey)
Cesari, Valentina
Carbon cycle
Carbonates
Carbonatos
Ciclo do carbono
Forçantes orbitais
Orbital forcing
Palaeoceanography
Paleoceanografia
Paleoclima
Paleoclimate
title_short Unravelling palaeoceanographic and paleoenvironmental changes during periods of major carbon-cycle perturbations and climate warming: new insights from the late Albian-early Turonian Sergipe-Alagoas Basin (northeastern Brazil) and the middle Eocene Elaz Basin (eastern Turkey)
title_full Unravelling palaeoceanographic and paleoenvironmental changes during periods of major carbon-cycle perturbations and climate warming: new insights from the late Albian-early Turonian Sergipe-Alagoas Basin (northeastern Brazil) and the middle Eocene Elaz Basin (eastern Turkey)
title_fullStr Unravelling palaeoceanographic and paleoenvironmental changes during periods of major carbon-cycle perturbations and climate warming: new insights from the late Albian-early Turonian Sergipe-Alagoas Basin (northeastern Brazil) and the middle Eocene Elaz Basin (eastern Turkey)
title_full_unstemmed Unravelling palaeoceanographic and paleoenvironmental changes during periods of major carbon-cycle perturbations and climate warming: new insights from the late Albian-early Turonian Sergipe-Alagoas Basin (northeastern Brazil) and the middle Eocene Elaz Basin (eastern Turkey)
title_sort Unravelling palaeoceanographic and paleoenvironmental changes during periods of major carbon-cycle perturbations and climate warming: new insights from the late Albian-early Turonian Sergipe-Alagoas Basin (northeastern Brazil) and the middle Eocene Elaz Basin (eastern Turkey)
author Cesari, Valentina
author_facet Cesari, Valentina
author_role author
dc.contributor.none.fl_str_mv Jovane, Luigi
dc.contributor.author.fl_str_mv Cesari, Valentina
dc.subject.por.fl_str_mv Carbon cycle
Carbonates
Carbonatos
Ciclo do carbono
Forçantes orbitais
Orbital forcing
Palaeoceanography
Paleoceanografia
Paleoclima
Paleoclimate
topic Carbon cycle
Carbonates
Carbonatos
Ciclo do carbono
Forçantes orbitais
Orbital forcing
Palaeoceanography
Paleoceanografia
Paleoclima
Paleoclimate
description The climatic history of the Earth is characterized by long- and short-term variations, including extreme conditions that have profoundly impacted ecosystems. This study aims to reconstruct palaeoceanographic changes and paleoenvironmental conditions in two stratigraphic successions that record major events of intense climatic and carbon-cycle perturbations. The first case study presents new integrated geochemical, magnetic, and mineralogical data from a core drilled through late Albian to early Turonian sediments in the Sergipe-Alagoas Basin, off northeastern Brazil, which includes one of the few records of the Oceanic Anoxic Event 2 (OAE2) from the South Atlantic Ocean. The obtained results show a major change in sedimentation in the middle Cenomanian when mixed carbonate and siliciclastic deposits were replaced by chalk. This transition reflects a major change in palaeoceanographic conditions toward a more stable circulation mode, with better connection between the different oceanic basins, persistent currents, and bottom ventilation. Cyclicity in the ln(K/Al) record indicates insolation-driven fluctuations in aridity and humidity. A new age model, based on the stable 405 kyr-long eccentricity cycles, places the onset of the OAE2 carbon isotope excursion at ~94.74 Ma. Sedimentation during the OAE2 seemed to be mainly controlled by long-term processes and local effects rather than global perturbations. Variations in ln(Sr/Ca) indicate increased primary productivity persisting for two long eccentricity cycles, while transient reducing conditions, inferred from loss in magnetic susceptibility compared to Fe, persisted across the earliest long eccentricity maximum phase, at least. The second case study focuses on a detailed petrographic analysis of bioclastic carbonate turbidites from the middle Eocene Baskil section of the Neotethyan Elaz Basin, eastern Turkey. The Baskil section is a global reference for the Middle Eocene Climatic Optimum (MECO), a transient (~500 ka) warming event interrupting a long-term cooling trend. In terms of duration and isotopic signature this event is more similar to an OAE than a hyperthermal. Turbidites in the Baskil section are mainly composed of intrabasinal carbonate clasts sourced from carbonate-ramp factories. Bioclastic detrital modes document changes in sediment sources triggered by the combination of local factors and global palaeoceanographic and climatic changes. The progressive shallowing of the intrabasinal source area is related to a regression which occurred in the Neotethys from ~41 Ma until the Eocene/Oligocene boundary (~34 Ma). The permanent decrease in abundance of the orthophragminids parallels the long-term climatic trend towards cooling conditions after the MECO. However, their abrupt reduction, coinciding with increased water column stratification, was also influenced by regional changes in ocean circulation after ~40 Ma. These changes negatively impacted the specialized orthophragminids thorough increased hydrodynamism in the meso-oligophotic zone, resulting in decreased carbonate production at this depth. The preponderance of encrusting foraminifera coincided with the deterioration of environmental conditions and basin restriction within the Neotethys. In conclusion, these two case studies highlight the crucial role of regional changes in ocean circulation in modulating both sedimentary and ecological responses during periods of climatic and carbon-cycle perturbations and allow for a better understanding of the interplay between global and local palaeoceanographic and paleoclimatic processes.
publishDate 2025
dc.date.none.fl_str_mv 2025-11-18
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/doctoralThesis
format doctoralThesis
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://www.teses.usp.br/teses/disponiveis/44/44145/tde-12012026-090105/
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dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv
dc.rights.driver.fl_str_mv Reter o conteúdo por motivos de patente, publicação e/ou direitos autoriais.
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Reter o conteúdo por motivos de patente, publicação e/ou direitos autoriais.
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
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dc.publisher.none.fl_str_mv Biblioteca Digitais de Teses e Dissertações da USP
publisher.none.fl_str_mv Biblioteca Digitais de Teses e Dissertações da USP
dc.source.none.fl_str_mv
reponame:Biblioteca Digital de Teses e Dissertações da USP
instname:Universidade de São Paulo (USP)
instacron:USP
instname_str Universidade de São Paulo (USP)
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institution USP
reponame_str Biblioteca Digital de Teses e Dissertações da USP
collection Biblioteca Digital de Teses e Dissertações da USP
repository.name.fl_str_mv Biblioteca Digital de Teses e Dissertações da USP - Universidade de São Paulo (USP)
repository.mail.fl_str_mv virginia@if.usp.br|| atendimento@aguia.usp.br||virginia@if.usp.br
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