Uso de microondas na síntese de 5-hidroxi-5-triclorometi-4,5-diidroisoxazóis
Ano de defesa: | 2002 |
---|---|
Autor(a) principal: | |
Orientador(a): | |
Banca de defesa: | , |
Tipo de documento: | Dissertação |
Tipo de acesso: | Acesso aberto |
Idioma: | por |
Instituição de defesa: |
Universidade Federal de Santa Maria
Centro de Ciências Naturais e Exatas |
Programa de Pós-Graduação: |
Programa de Pós-Graduação em Química
|
Departamento: |
Química
|
País: |
Brasil
|
Palavras-chave em Português: | |
Área do conhecimento CNPq: | |
Link de acesso: | http://repositorio.ufsm.br/handle/1/28142 |
Resumo: | A series of thirteen 5-hydroxy-5-trichloromethyl-4,5- dihydroisoxazoles have been synthesized in 78–96 % yield by environmentally benign microwave induced technique involving the cyclocondensation of 4-alkoxy-1,1,1-trichloro-3-alken-2-ones [CCl3C(O)C(R2)=C(R1)OR, where R2 = H, alkyl; aryl and R=H, alkyl] with hydroxylamine using toluene as solvent. The advantages obtained by the use of microwave irradiation in relation to classical method were demonstrated. |
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Biblioteca Digital de Teses e Dissertações do UFSM |
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2023-03-10T11:55:59Z2023-03-10T11:55:59Z2002-10http://repositorio.ufsm.br/handle/1/28142A series of thirteen 5-hydroxy-5-trichloromethyl-4,5- dihydroisoxazoles have been synthesized in 78–96 % yield by environmentally benign microwave induced technique involving the cyclocondensation of 4-alkoxy-1,1,1-trichloro-3-alken-2-ones [CCl3C(O)C(R2)=C(R1)OR, where R2 = H, alkyl; aryl and R=H, alkyl] with hydroxylamine using toluene as solvent. The advantages obtained by the use of microwave irradiation in relation to classical method were demonstrated.Uma série de treze 5-hidroxi-5-triclorometi-4,5-diidroisoxazóis foi sintetizada, em bons rendimento (78–96 %), através da ceclocondensação de 4-alcoxi-1,1,1-trialometil-3-alquen-2-ona [CCl3C(O)C(R2)=C(R1)OR, onde R2 = H, e R1=H, Me, Et, n-Pr, ciclo-Pr, n-Bu ,isso-Bu, terc-Bu, nhex, Ph, NO2-Ph,-(CH2)-] com hidroxilamina e tolueno como solvente. Demonstrar as vantagens obtidas com o uso de irradiação de microondas em relação a metodologia clássica.Conselho Nacional de Pesquisa e Desenvolvimento Científico e Tecnológico - CNPqporUniversidade Federal de Santa MariaCentro de Ciências Naturais e ExatasPrograma de Pós-Graduação em QuímicaUFSMBrasilQuímicaAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessMicroondasCNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICAUso de microondas na síntese de 5-hidroxi-5-triclorometi-4,5-diidroisoxazóisMicrowave assisted synthesis of 5-hydroxy-5-trichloromethyl-4,5-dihydroisoxazolesinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisMartins, Marcos Antonio Pintohttp://lattes.cnpq.br/6457412713967642Zanatta, NiloSinhorin, Adilson Paulohttp://lattes.cnpq.br/4175014494565472Beck, Paulo Henrique100600000000600600600600600c28419d9-6027-4f9c-acd2-76e8067a85d10cd25fcc-995a-4530-b869-efd6954482c612036c3b-18f6-4b7d-ad7e-5fd56bfce1d762c77e6f-0fe3-4187-8141-d8365e8d38a0reponame:Biblioteca Digital de Teses e Dissertações do UFSMinstname:Universidade Federal de Santa Maria (UFSM)instacron:UFSMORIGINALDIS_PPGQUIMICA_2002_BECK_PAULO.pdfDIS_PPGQUIMICA_2002_BECK_PAULO.pdfDissertaçãoapplication/pdf5334221http://repositorio.ufsm.br/bitstream/1/28142/1/DIS_PPGQUIMICA_2002_BECK_PAULO.pdf7c00a0e8829b976cdc39c8875ac305d5MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8805http://repositorio.ufsm.br/bitstream/1/28142/2/license_rdf4460e5956bc1d1639be9ae6146a50347MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81956http://repositorio.ufsm.br/bitstream/1/28142/3/license.txt2f0571ecee68693bd5cd3f17c1e075dfMD531/281422023-03-10 08:55:59.584oai:repositorio.ufsm.br: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 Digital de Teses e Dissertaçõeshttps://repositorio.ufsm.br/ONGhttps://repositorio.ufsm.br/oai/requestatendimento.sib@ufsm.br||tedebc@gmail.comopendoar:2023-03-10T11:55:59Biblioteca Digital de Teses e Dissertações do UFSM - Universidade Federal de Santa Maria (UFSM)false |
dc.title.por.fl_str_mv |
Uso de microondas na síntese de 5-hidroxi-5-triclorometi-4,5-diidroisoxazóis |
dc.title.alternative.eng.fl_str_mv |
Microwave assisted synthesis of 5-hydroxy-5-trichloromethyl-4,5-dihydroisoxazoles |
title |
Uso de microondas na síntese de 5-hidroxi-5-triclorometi-4,5-diidroisoxazóis |
spellingShingle |
Uso de microondas na síntese de 5-hidroxi-5-triclorometi-4,5-diidroisoxazóis Beck, Paulo Henrique Microondas CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA |
title_short |
Uso de microondas na síntese de 5-hidroxi-5-triclorometi-4,5-diidroisoxazóis |
title_full |
Uso de microondas na síntese de 5-hidroxi-5-triclorometi-4,5-diidroisoxazóis |
title_fullStr |
Uso de microondas na síntese de 5-hidroxi-5-triclorometi-4,5-diidroisoxazóis |
title_full_unstemmed |
Uso de microondas na síntese de 5-hidroxi-5-triclorometi-4,5-diidroisoxazóis |
title_sort |
Uso de microondas na síntese de 5-hidroxi-5-triclorometi-4,5-diidroisoxazóis |
author |
Beck, Paulo Henrique |
author_facet |
Beck, Paulo Henrique |
author_role |
author |
dc.contributor.advisor1.fl_str_mv |
Martins, Marcos Antonio Pinto |
dc.contributor.advisor1Lattes.fl_str_mv |
http://lattes.cnpq.br/6457412713967642 |
dc.contributor.referee1.fl_str_mv |
Zanatta, Nilo |
dc.contributor.referee2.fl_str_mv |
Sinhorin, Adilson Paulo |
dc.contributor.authorLattes.fl_str_mv |
http://lattes.cnpq.br/4175014494565472 |
dc.contributor.author.fl_str_mv |
Beck, Paulo Henrique |
contributor_str_mv |
Martins, Marcos Antonio Pinto Zanatta, Nilo Sinhorin, Adilson Paulo |
dc.subject.por.fl_str_mv |
Microondas |
topic |
Microondas CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA |
dc.subject.cnpq.fl_str_mv |
CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA |
description |
A series of thirteen 5-hydroxy-5-trichloromethyl-4,5- dihydroisoxazoles have been synthesized in 78–96 % yield by environmentally benign microwave induced technique involving the cyclocondensation of 4-alkoxy-1,1,1-trichloro-3-alken-2-ones [CCl3C(O)C(R2)=C(R1)OR, where R2 = H, alkyl; aryl and R=H, alkyl] with hydroxylamine using toluene as solvent. The advantages obtained by the use of microwave irradiation in relation to classical method were demonstrated. |
publishDate |
2002 |
dc.date.issued.fl_str_mv |
2002-10 |
dc.date.accessioned.fl_str_mv |
2023-03-10T11:55:59Z |
dc.date.available.fl_str_mv |
2023-03-10T11:55:59Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/masterThesis |
format |
masterThesis |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://repositorio.ufsm.br/handle/1/28142 |
url |
http://repositorio.ufsm.br/handle/1/28142 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.cnpq.fl_str_mv |
100600000000 |
dc.relation.confidence.fl_str_mv |
600 600 600 600 600 |
dc.relation.authority.fl_str_mv |
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dc.rights.driver.fl_str_mv |
Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ |
eu_rights_str_mv |
openAccess |
dc.publisher.none.fl_str_mv |
Universidade Federal de Santa Maria Centro de Ciências Naturais e Exatas |
dc.publisher.program.fl_str_mv |
Programa de Pós-Graduação em Química |
dc.publisher.initials.fl_str_mv |
UFSM |
dc.publisher.country.fl_str_mv |
Brasil |
dc.publisher.department.fl_str_mv |
Química |
publisher.none.fl_str_mv |
Universidade Federal de Santa Maria Centro de Ciências Naturais e Exatas |
dc.source.none.fl_str_mv |
reponame:Biblioteca Digital de Teses e Dissertações do UFSM instname:Universidade Federal de Santa Maria (UFSM) instacron:UFSM |
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UFSM |
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Biblioteca Digital de Teses e Dissertações do UFSM |
collection |
Biblioteca Digital de Teses e Dissertações do UFSM |
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