Remoção de metais provenientes de drenagem ácida de minas em reator anaeróbio horizontal com biomassa imobilizada

Detalhes bibliográficos
Ano de defesa: 2016
Autor(a) principal: Melo Júnior, Omar Mendes De lattes
Orientador(a): Sancinetti, Giselle Patrícia lattes
Banca de defesa: Brito, Rafael De Moura, Pires, Lorena De Oliveira
Tipo de documento: Dissertação
Tipo de acesso: Acesso aberto
Idioma: por
Instituição de defesa: Universidade Federal de Alfenas
Programa de Pós-Graduação: Programa de Pós-Graduação em Ciência e Engenharia Ambiental
Departamento: Instituto de Ciência e Tecnologia
País: Brasil
Palavras-chave em Português:
Área do conhecimento CNPq:
Link de acesso: https://repositorio.unifal-mg.edu.br/handle/123456789/871
Resumo: The mining activity, beyond positively influence the economic and social development of the country presents a major environmental liabilities: wastewater rich in sulfate. Better known as Acid Mine Drainage, AMD, these wastewaters are from most of the time, mining of coal and heavy metals where the mineral sulfides are oxidized naturally sulphate and the main features low pH and high concentrations metals. There are several treatments for AMD, being physical, chemical and biological. Physicochemical methods consist of neutralization and precipitation of heavy metals, with high operating costs. Already biological methods are an excellent alternative for the treatment and remediation of AMD, because through anaerobic reactors, promote the reduction of sulfate and the recovery of metals. In this study, a horizontal anaerobic fixed bed reactor was used, HABR, for the bioremediation of synthetic AMD, having its interior filled with polyurethane foam for immobilization of biomass and ethanol as carbon source, relationship between the chemical oxygen demand, and sulfate, COD/SO42- and hydraulic retention time, TDH, 24 and 36 hours. Throughout this experiment was varied conditions with respect to concentration of COD and SO42-, HRT and filler metals. The pH, SO42-, sulfide, COD and metals, were very satisfactory in relation to the reactor performance for all operating phases. Increasing the HRT of 24 to 36 hours, it was observed that the removal efficiency values were significant compared with the previous stages. Thus, the study demonstrated its effectiveness for treating AMD in a synthetic HABR, achieving high removal values.
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spelling Melo Júnior, Omar Mendes Dehttp://lattes.cnpq.br/4219001672564016Rodriguez, Renata Piacentinihttp://lattes.cnpq.br/3494982072959140Brito, Rafael De MouraPires, Lorena De OliveiraSancinetti, Giselle Patríciahttp://lattes.cnpq.br/15147415165732552016-10-27T23:06:56Z2016-07-29MELO JÚNIOR, Omar Mendes de. Remoção de metais provenientes de drenagem ácida de minas em reator anaeróbio horizontal com biomassa imobilizada. 2016.50 f. Dissertação (Mestrado em Ciência e Engenharia Ambiental) - Universidade Federal de Alfenas, Poços de Caldas, MG, 2016.https://repositorio.unifal-mg.edu.br/handle/123456789/871The mining activity, beyond positively influence the economic and social development of the country presents a major environmental liabilities: wastewater rich in sulfate. Better known as Acid Mine Drainage, AMD, these wastewaters are from most of the time, mining of coal and heavy metals where the mineral sulfides are oxidized naturally sulphate and the main features low pH and high concentrations metals. There are several treatments for AMD, being physical, chemical and biological. Physicochemical methods consist of neutralization and precipitation of heavy metals, with high operating costs. Already biological methods are an excellent alternative for the treatment and remediation of AMD, because through anaerobic reactors, promote the reduction of sulfate and the recovery of metals. In this study, a horizontal anaerobic fixed bed reactor was used, HABR, for the bioremediation of synthetic AMD, having its interior filled with polyurethane foam for immobilization of biomass and ethanol as carbon source, relationship between the chemical oxygen demand, and sulfate, COD/SO42- and hydraulic retention time, TDH, 24 and 36 hours. Throughout this experiment was varied conditions with respect to concentration of COD and SO42-, HRT and filler metals. The pH, SO42-, sulfide, COD and metals, were very satisfactory in relation to the reactor performance for all operating phases. Increasing the HRT of 24 to 36 hours, it was observed that the removal efficiency values were significant compared with the previous stages. Thus, the study demonstrated its effectiveness for treating AMD in a synthetic HABR, achieving high removal values.A atividade minerária, além de influenciar de maneira positiva no desenvolvimento econômico e social do país, apresenta um dos principais passivos ambientais: as águas residuárias ricas em sulfato. Mais conhecidas como Drenagem Ácida de Minas, DAM, essas águas residuárias são oriundas na maioria das vezes, da mineração de carvão e metais pesados, onde os minerais de sulfetos são oxidados de maneira natural a sulfato tendo como principais características o baixo pH e elevadas concentrações de metais. Diversos são os tratamentos para a DAM, sendo eles físico-químicos e biológicos. Os métodos físico-químicos consistem na neutralização e precipitação dos metais pesados, apresentando elevado custo operacional. Já os métodos biológicos são uma excelente alternativa para o tratamento e remediação da DAM, pois através de reatores anaeróbios, promovem a redução do sulfato e a recuperação dos metais. Nesse estudo, foi utilizado um reator anaeróbio horizontal de leito fixo, RAHLF, para a biorremediação da DAM sintética, tendo seu interior preenchido com espuma de poliuretano para imobilização da biomassa e o etanol como fonte de carbono, relação entre a Demanda Química de Oxigênio e Sulfato, DQO/SO42- de 1 e Tempo de Detenção Hidráulica, TDH, de 24 e 36 horas. Ao longo do experimento variou-se as condições da alimentação, com relação a concentração de DQO e SO42-, TDH, bem como adição de metais. As análises de pH, SO42-, sulfeto, DQO e metais, foram muito satisfatórias em relação ao desempenho do reator para todas as fases de operação. Aumentando-se o TDH de 24 para 36 horas, observou-se que os valores na eficiência de remoção, foram significativos quando comparados com as fases anteriores. Dessa maneira, o estudo mostrou-se eficiente para o tratamento da DAM sintética em um RAHLF, alcançando elevados valores de remoção.application/pdfporUniversidade Federal de AlfenasPrograma de Pós-Graduação em Ciência e Engenharia AmbientalUNIFAL-MGBrasilInstituto de Ciência e Tecnologiainfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/BiorremediaçãoMinas – DrenagemÁguas residuaisTratamento anaeróbioENGENHARIA SANITARIA::TRATAMENTO DE AGUAS DE ABASTECIMENTO E RESIDUARIASRemoção de metais provenientes de drenagem ácida de minas em reator anaeróbio horizontal com biomassa imobilizadaMetals removal from acid mine drainage in horizontal anaerobic immobilized biomassinfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/publishedVersion-4297417259498638931600600-4957377345672117885reponame:Repositório Institucional da Universidade Federal de Alfenas - RiUnifalinstname:Universidade Federal de Alfenas (UNIFAL)instacron:UNIFALMelo Júnior, Omar Mendes DeLICENSElicense.txtlicense.txttext/plain; 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dc.title.pt-BR.fl_str_mv Remoção de metais provenientes de drenagem ácida de minas em reator anaeróbio horizontal com biomassa imobilizada
dc.title.alternative.eng.fl_str_mv Metals removal from acid mine drainage in horizontal anaerobic immobilized biomass
title Remoção de metais provenientes de drenagem ácida de minas em reator anaeróbio horizontal com biomassa imobilizada
spellingShingle Remoção de metais provenientes de drenagem ácida de minas em reator anaeróbio horizontal com biomassa imobilizada
Melo Júnior, Omar Mendes De
Biorremediação
Minas – Drenagem
Águas residuais
Tratamento anaeróbio
ENGENHARIA SANITARIA::TRATAMENTO DE AGUAS DE ABASTECIMENTO E RESIDUARIAS
title_short Remoção de metais provenientes de drenagem ácida de minas em reator anaeróbio horizontal com biomassa imobilizada
title_full Remoção de metais provenientes de drenagem ácida de minas em reator anaeróbio horizontal com biomassa imobilizada
title_fullStr Remoção de metais provenientes de drenagem ácida de minas em reator anaeróbio horizontal com biomassa imobilizada
title_full_unstemmed Remoção de metais provenientes de drenagem ácida de minas em reator anaeróbio horizontal com biomassa imobilizada
title_sort Remoção de metais provenientes de drenagem ácida de minas em reator anaeróbio horizontal com biomassa imobilizada
author Melo Júnior, Omar Mendes De
author_facet Melo Júnior, Omar Mendes De
author_role author
dc.contributor.author.fl_str_mv Melo Júnior, Omar Mendes De
dc.contributor.advisor1Lattes.fl_str_mv http://lattes.cnpq.br/4219001672564016
dc.contributor.advisor-co1.fl_str_mv Rodriguez, Renata Piacentini
dc.contributor.advisor-co1Lattes.fl_str_mv http://lattes.cnpq.br/3494982072959140
dc.contributor.referee1.fl_str_mv Brito, Rafael De Moura
dc.contributor.referee2.fl_str_mv Pires, Lorena De Oliveira
dc.contributor.advisor1.fl_str_mv Sancinetti, Giselle Patrícia
dc.contributor.authorLattes.fl_str_mv http://lattes.cnpq.br/1514741516573255
contributor_str_mv Rodriguez, Renata Piacentini
Brito, Rafael De Moura
Pires, Lorena De Oliveira
Sancinetti, Giselle Patrícia
dc.subject.por.fl_str_mv Biorremediação
Minas – Drenagem
Águas residuais
Tratamento anaeróbio
topic Biorremediação
Minas – Drenagem
Águas residuais
Tratamento anaeróbio
ENGENHARIA SANITARIA::TRATAMENTO DE AGUAS DE ABASTECIMENTO E RESIDUARIAS
dc.subject.cnpq.fl_str_mv ENGENHARIA SANITARIA::TRATAMENTO DE AGUAS DE ABASTECIMENTO E RESIDUARIAS
description The mining activity, beyond positively influence the economic and social development of the country presents a major environmental liabilities: wastewater rich in sulfate. Better known as Acid Mine Drainage, AMD, these wastewaters are from most of the time, mining of coal and heavy metals where the mineral sulfides are oxidized naturally sulphate and the main features low pH and high concentrations metals. There are several treatments for AMD, being physical, chemical and biological. Physicochemical methods consist of neutralization and precipitation of heavy metals, with high operating costs. Already biological methods are an excellent alternative for the treatment and remediation of AMD, because through anaerobic reactors, promote the reduction of sulfate and the recovery of metals. In this study, a horizontal anaerobic fixed bed reactor was used, HABR, for the bioremediation of synthetic AMD, having its interior filled with polyurethane foam for immobilization of biomass and ethanol as carbon source, relationship between the chemical oxygen demand, and sulfate, COD/SO42- and hydraulic retention time, TDH, 24 and 36 hours. Throughout this experiment was varied conditions with respect to concentration of COD and SO42-, HRT and filler metals. The pH, SO42-, sulfide, COD and metals, were very satisfactory in relation to the reactor performance for all operating phases. Increasing the HRT of 24 to 36 hours, it was observed that the removal efficiency values were significant compared with the previous stages. Thus, the study demonstrated its effectiveness for treating AMD in a synthetic HABR, achieving high removal values.
publishDate 2016
dc.date.accessioned.fl_str_mv 2016-10-27T23:06:56Z
dc.date.issued.fl_str_mv 2016-07-29
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dc.identifier.citation.fl_str_mv MELO JÚNIOR, Omar Mendes de. Remoção de metais provenientes de drenagem ácida de minas em reator anaeróbio horizontal com biomassa imobilizada. 2016.50 f. Dissertação (Mestrado em Ciência e Engenharia Ambiental) - Universidade Federal de Alfenas, Poços de Caldas, MG, 2016.
dc.identifier.uri.fl_str_mv https://repositorio.unifal-mg.edu.br/handle/123456789/871
identifier_str_mv MELO JÚNIOR, Omar Mendes de. Remoção de metais provenientes de drenagem ácida de minas em reator anaeróbio horizontal com biomassa imobilizada. 2016.50 f. Dissertação (Mestrado em Ciência e Engenharia Ambiental) - Universidade Federal de Alfenas, Poços de Caldas, MG, 2016.
url https://repositorio.unifal-mg.edu.br/handle/123456789/871
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