Development of chromatographic method for applications in quality control and authenticity of distilled beverages

Detalhes bibliográficos
Ano de defesa: 2023
Autor(a) principal: Nascimento, Hélio Oliveira do
Orientador(a): Nascimento, Ronaldo Ferreira do
Banca de defesa: Não Informado pela instituição
Tipo de documento: Tese
Tipo de acesso: Acesso aberto
Idioma: eng
Instituição de defesa: Não Informado pela instituição
Programa de Pós-Graduação: Não Informado pela instituição
Departamento: Não Informado pela instituição
País: Não Informado pela instituição
Área do conhecimento CNPq:
CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA::QUIMICA ANALITICA
Link de acesso: http://repositorio.ufc.br/handle/riufc/77018
Resumo: Cachaça and whiskey distilled beverages are widely consumed in Brazil and their acceptance is closely related to quality control in their production. However, these beverages are frequent targets for adulteration, which alters the quality of these products and can lead to health problems for consumers. This work comprises three chapters where the first deals with a literature review on applications of the Solid-phase microextraction (SPME) technique in cachaça and whisky, the second was the development of a new methodology for the analysis of higher alcohols, n-butanol and total esters using gas chromatography coupled to barrier discharge ionization detector (GC-BID) and SPME via headspace (HS) as a sample preparation method for the analysis of 25 samples of cachaça and 26 of whiskeys, in the third chapter 16 samples of original and 14 counterfeit whiskeys were differentiated through principal component analysis (PCA) applied to data obtained by the HS-SPME-GC-BID method and aldehydes derivatized by 2,4-dinitrophenylhydrazine (2,4-DNPH) in high performance liquid chromatography coupled to diode array detector (HPLC-DAD). The results showed that the use of SPME in chromatographic analyzes of distilled beverages is a powerful tool that allows both the development of methods for quality control applications and the differentiation between original and counterfeit beverages.
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spelling Nascimento, Hélio Oliveira doNascimento, Ronaldo Ferreira do2024-06-10T11:59:59Z2024-06-10T11:59:59Z2023NASCIMENTO, Hélio Oliveira do. Development of chromatographic method for applications in quality control and authenticity of distilled beverages. 2023. 71 f. Tese (Doutorado em Química) – Universidade Federal do Ceará, Fortaleza, 2023.http://repositorio.ufc.br/handle/riufc/77018Cachaça and whiskey distilled beverages are widely consumed in Brazil and their acceptance is closely related to quality control in their production. However, these beverages are frequent targets for adulteration, which alters the quality of these products and can lead to health problems for consumers. This work comprises three chapters where the first deals with a literature review on applications of the Solid-phase microextraction (SPME) technique in cachaça and whisky, the second was the development of a new methodology for the analysis of higher alcohols, n-butanol and total esters using gas chromatography coupled to barrier discharge ionization detector (GC-BID) and SPME via headspace (HS) as a sample preparation method for the analysis of 25 samples of cachaça and 26 of whiskeys, in the third chapter 16 samples of original and 14 counterfeit whiskeys were differentiated through principal component analysis (PCA) applied to data obtained by the HS-SPME-GC-BID method and aldehydes derivatized by 2,4-dinitrophenylhydrazine (2,4-DNPH) in high performance liquid chromatography coupled to diode array detector (HPLC-DAD). The results showed that the use of SPME in chromatographic analyzes of distilled beverages is a powerful tool that allows both the development of methods for quality control applications and the differentiation between original and counterfeit beverages.A cachaça e o uísque são bebidas destiladas amplamente consumidas no Brasil e sua aceitação está intimamente relacionada ao controle de qualidade em sua produção. No entanto, essas bebidas são alvos frequentes de adulteração, o que altera a qualidade desses produtos e pode levar a problemas de saúde para os consumidores. Este trabalho é composto por três capítulos onde o primeiro trata de uma revisão de literatura sobre aplicações da técnica de microextração em fase sólida (SPME) em cachaça e uísque, o segundo foi o desenvolvimento de uma nova metodologia para a análise de álcoois superiores, n-butanol e total ésteres utilizando cromatografia gasosa acoplada a detector de ionização por descarga de barreira (GC-BID) e SPME via headspace (HS) como método de preparo de amostras para análise de 25 amostras de cachaça e 26 de uísques, no terceiro capítulo 16 amostras originais e 14 uísques falsificados foram diferenciados por meio de análise de componentes principais (PCA) aplicada aos dados obtidos pelo método HS-SPME-GC-BID e aldeídos derivados por 2,4-dinitrofenilhidrazina (2,4-DNPH) em cromatografia líquida de alta eficiência acoplada a arranjo de diodos detector (HPLC-DAD). Os resultados mostraram que o uso de SPME em análises cromatográficas de bebidas destiladas é uma ferramenta poderosa que permite tanto o desenvolvimento de métodos para aplicações no controle de qualidade quanto para a diferenciação entre bebidas originais e falsificadas.Development of chromatographic method for applications in quality control and authenticity of distilled beveragesDesenvolvimento de método cromatográfico para aplicações no controle de qualidade e autenticidade de bebidas destiladasinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesisMicroextração em fase sólidaCromatografia gasosa acoplada a detector de ionização por descarga de barreiraCromatografia líquida de alta eficiência acoplada a detector de arranjo de diodosCachaçaUísqueAnálise de componentes principaisSolid-phase microextractionGas chromatography coupled to barrier discharge ionization detectorHigh performance liquid chromatography coupled to diode array detectorCachaçaWhiskyPrincipal component analysisCNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA::QUIMICA ANALITICAinfo:eu-repo/semantics/openAccessengreponame:Repositório Institucional da Universidade Federal do Ceará (UFC)instname:Universidade Federal do Ceará (UFC)instacron:UFChttp://lattes.cnpq.br/7176379246203706http://lattes.cnpq.br/63454406662735612024-06-10ORIGINAL2023_tese_honascimento.pdf2023_tese_honascimento.pdfapplication/pdf1681844http://repositorio.ufc.br/bitstream/riufc/77018/3/2023_tese_honascimento.pdffb3a6078041ff8e39d27e26b79204038MD53LICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://repositorio.ufc.br/bitstream/riufc/77018/4/license.txt8a4605be74aa9ea9d79846c1fba20a33MD54riufc/770182024-06-10 09:00:01.178oai:repositorio.ufc.br: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Repositório InstitucionalPUBhttp://www.repositorio.ufc.br/ri-oai/requestbu@ufc.br || repositorio@ufc.bropendoar:2024-06-10T12:00:01Repositório Institucional da Universidade Federal do Ceará (UFC) - Universidade Federal do Ceará (UFC)false
dc.title.pt_BR.fl_str_mv Development of chromatographic method for applications in quality control and authenticity of distilled beverages
dc.title.alternative.pt_BR.fl_str_mv Desenvolvimento de método cromatográfico para aplicações no controle de qualidade e autenticidade de bebidas destiladas
title Development of chromatographic method for applications in quality control and authenticity of distilled beverages
spellingShingle Development of chromatographic method for applications in quality control and authenticity of distilled beverages
Nascimento, Hélio Oliveira do
CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA::QUIMICA ANALITICA
Microextração em fase sólida
Cromatografia gasosa acoplada a detector de ionização por descarga de barreira
Cromatografia líquida de alta eficiência acoplada a detector de arranjo de diodos
Cachaça
Uísque
Análise de componentes principais
Solid-phase microextraction
Gas chromatography coupled to barrier discharge ionization detector
High performance liquid chromatography coupled to diode array detector
Cachaça
Whisky
Principal component analysis
title_short Development of chromatographic method for applications in quality control and authenticity of distilled beverages
title_full Development of chromatographic method for applications in quality control and authenticity of distilled beverages
title_fullStr Development of chromatographic method for applications in quality control and authenticity of distilled beverages
title_full_unstemmed Development of chromatographic method for applications in quality control and authenticity of distilled beverages
title_sort Development of chromatographic method for applications in quality control and authenticity of distilled beverages
author Nascimento, Hélio Oliveira do
author_facet Nascimento, Hélio Oliveira do
author_role author
dc.contributor.author.fl_str_mv Nascimento, Hélio Oliveira do
dc.contributor.advisor1.fl_str_mv Nascimento, Ronaldo Ferreira do
contributor_str_mv Nascimento, Ronaldo Ferreira do
dc.subject.cnpq.fl_str_mv CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA::QUIMICA ANALITICA
topic CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA::QUIMICA ANALITICA
Microextração em fase sólida
Cromatografia gasosa acoplada a detector de ionização por descarga de barreira
Cromatografia líquida de alta eficiência acoplada a detector de arranjo de diodos
Cachaça
Uísque
Análise de componentes principais
Solid-phase microextraction
Gas chromatography coupled to barrier discharge ionization detector
High performance liquid chromatography coupled to diode array detector
Cachaça
Whisky
Principal component analysis
dc.subject.ptbr.pt_BR.fl_str_mv Microextração em fase sólida
Cromatografia gasosa acoplada a detector de ionização por descarga de barreira
Cromatografia líquida de alta eficiência acoplada a detector de arranjo de diodos
Cachaça
Uísque
Análise de componentes principais
dc.subject.en.pt_BR.fl_str_mv Solid-phase microextraction
Gas chromatography coupled to barrier discharge ionization detector
High performance liquid chromatography coupled to diode array detector
Cachaça
Whisky
Principal component analysis
description Cachaça and whiskey distilled beverages are widely consumed in Brazil and their acceptance is closely related to quality control in their production. However, these beverages are frequent targets for adulteration, which alters the quality of these products and can lead to health problems for consumers. This work comprises three chapters where the first deals with a literature review on applications of the Solid-phase microextraction (SPME) technique in cachaça and whisky, the second was the development of a new methodology for the analysis of higher alcohols, n-butanol and total esters using gas chromatography coupled to barrier discharge ionization detector (GC-BID) and SPME via headspace (HS) as a sample preparation method for the analysis of 25 samples of cachaça and 26 of whiskeys, in the third chapter 16 samples of original and 14 counterfeit whiskeys were differentiated through principal component analysis (PCA) applied to data obtained by the HS-SPME-GC-BID method and aldehydes derivatized by 2,4-dinitrophenylhydrazine (2,4-DNPH) in high performance liquid chromatography coupled to diode array detector (HPLC-DAD). The results showed that the use of SPME in chromatographic analyzes of distilled beverages is a powerful tool that allows both the development of methods for quality control applications and the differentiation between original and counterfeit beverages.
publishDate 2023
dc.date.issued.fl_str_mv 2023
dc.date.accessioned.fl_str_mv 2024-06-10T11:59:59Z
dc.date.available.fl_str_mv 2024-06-10T11:59:59Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/doctoralThesis
format doctoralThesis
status_str publishedVersion
dc.identifier.citation.fl_str_mv NASCIMENTO, Hélio Oliveira do. Development of chromatographic method for applications in quality control and authenticity of distilled beverages. 2023. 71 f. Tese (Doutorado em Química) – Universidade Federal do Ceará, Fortaleza, 2023.
dc.identifier.uri.fl_str_mv http://repositorio.ufc.br/handle/riufc/77018
identifier_str_mv NASCIMENTO, Hélio Oliveira do. Development of chromatographic method for applications in quality control and authenticity of distilled beverages. 2023. 71 f. Tese (Doutorado em Química) – Universidade Federal do Ceará, Fortaleza, 2023.
url http://repositorio.ufc.br/handle/riufc/77018
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.none.fl_str_mv reponame:Repositório Institucional da Universidade Federal do Ceará (UFC)
instname:Universidade Federal do Ceará (UFC)
instacron:UFC
instname_str Universidade Federal do Ceará (UFC)
instacron_str UFC
institution UFC
reponame_str Repositório Institucional da Universidade Federal do Ceará (UFC)
collection Repositório Institucional da Universidade Federal do Ceará (UFC)
bitstream.url.fl_str_mv http://repositorio.ufc.br/bitstream/riufc/77018/3/2023_tese_honascimento.pdf
http://repositorio.ufc.br/bitstream/riufc/77018/4/license.txt
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repository.name.fl_str_mv Repositório Institucional da Universidade Federal do Ceará (UFC) - Universidade Federal do Ceará (UFC)
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